Startseite Thermodynamic description of the C-Fe-Mn system with key experiments and its practical applications
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Thermodynamic description of the C-Fe-Mn system with key experiments and its practical applications

  • Lijun Zhang , Yong Du , Qing Chen , Honghui Xu , Feng Zheng , Chengying Tang und Hailin Chen
Veröffentlicht/Copyright: 18. Mai 2013
Veröffentlichen auch Sie bei De Gruyter Brill

Abstract

Based on the critically reviewed experimental data available in the literature, new phase transition temperatures and phase equilibria at 800 °C close to the Cu-Fe side of the Cu-Fe-Mn system were measured in the present work. The composition-invariant (γFe, γMn) → (αFe) massive transformations were observed in the two quenched alloys in the Fe-rich region. A set of consistent thermodynamic parameters of the Cu-Fe-Mn system was then obtained by taking into account all kinds of experimental data. Comparisons between the calculated and measured phase diagrams indicate that most of the experimental information is satisfactorily described by the present thermodynamic modeling. The liquidus isolines, liquidus projection and reaction scheme of this ternary system are also presented. Significant improvements have been made, compared with the previous assessments. The presently obtained parameters were applied in successfully solving the !surface fissure" during hot rolling of steel and controlling the micro-structure of the Cu-Fe based alloys in rapid solidification.


Correspondence address, Professor Dr. Yong Du, State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083, P.R. China, Tel.: +86731 8836213, Fax: +86731 8710855. E-mail:

References

[1] D.W.James: Mater. Sci. Eng.4 (1969) 1.10.1016/0025-5416(69)90033-0Suche in Google Scholar

[2] J.M.Vitek, H.Warlimont: Met. Sci.10 (1976) 7.10.1179/030634576790431426Suche in Google Scholar

[3] C.P.Wang, XJ.Liu, I.Ohnuma, R.Kainuma, K.Ishida: J. Alloys Compd.438 (2007) 129.10.1016/j.jallcom.2006.08.018Suche in Google Scholar

[4] L.J.Zhang, Y.Du, H.H.Xu, C.Y.Tang, H.L.Chen, W.Q.Zhang: J. Alloys Compd.454 (2008) 129.10.1016/j.jallcom.2006.12.042Suche in Google Scholar

[5] L.J.Zhang, Y.Du: CALPHAD31 (2007) 529.10.1016/j.calphad.2007.03.003Suche in Google Scholar

[6] Y.Du, J.C.Schuster, Z.-K.Liu, R.X.Hu, P.Nash, W.H.Sun. W.W.Zhang, J.Wang, LJ.Zhang, C.Y.Tang, ZJ.Zhu, S.H.Liu, Y.F.Ouyang, W.Q.Zhang, N.Krendelsberger: Intermetallics16 (2008) 554.10.1016/j.intermet.2008.01.003Suche in Google Scholar

[7] Y.Du, J.Wang, J.R.Zhao, J.C.Schuster, F.Weitzer, R.Schmid-Fetzer, M.Ohno, H.H.Xu, Z.-K.Liu, S.L.Shang, W.Q.Zhang: Int. J. Mat. Res.98 (2007) 855.10.3139/146.101547Suche in Google Scholar

[8] N.Parravano: Int. Z. Metallogr.4 (1913) 171.Suche in Google Scholar

[9] Y.A.Chang, J.P.Neumann, A.Mikula, D.Goldberg: Phase Diagrams and Thermodynamic Properties of Ternary Copper-Metal Systems, Int. Copper Research Association, Vol. VI, (1979).Suche in Google Scholar

[10] V.G.Rivlin, G.VRaynor: Int. Met. Rev.28 (1983) 23.10.1179/095066083790411731Suche in Google Scholar

[11] G.V.Raynor, V.G.Rivlin: Phase Equilibria in Iron Ternary Alloys, Vol. 4, The Institute of Metals, London (1988) 345.Suche in Google Scholar

[12] P.Villars, A.Prince, H.Okamoto: Handbook of ternary alloy phase diagrams, Vol. 7, ASM International, Materials Park, OH (1995) 9336.Suche in Google Scholar

[13] V.Raghavan: J. Phase Equilib.15 (1994) 542.10.1007/BF02649414Suche in Google Scholar

[14] V.Raghavan: J. Phase Equilib.23 (2002) 259.10.1361/105497102770331767Suche in Google Scholar

[15] M.Hasebe, T.Nishizawa: Applications of phase diagrams in metallurgy and ceramics, National Bureau of Standards SP-496, Vol. 2, Washington (1978) 911.Suche in Google Scholar

[16] TNishizawa, M.Hasebe: Tetsu-to-Hagane67 (1981) 2086.Suche in Google Scholar

[17] AT.Dinsdale: CALPHAD15 (1991) 317.10.1016/0364-5916(91)90030-NSuche in Google Scholar

[18] K.C.Harikumar, V.Raghavan: J. Alloy Phase Diagrams4 (1988) 53.Suche in Google Scholar

[19] K.C.Harikumar, V.Raghavan: J. Alloy Phase Diagrams5 (1989) 201.Suche in Google Scholar

