Startseite Effects of various vitamin C amounts on the green synthesis of reduced graphene oxide
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Effects of various vitamin C amounts on the green synthesis of reduced graphene oxide

  • Ferda Mindivan und Meryem Göktaş
Veröffentlicht/Copyright: 26. September 2019
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Abstract

In this study, a simple and green chemistry approach is described for the preparation of reduced graphene oxide (RGO). To this aim, we used a novel reducing agent (vitamin C) for the synthesis of RGO. The GO was reduced at different weight ratios of vitamin C:GO (1:1, 1.5:1 and 2:1). The XRD, FTIR and EDS results showed the deoxygenation of GO due to the loss of hydroxyl, carbonyl, and epoxy groups. The thermal stability of the GO was lower than those of all the RGO powders, and the BET surface area of the GO was much lower than those of all the RGO powders. The results showed that the structural and thermal properties of RGO powders depend on the ratio of vitamin C:GO. When the ratio is 1:1, the RGO powder has the best thermal stability, and the highest BET surface area (m2g−1) was found to be a 2:1 ratio.


Correspondence Address, Assist. Prof. Dr. Ferda Mindivan, Faculty of Engineering, Dept.of Bioengineering & Biotechnology, Application and Research Centre, Bilecik Şeyh Edebali University, 11230, Bilecik, Turkey, E-mail:

Assistant Prof. Dr. Ferda Mindivan, born in 1983, graduated from Ataturk University, Erzurum, Turkey, Department of Chemistry, in 2005. After receiving her PhD degree from the same university in the field of Physical Chemistry in 2013, she is continuing her professional career as Assistant Professor at the Biotechnology Application and Research Center, Bilecik S. E. University, Bilecik, Turkey. Her main research interests include polymer matrix composites and their structural, thermal and mechanical characterization.

Meryem Göktaş, born 1982, received her BSc degree in Mining Engineering from Inönü University, Malatya, Turkey in 2003, and her MSc degree in Mining Engineering from Dokuz Eylül University, Izmir, Turkey in 2007, as well as her PhD degree in Mining Engineering from Inönü University, Malatya, Turkey in 2013. Since 2017, she has been working as Assistant Professor in the Metallurgy Department at Bilecik S. E. University, Bilecik, Turkey. Her main research interests include physicochemical operations and mechanochemical processes in mineral engineering, polymer matrix composites and their structural, thermal and mechanical characterization.


References

1 S.Pei, H.-M.Cheng: The Reduction of graphene oxide, Carbon50 (2012), pp. 3210322810.1016/j.carbon.2011.11.010Suche in Google Scholar

2 Y.Jin, S.Huang, M.Zhang, M.Jia, D.Hu: A green and efficient method to produce graphene for electrochemical capacitors from graphene oxide using sodium carbonate as a reducing agent, Applied Surface Science268 (2013), pp. 54154610.1016/j.apsusc.2013.01.004Suche in Google Scholar

3 S.Stankovich, D. A.Dikin, R. D.Piner, K. A.Kohlhaas, A.Kleinhammes, Y.Jia, Y.Wu, S. T.Nguyen, R. S.Ruoff: Synthesis of graphene-based nano sheets via chemical reduction of exfoliated graphite oxide, Carbon45 (2007), pp. 1558156510.1016/j.carbon.2007.02.034Suche in Google Scholar

4 S.Schöch, N.Hong, M.Khorasaninejad, A.Ambrosio, E.Orabona, P.Maddalena, F.Capasso: Optical properties of graphene oxide and reduced graphene oxide determined by spectroscopic ellipsometry, Applied Surface Science421 (2017), pp. 77878210.1016/j.apsusc.2017.01.035Suche in Google Scholar

5 H.Yu, B.Zhang, C.Bulin, R.Li, R.Xing: High-efficient synthesis of graphene oxide based on improved hummers method, Scientific Reports6 (2016), pp. 1610.1038/srep36143Suche in Google Scholar PubMed PubMed Central

6 L.Ju, Y.Dai, W.Wei, M.Li, C.Jin, B.Huang: Theoretical study on the photo catalytic properties of graphene oxide with single Au atom adsorption, Surface Science669 (2018), pp. 7178, 10.1016/j.susc.2017.11.012Suche in Google Scholar

