Experimental study and thermodynamic assessment of the ZrO2–DyO1.5 system
-
Chong Wang
, Matsvei Zinkevich und Fritz Aldinger
Abstract
The phase equilibria and thermodynamic properties in the ZrO2 – DyO1.5 system have been studied using the experimental methods of X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, differential thermal analysis and high temperature drop calorimetry. The tetragonal + fluorite and fluorite + C-Dy2O3 phase equilibria between 1400 °C and 1700 °C have been determined, together with the enthalpy increments of the materials with 30 mol.% and 50 mol.% DyO1.5 in the temperature range 200 – 1400 °C. Furthermore, the martensitic transformation temperatures (As, Ms) have been measured for the samples with 1 and 2 mol.% DyO1.5. Finally, thermodynamic assessment has been carried out using the experimental results obtained and literature data.
References
[1] J.Wu, X.Wei, N.P.Padture, P.G.Klemens, M.Gell, E.Garcia, P.Miranzo, M.I.Osendi: J. Am. Ceram. Soc.85 (2002) 3031.10.1111/j.1151-2916.2002.tb00574.xSuche in Google Scholar
[2] M.Yashima, M.Kakihana, M.Yoshimura: Solid State Ionics86–88 (1996) 1131.Suche in Google Scholar
[3] R.H.J.Hannink, P.M.Kelly, B.C.Muddle: J. Am. Ceram. Soc.83 (2000) 461.10.1111/j.1151-2916.2000.tb01221.xSuche in Google Scholar
[4] M.Perez, Y.Jorba: Ann. Chim.7 (1962) 479.Suche in Google Scholar
[5] M.R.Thornber, D.J.M.Bevan, E.Summerville: J. Solid State Chem.1 (1970) 545.10.1016/0022-4596(70)90140-4Suche in Google Scholar
[6] A.Rouanet: Rev. Int. Hautes Temp. Refract.8 (1971) 161.Suche in Google Scholar
[7] C.Pascual, P.Duran: J. Mater. Sci.15 (1980) 1701.10.1007/BF00550588Suche in Google Scholar
[8] A.M.Gavrish, L.S.Alekseenko, L.A.Tatrsova, G.P.Orekhova: Inorg. Mater.17 (1981) 1541.Suche in Google Scholar
[9] E.I.Zoz, E.N.Fomichev, A.A.Kalashnik, G.G.Eliseeva: Russ. J. Inorg. Chem.27 (1982) 95.Suche in Google Scholar
[10] M.Zinkevich, Ch.Wang, F.M.Morales, M.Rühle, F.Aldinger: J. Alloy. Compd.398 (2005) 261.10.1016/j.jallcom.2005.02.022Suche in Google Scholar
[11] K.Helean, B.D.Begg, A.Navrotsky, B.Ebbinghaus, W.J.Weber, R.C.Ewing: Mat. Res. Soc. Proc.663 (2001) 691.10.1557/PROC-663-691Suche in Google Scholar
[12] Ch.Wang, M.Zinkevich, F.Aldinger: J. Am. Ceram. Soc.89 (2006) 3751.10.1111/j.1551-2916.2006.01286.xSuche in Google Scholar
[13] M.Zinkevich: Prog. Mater. Sci. (2006) in press.Suche in Google Scholar
[14] M.Hillert, B.Jansson, B.Sundman, J.Ågren: Metall. Trans. A16 (1985) 261.Suche in Google Scholar
[15] M.Hillert: J. Alloy. Compd.320 (2001) 161.10.1016/S0925-8388(00)01481-XSuche in Google Scholar
[16] O.Fabrichnaya, F.Aldinger: Z. Metallkd.95 (2004) 27.Suche in Google Scholar
[17] B.Sundman, B.Jansson, J.-O.Andersson: Calphad9 (1985) 153.10.1016/0364-5916(85)90021-5Suche in Google Scholar
[18] A.T.Dinsdale: Calphad15 (1991) 317.10.1016/0364-5916(91)90030-NSuche in Google Scholar
© 2007, Carl Hanser Verlag, München
Artikel in diesem Heft
- Contents
- Contents
- Basic
- A comparison of different distributions of azimuth angles in the sin2 ψ-method
- Experimental study and thermodynamic assessment of the ZrO2–DyO1.5 system
- Liquid–solid phase equilibria in metal-rich Hf–Ti–Si alloys
- Density and atomic volume in liquid Al–Fe and Al–Ni binary alloys
- Identification of liquid/solid transformations in eutectic Pb–Sn alloy
- Cyclic deformation behaviour and lifetime calculation of the magnesium die-cast alloys AZ91D, MRI 153M and MRI 230D
- Applied
- Superplastic deformation behavior of a spray-deposited eutectic NiAl/Cr(Mo) alloy doped with Dy
- Fracture behavior of overmatched ductile iron weldment
- Design of carbide-free low-temperature ultra high strength bainitic steels
- The influence of orientation and aluminium content on the deformation mechanisms of Hadfield steel single crystals
- Effect of tempering on the microstructure and hardness of ledeburitic chromium steel X155CrVMo12.1
- Notifications
- DGM News
Artikel in diesem Heft
- Contents
- Contents
- Basic
- A comparison of different distributions of azimuth angles in the sin2 ψ-method
- Experimental study and thermodynamic assessment of the ZrO2–DyO1.5 system
- Liquid–solid phase equilibria in metal-rich Hf–Ti–Si alloys
- Density and atomic volume in liquid Al–Fe and Al–Ni binary alloys
- Identification of liquid/solid transformations in eutectic Pb–Sn alloy
- Cyclic deformation behaviour and lifetime calculation of the magnesium die-cast alloys AZ91D, MRI 153M and MRI 230D
- Applied
- Superplastic deformation behavior of a spray-deposited eutectic NiAl/Cr(Mo) alloy doped with Dy
- Fracture behavior of overmatched ductile iron weldment
- Design of carbide-free low-temperature ultra high strength bainitic steels
- The influence of orientation and aluminium content on the deformation mechanisms of Hadfield steel single crystals
- Effect of tempering on the microstructure and hardness of ledeburitic chromium steel X155CrVMo12.1
- Notifications
- DGM News