[20] H.Ohtani, H.Suda, K.Ishida: ISIJ Int.37 (1997) 207.10.2355/isijinternational.37.207Suche in Google Scholar

[21] J.Miettinen: CALPHAD27 (2003) 141.10.1016/j.calphad.2003.08.004Suche in Google Scholar

[22] R.Schmid-Fetzer, D.Andersson, P.Y.Chevalier, L.Eleno, O.Fabrichnaya, U.R.Kattner, B.Sundman, C.Wang, A.Watson, L.Zabdyr, M.Zinkevich: CALPHAD31 (2007) 38.10.1016/j.calphad.2006.02.007Suche in Google Scholar

[23] C.Y.He, Y.Du, H.-L.Chen, S.H.Liu, H.H.Xu, Y.F.Ouyang, Z.K.Liu: J. Alloys Compd.457 (2008) 233.10.1016/j.jallcom.2007.03.041Suche in Google Scholar

[24] W.J.M.Salter: J. Iron Steel Inst.204 (1966) 478.Suche in Google Scholar

[25] C.P.Wang: Ph.D. Thesis, Tohoku University, Japan (2001).Suche in Google Scholar

[26] I.Ansara, A.Jansson: Trita-Mac-0533, Materials research centre, the Royal Institute of Technology, Stockholm (1993).Suche in Google Scholar

[27] W.Huang: CALPHAD13 (1989) 243.10.1016/0364-5916(89)90004-7Suche in Google Scholar

[28] O.Redlich, A.T.Kister: Ind. Eng. Chem.40 (1948) 345.10.1021/ie50458a036Suche in Google Scholar

[29] GInden, in: The proceedings of CALPHAD V project meeting, Max-Planck Institute for Metal Research, Diisseldorf (1976) 1.Suche in Google Scholar

[30] M.Hillert, M.Jarl: CALPHAD2 (1978) 227.10.1016/0364-5916(78)90011-1Suche in Google Scholar

[31] N.M.Hwang, D.YYoon: J. Mater. Sci.32 (1997) 4847.10.1023/A:1018655603436Suche in Google Scholar

[32] T.B.Massalski: ActaMetall.6 (1958) 243.10.1016/0001-6160(58)90143-3Suche in Google Scholar

[33] J.E.Kittl, T.B.Massalski: ActaMetall.15 (1967) 161.Suche in Google Scholar

[34] T.B.Massalski: Metall. Mater. Trans. A33 (2002) 2277.10.1007/s11661-002-0351-7Suche in Google Scholar

[35] J.-OAndersson, T.Helander, L.Hoglund, P.F.Shi, B.Sundman: CALPHAD26 (2002) 273.10.1016/S0364-5916(02)00037-8Suche in Google Scholar

[36] B.Sundman, B.Jansson, J.-O.Andersson: CALPHAD9 (1985) 153.10.1016/0364-5916(85)90021-5Suche in Google Scholar

[37] Y.Du, R.Schmid-Fetzer, H.Ohtani: Z. Metallkd.88 (1997) 545.Suche in Google Scholar

[38] A.D.de Silva, J.Agren, M.T.Clavaguera-Mora, D.Djurovic, T.Gomez-Acebo, B.-J.Lee, Z.-K.Liu, P.Miodownik, H.J.Sei-fert: CALPHAD31 (2007) 53.10.1016/j.calphad.2006.02.006Suche in Google Scholar

[39] S.Oki: Tetsu-to-Hagane43 (1957) 1293.10.2355/tetsutohagane1955.43.12_1293Suche in Google Scholar

[40] E.Asano, A.Suseki: Tetsu-to-Hagane45 (1959) 27.Suche in Google Scholar

[41] A.Nicholson, J.D.Murray: J. Iron Steel Inst.203 (1965) 1007.Suche in Google Scholar

[42] T.Kajitani, M.Wakoh, N.Tokumitsu, S.Ogibayashi, S.Mizogu-chi: Tetsu-to-Hagane81 (1995) 185.Suche in Google Scholar

[43] H.L.Chen: Ph.D. Thesis, Central South University, China (2008).Suche in Google Scholar

[44] Q.Chen, Z.P.Jin: Metall. Mater. Trans. A25 (1995) 417.10.1007/BF02664678Suche in Google Scholar

[45] Y.Nakagawa: Acta Metall.6 (1958) 704.10.1016/0001-6160(58)90061-0Suche in Google Scholar

[46] GWilde, R.Willnecker, R.N.Singh, F.Sommer: Z. Metallkd.88 (1997) 804.Suche in Google Scholar

[47] S.Amara, A.Belhadj, R.Kesri, S.H.Thibault: Z. Metallkd.90 (1999) 116.Suche in Google Scholar

[48] X.YLu, CD.Cao, B.Wei: Mater. Sci. Eng. A313 (2001) 198.10.1016/S0921-5093(01)00928-5Suche in Google Scholar

Received: 2008-4-12
Accepted: 2008-9-10
Published Online: 2013-05-18
Published in Print: 2008-12-01

© 2008, Carl Hanser Verlag, München

Heruntergeladen am 21.9.2025 von https://www.degruyterbrill.com/document/doi/10.3139/146.101773/html
Button zum nach oben scrollen