7 L. Q.Xu, Y. B.Liao, N. N.Li, Y. J.Li, J. Y.Zhang, Y. B.Wang, X. F.Hu, C. M.Li: Vancomycin-assisted green synthesis of reduced graphene oxide for antimicrobial applications, Journal of Colloid and Interface Science514 (2018), pp. 73373910.1016/j.jcis.2018.01.014Suche in Google Scholar PubMed

8 S.Park, J.An, J. R.Potts, A.Velamakanni, S.Murali, R. S.Ruoff: Hydrazine-reduction of graphite- and graphene oxide, Carbon49 (2011), pp. 3019302310.1016/j.carbon.2011.02.071Suche in Google Scholar

9 L.Stobinski, B.Lesiak, A.Malolepszy, M.Mazurkiewicz, B.Mierzwa, J.Zemek, P.Jiricek, I.Bieloshapka: Graphene oxide and reduced graphene oxide studied by the XRD, TEM and electron spectroscopy methods, Journal of Electron Spectroscopy and Related Phenomena195 (2014), pp. 14515410.1016/j.elspec.2014.07.003Suche in Google Scholar

10 D. N. H.Tran, S.Kabiri, D.Losic: A green approach for the reduction of graphene oxide nanosheets using non-aromatic amino acids, Carbon76 (2014), pp. 19320210.1016/j.carbon.2014.04.067Suche in Google Scholar

11 S.Thakur, N.Karak: Green reduction of graphene oxide by aqueous phytoextracts, Carbon50 (2012), pp. 5331533910.1016/j.carbon.2012.07.023Suche in Google Scholar

12 Y.Liu, Y.Zhang, G.Ma, Z.Wang, K.Liu, H.Liu: Ethylene glycol reduced graphene oxide/polypyrrole composite for supercapacitor, Electrochimica Acta88 (2013), pp. 51952510.1016/j.electacta.2012.10.082Suche in Google Scholar

13 M. J.Fernandez-Merino, L.Guardia, J. I.Paredes, S.Villar-Rodil, P.Solís-Fernández, A.Martínez-Alonso, J. M. D.Tascón: Vitamin C is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions, The Journal of Physical Chemistry C114 (2010), pp. 6426643210.1021/jp100603hSuche in Google Scholar

14 A. I.Kamisan, A.-S.Kamisan, R. Md.Ali, T. I.Tunku Kudin, O. H.Hassan, N. A.Halim, M. Z. A.Yahya: Synthesis of graphene via green reduction of graphene oxide with simple sugars, Advanced Materials Research1107 (2015), pp. 54254610.4028/www.scientific.net/AMR.1107.542Suche in Google Scholar

15 Y.Wang, Z.Shi, J.Yin: Facile synthesis of soluble graphene via a green reduction of graphene oxide in tea solution and its biocomposites, American Chemical Society Applied Materials and Interfaces3 (2011), pp. 1127113310.1021/am1012613Suche in Google Scholar PubMed

16 Y.Guo, X.Sun, Y.Liu, W.Wang, H.Qiu, J.Gao: One pot preparation of reduced graphene oxide (RGO) or Au (Ag) nanoparticle-RGO hybrids using chitosan as a reducing and stabilizing agent and their use in methanol electrooxidation, Carbon50 (2012), pp. 2513252310.1016/j.carbon.2012.01.074Suche in Google Scholar

17 W. S.Hummers, R. E.Offeman: Preparation of graphitic oxide, Journal of the American Chemical Society80 (1958), pp. 133910.1021/ja01539a017Suche in Google Scholar

18 F.Mindivan: Effect of various initial concentrations of CTAB on the noncovalent modified graphene oxide (MGNO) structure and thermal stability, Materials Testing59 (2017), No. 9, pp. 72973410.3139/120.111063Suche in Google Scholar

19 A.Romero, M. P.Lavin-Lopez, L.Sanchez-Silva, J. L.Valverde, A.Paton-Carrero: Comparative study of different scalable routes to synthesize graphene oxide and reduced graphene oxide, Materials Chemistry and Physics203 (2018), pp. 28429210.1016/j.matchemphys.2017.10.013Suche in Google Scholar

