Startseite Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte

  • Iwao Katayama , Dragana Živković , Rada Novaković und Hiromi Yamashita
Veröffentlicht/Copyright: 18. Mai 2013
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen
International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 99 Heft 12

Abstract

The EMF of galvanic cells with zirconia solid electrolytes was measured to determine the activity of gallium in liquid Ga-Bi-Sn alloys in the temperature range of 1000–1250 K along three pseudo-binary lines of (Biy, Sn1−y)-Ga where y = 0.25, 0.50 and 0.75. A mixture of Ga and Ga203 was used as a reference electrode. The activity curves of Ga show positive deviations from ideality in the whole composition range. The excess free energies of mixing for Ga-Bi-Sn alloys have been calculated using the general solution model in the same temperature range and along same pseudo-binary lines. The gallium activities obtained by the EMF method and calculated using the general solution model at 1100 K were compared with literature data.

Keywords: Gallium-bismuth-tin alloy; Activity; Liquid alloy; Electromotive force method; Thermodynamics
∗ Correspondence address, Dr. Iwao Katayama, National Institute of Advanced Industrial Science and Technology, (AIST), Kansai, Research Institute for Ubiquitous Energy Devices, 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan, Tel.: +8172751 7821, Fax: +8172751 9623. E-mail:

References

[1] S.P.Yatsenko, V.N.Danilin: Neorgan. Mater.4 (1968) 863.Suche in Google Scholar

[2] B.Predel, M.Frebel, W.Gust: J. Less Comm. Met.17 (1969) 391.10.1016/0022-5088(69)90065-4Suche in Google Scholar

[3] M.Gambino, J.P.Bros, F.Agersch, I.Ansara: Thermochim. Acta, 14 (1974) 305.10.1016/0040-6031(76)85007-1Suche in Google Scholar

[4] Z.Moser, K.Rzyman: Arch. Metall.32 (1987) 3.Suche in Google Scholar

[5] I.Katayama, J.Nakayama, T.Ikura, Z.Kozuka, T.Iida: Mat. Trans. JIM34 (1993) 792.Suche in Google Scholar

[6] D.Zivkovic, D.Manasijevic, Z.Zivkovic: J. Therm. Anal. Calor.79 (2005) 71.10.1007/s10973-004-0564-7Suche in Google Scholar

[7] B.Predel: J. Less-Common Met.7 (1964) 347.10.1016/0022-5088(64)90079-7Suche in Google Scholar

[8] V.N.Danilin, S.P.Yatsenko: Izv. Akad. Nauk SSSR, Metall.5 (1968) 14.Suche in Google Scholar

[9] J.Anderson, I.Ansara: J. Phase Equilib.13 (1992) 181.10.1007/BF02667485Suche in Google Scholar

[10] I.Katayama, K.Maki, M.Nakano, T.Iida: Mat. Trans. JIM37 (1996) 988.Suche in Google Scholar

[11] R.Novakovic, D.Zivkovic: J. Mater. Sci.40 (2005) 2251.10.1007/s10853-005-1942-7Suche in Google Scholar

[12] I.Katayama, T.Tanaka, S.Akai, K.Yamazaki, T.Iida: Mater. Sci. Forum502 (2005) 129; D.V. Malakhov, J.-L. Xing, I. Ohnu-ma, K. Ishida: J. Phase Equilib. 21 (2000) 514.10.4028/www.scientific.net/MSF.502.129Suche in Google Scholar

[13] Y.M.Muggianu, M.Gambino, J.P.Bros: J. Chim. Physique72 (1975) 83.Suche in Google Scholar

[14] R.Q.Li: Calphad13 (1989) 67.10.1016/0364-5916(89)90040-0Suche in Google Scholar

[15] D.Zivkovic, I.Katayama, R.Novakovic, J.Lee, T.Tanaka, in: H.Oonk (Ed.), Calphad XXXIV, Maastricht (The Netherlands), 22–27 May 2005, Book of Abstracts, pp. 144.Suche in Google Scholar

[16] D.Zivkovic, I.Katayama, L.Gomidzelovic, D.Manasijevic. R.Novakovic: Int. J. Mat. Res. (Z. Metallkd.)98 (2007) 1025.10.3139/146.101561Suche in Google Scholar

