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Hydrogen as a probe into 5f-magnetism

  • Silvie Mašková , Ladislav Havela , Eva Šantavá und Khrystyna Miliyanchuk
Veröffentlicht/Copyright: 11. Juni 2013
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Abstract

We performed magnetic measurements on the hydrogenated system (U, Th)CoSn as part of an investigation of UTX compounds (T – transitional metal, X – p-metal). The U1–xThxCoSn compounds crystallize in the hexagonal structure (ZrNiAl type, space group P 2m). Hydrogen absorption of approximately 1 H/f. u. could be achieved. The hydrogenation does not change the crystal structure. In all cases it leads to a unit-cell expansion by 3.0 % to 3.6 %. Studies of the temperature dependence of the magnetic susceptibility indicate a certain increase in the Curie temperature TC in the hydrides, but the Th concentration at which ferromagnetism vanishes remains practically unchanged (U0.2Th0.8CoSn has a paramagnetic ground state).


* Correspondence address, Mgr. Silvie Mašková, Ke Karlovu 5, 12116, Prague, Czech Republic, Tel.: +42 02 2191 1351, Fax: +42 02 2191 1351, E-mail:

References

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[3] K.Miliyanchuk, L.Havela, J.C.Waerenborgh, P.M.Gaczynski, O.Prokhnenko: Chem. Met. Alloys1 (2008) 174.Suche in Google Scholar

Received: 2008-8-26
Accepted: 2009-2-27
Published Online: 2013-06-11
Published in Print: 2009-09-01

© 2009, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. History
  4. Pierre Auger – Lise Meitner: Comparative contributions to the Auger effect
  5. Surface and grain-boundary segregation studied by quantitative AES and XPS
  6. High temperature mechanical spectroscopy of fine-grained ceramics
  7. The effect of electro-thermal fatigue on the structure of power electronic devices. Micro-structural evolution of the metallization layer
  8. f-Element hydrides: structure and magnetism
  9. Basic
  10. Hydrogen as a probe into 5f-magnetism
  11. Magnetism in PrPdSn and NdPdSn studied on single crystals
  12. Magnetic properties of fcc Ni-based transition metal alloys
  13. X-ray characterization of magnetic digital alloys
  14. Are RENiAl hydrides metallic?
  15. HoZn5Al3: rare-earth magnetism in a new structure type
  16. The influence of substitutions on the magnetocaloric effect in RCo2 compounds
  17. Thickness shear modes and magnetoelastic waves in a bi-layered structure: magnetic film–non-magnetic substrate
  18. Electrochemical properties of fine-grained AZ31 magnesium alloy
  19. Severe plastic deformation in Gum Metal with composition at the structural stability limit
  20. Applied
  21. Structural, magnetic, and transport properties of quantum well GaAs/δ-Mn/GaAs/InxGa1–xAs/GaAs heterostructures
  22. Effect of co-doping by Pb and La on structural and magnetic properties of Bi2212 superconducting ceramics
  23. Magnetic properties of the hydrogenated unconventional superconductor UCoGe–H
  24. Electrophoresis deposition of metal nanoparticles with reverse micelles onto InP
  25. Electronic structure and electric field gradient calculations for the Zr2Ni intermetallic compound
  26. Solution growth of the Gd–Cu–Al systems in the low-gadolinium concentration range
  27. Low-temperature specific heat of selected ceramics
  28. Novel behaviors in rare-earth-filled skutterudites studied by bulk-sensitive photoemission spectroscopy
  29. Charge transport in photosensitive nanocrystalline PbTe(In) films in an alternating electric field
  30. Enrichment and depletion of alloying elements in surface layers of iron base alloys annealed under different conditions
  31. Notifications
  32. Personal
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