20 C.Bora, P.Bharali, S.Baglari, S. K.Dolui, B. K.Konwar: Strong and conductive reduced graphene oxide/polyester resin composite films with improved mechanical strength, thermal stability and its antibacterial activity, Composites Science and Technology87 (2013), pp. 1710.1016/j.compscitech.2013.07.025Suche in Google Scholar

21 J.Hu, X.Jia, C.Li, Z.Ma, G.Zhang, W.Sheng, X.Zhang, Z.Wei: Effect of interfacial interaction between graphene oxide derivatives and poly (vinylchloride) upon the mechanical properties of their nanocomposites, Journal of Materials Science49 (2014), pp. 2943295110.1007/s10853-013-8006-1Suche in Google Scholar

22 H.Saleem, M.Haneef, H. Y.Abbasi: Synthesis route of reduced graphene oxide via thermal reduction of chemically exfoliated graphene oxide, Materials Chemistry and Physics204 (2018), pp. 1710.1016/j.matchemphys.2017.10.020Suche in Google Scholar

23 S.Chowdhury, R.Balasubramanian: Recent advances in the use of graphene-family nanoadsorbents for removal of toxic pollutants from wastewater, Advances in Colloid and Interface Science204 (2014), pp. 355610.1016/j.cis.2013.12.005Suche in Google Scholar PubMed

24 V.Singh, D.Joung, L.Zhai, S.Das, S. I.Khondaker, S.Seal: Graphene based materials: Past, present and future, Progress in Materials Science56 (2011), pp. 1178127110.1016/j.pmatsci.2011.03.003Suche in Google Scholar

25 R.Castaldo, G. C.Lama, P.Aprea, G.Gentile, M.Lavorgna, V.Ambrogi, P.Cerruti: Effect of the oxidation degree on self-assembly, adsorption and barrier properties of nano-graphene, Microporous and Mesoporous Materials260 (2018), pp. 10211510.1016/j.micromeso.2017.10.026Suche in Google Scholar

26 L.Yu, L.Wang, W.Xu, L.Chen, M.Fu, J.Wu and D.Ye, Adsorption of VOCs on Reduced Graphene Oxide, Journal of Environmental Sciences67 (2018), pp. 17117810.1016/j.jes.2017.08.022Suche in Google Scholar PubMed

27 J.Yao, S.Yao, F.Gao, L.Duan, M.Niu, J.Liu: Reduced graphene oxide/Mn3O4 nanohybrid for high-rate pseduocapacitive electrodes, Journal of Colloid and Interface Science511 (2018), pp. 43443910.1016/j.jcis.2017.10.031Suche in Google Scholar PubMed

28 K.Chang, X.Li, Q.Liao, B.Hu, J.Hu, G.Sheng, W.Linghu, Y.Huang, A. M.Asiri, K. A.Alamry: Molecular insights into the role of fulvic acid in cobalt sorption onto graphene oxide and reduced graphene oxide, Chemical Engineering Journal327 (2017), pp. 32032710.1016/j.cej.2017.06.100Suche in Google Scholar

29 L.Lu, J.Wang, B.Chen: Adsorption and desorption of phthalic acid esters on graphene oxide and reduced graphene oxide as affected by humic acid, Environmental Pollution232 (2018), pp. 50551310.1016/j.envpol.2017.09.078Suche in Google Scholar PubMed

30 M. P.Lavin-Lopez, A.Paton-Carrero, L.Sanchez-Silva, J. L.Valverde, A.Romero: Influence of the reduction strategy in the synthesis of reduced graphene oxide, Advanced Powder Technology28 (2017), pp. 3195320310.1016/j.apt.2017.09.032Suche in Google Scholar

31 D. C.Marcano, D. V.Kosynkin, J. M.Berlin, A.Sinitskii, Z.Sun, A.Slesarev, L. B.Alemany, W.Lu, J. M.Tour: Improved synthesis of graphene oxide, American Chemical Society Nano8 (2010), No. 4, pp. 4806481410.1021/nn1006368Suche in Google Scholar PubMed

32 H.Liu, L.Hou, W.Peng, Q.Zhang, X.Zhang: Fabrication and characterization of polyamide 6-functionalized graphene nanocomposite fiber, Journal of Materials Science47 (2012), pp. 8052806010.1007/s10853-012-6695-5Suche in Google Scholar

Published Online: 2019-09-26
Published in Print: 2019-10-02

© 2019, Carl Hanser Verlag, München

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