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Experimental study of phase equilibria in the “SnO2” – CaO – SiO2 system in air

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Published/Copyright: May 14, 2013

Abstract

Experimental studies have been conducted to determine the primary phases and liquidus temperatures in the “SnO2” – CaO – SiO2 system in air between 1693 and 1898 K, using high temperature equilibration and quenching followed by electron probe X-ray microanalysis. The following primary phase fields were identified: CaSiSnO5 (malayaite), Ca3Si2SnO9 (tricalcium tin silicate), CaSiO3 (pseudo-wollastonite), Ca2SiO4 (dicalcium silicate), SiO2 (tridymite and cristobalite), SnO2 (cassiterite) and CaSnO3 (calcium stannate).


* Correspondence address Mr. Xiaoyong Xu, The Pyrosearch Centre at the School of Chemical Engineering The University of Queensland, Brisbane Qld 4072, Australia, Tel.: +61 7 33 65 36 66, Fax: +61 7 33 65 38 88, E-mail:

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Received: 2010-3-26
Accepted: 2011-8-16
Published Online: 2013-05-14
Published in Print: 2011-10-01

© 2011, Carl Hanser Verlag, München

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