[17] I.Katayama, K.Shimazawa, D.Zivkovic, D.Manasijevic, Z.Zivkovic, T.Iida: Z. Metallkd.94 (2003) 1296.Suche in Google Scholar

[18] I.Katayama, KYamazaki, Y.Hattori, T.Iida: Mater. Trans. JIM41 (2003) 251.Suche in Google Scholar

[19] K.C.Chou: Calphad19 (1995) 315.10.1016/0364-5916(95)00029-ESuche in Google Scholar

[20] K.C.Chou, W.C.Li, F.Li, M.He: Calphad20 (1996) 395.10.1016/S0364-5916(97)00002-3Suche in Google Scholar

[21] Scientific Group of Thermodata Europe: SGTE Solution Data, Edition 1992.Suche in Google Scholar

[22] H.Ohtani, KIshida: J. Electron. Mater.23 (1994) 747.10.1007/BF02651369Suche in Google Scholar

[23] Ver.2.2 COST531 Thermodynamic Database, 2006. (http://www.univie.ac.at/cost531)Suche in Google Scholar

Received: 2007-11-10
Accepted: 2008-9-19
Published Online: 2013-05-18
Published in Print: 2008-12-01

© 2008, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Editorial December 2008
  5. Basic
  6. Thermodynamic description of the C-Fe-Mn system with key experiments and its practical applications
  7. A study of phase equilibria in the Al-rich part of the Al-Mn alloy system
  8. Transient dopant segregation and precipitation in yttrium-doped alumina
  9. Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte
  10. Modeling of the hot deformation behavior of boron microalloyed steels under uniaxial hot-compression conditions
  11. A new kinetic treatment of the oxidation of β-SiAlON powder
  12. Quantification of ∊-martensite after thermocycling in Fe-(17∼25)Mn alloys
  13. The effect of pre-structure process on magnetorheological elastomer performance
  14. Applied
  15. Corrosion protective double layer hard coatings
  16. Interpretation of inorganic melts' surface properties on the basis of chemical status and structural relations
  17. Basic
  18. Achieving ultra-fine grains in AZ61 Mg alloy by friction stir processing
  19. The combined effect of titanic carbide and aluminum phosphide on the refinement of primary silicon in Al-50Si alloy
  20. Applied
  21. The role of solidification conditions on the microstructural features of AA6111 aluminum strips cast on a horizontal single belt caster
  22. Far infrared spectroscopy of Pb0.85Sn0.15Te alloy doped with Ni
  23. DGM News
  24. DGM News
https://doi.org/10.3139/146.101774
Schlagwörter für diesen Artikel
Gallium-bismuth-tin alloy; Activity; Liquid alloy; Electromotive force method; Thermodynamics

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Editorial December 2008
  5. Basic
  6. Thermodynamic description of the C-Fe-Mn system with key experiments and its practical applications
  7. A study of phase equilibria in the Al-rich part of the Al-Mn alloy system
  8. Transient dopant segregation and precipitation in yttrium-doped alumina
  9. Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte
  10. Modeling of the hot deformation behavior of boron microalloyed steels under uniaxial hot-compression conditions
  11. A new kinetic treatment of the oxidation of β-SiAlON powder
  12. Quantification of ∊-martensite after thermocycling in Fe-(17∼25)Mn alloys
  13. The effect of pre-structure process on magnetorheological elastomer performance
  14. Applied
  15. Corrosion protective double layer hard coatings
  16. Interpretation of inorganic melts' surface properties on the basis of chemical status and structural relations
  17. Basic
  18. Achieving ultra-fine grains in AZ61 Mg alloy by friction stir processing
  19. The combined effect of titanic carbide and aluminum phosphide on the refinement of primary silicon in Al-50Si alloy
  20. Applied
  21. The role of solidification conditions on the microstructural features of AA6111 aluminum strips cast on a horizontal single belt caster
  22. Far infrared spectroscopy of Pb0.85Sn0.15Te alloy doped with Ni
  23. DGM News
  24. DGM News
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 30.9.2025 von https://www.degruyterbrill.com/document/doi/10.3139/146.101774/html
Button zum nach oben scrollen