Corrosion inhibition of steel in a sodium chloride solution by natural honey

Veselinka Grudić; Sanja Martinez; Bojana Knežević; Ivana Bošković

doi:10.3139/120.111398

Artikel

Corrosion inhibition of steel in a sodium chloride solution by natural honey

Veselinka Grudić , Sanja Martinez , Bojana Knežević und Ivana Bošković

Veröffentlicht/Copyright: 30. August 2019

Veröffentlicht von

Veröffentlichen auch Sie bei De Gruyter Brill

Manuskript einreichen Informationen für Autor*innen

Aus der Zeitschrift Materials Testing Band 61 Heft 9

Abstract

This paper studies the corrosion inhibition of carbon steel in a 0.51 mol × dm⁻³ sodium chloride solution in the presence of honey. The tests were carried out using the potentiodynamic polarization method, scanning electronic spectroscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and Fourier-transform infrared spectroscopy (FTIR). Electrochemical parameters which indicate the corrosion behavior of the steel in the sodium chloride solution in the absence and in presence of honey were calculated based on the experimental results. It was shown that honey acts as a mixed corrosion inhibitor whose efficiency increases with an increasing concentration. The maximum efficiency of inhibition (77.68 %) was maintained through a 1200 ppm concentration of honey. The adsorption of the tested inhibitor is described by Langmuir's isotherm, and the calculated value of free adsorption energy indicates the physical adsorption of the organic components of honey on the steel surface. The results of the SEM, FTIR and EDX analysis show that the honey covers the steel surface and prevents the influence of the aggressive medium.

∗Correspondence Address, XAssoc. Prof. Dr. Ivana Bošković, Faculty of Metallurgy and Technology, Cetinjski put Street, University of Montenegro, 81000 Podgorica, Montenegro, E-mail: ivabo@ucg.ac.me

Dr. Veselinka Grudić, born in 1972, is Associate Professor at the Faculty of Metallurgy and Technology, Podgorica, Montenegro with an expertise in electrochemistry. She studied Metallurgy and Technology at the same Faculty from 1990 to 1995, finishing her postgraduate studies at the Faculty of Physical Chemistry, Belgrade in 1999 and receiving her PhD degree in 2004 at the Faculty of Physical Chemistry, Belgrade, Serbia.

Dr. Sanja Martinez is a Full Professor at the Faculty of Chemical Engineering and Technology, University of Zagreb, Croatia, with an expertise in Chemical Engineering, Analytical Chemistry, Biochemistry.

Bojana Knežević, born in 1993, has a Master's degree in Engineering. She studied at the Faculty of Metallurgy and Technology, Podgorica, Montenegro from 2012 to 2016 and finished her postgraduate studies in 2017 at the Faculty of Metallurgy and Technology, Podgorica, Montenegro.

Ivana Bošković, born in 1971, is Associate Professor at the Faculty of Metallurgy and Technology, Podgorica, Montenegro with an expertise in physical chemistry. She studied Chemical Technology at the same Faculty from 1990 to 1995 and completed her postgraduate studies at the Faculty of Physical Chemistry, Belgrade, in 1999 and received her PhD degree in 2006 at the Faculty of Physical Chemistry, Belgrade, Serbia,

References

1 A. Y.El-Etre: Natural honey as corrosion inhibitor for metals and alloys I. Copper in neutral aqueous solution, Corrosion Science40 (1998), No. 11, pp. 1845–185010.1016/S0010-938X(98)00082-1Suche in Google Scholar

2 A. A.Rahim, E.Rocca, J.Steinmetz, M. J.Kassim, R.Adnan, M. SaniIbrahim: Mangrove tannins and their flavanoid monomers as alternative steel corrosion inhibitors in acidic medium, Corrosion. Science49 (2007), No. 2, pp. 402–41710.1016/j.corsci.2006.04.013Suche in Google Scholar

3 A. Y.El-Etre: Inhibition of acid corrosion of aluminum using vanillin, Corrosion Science43 (2001), No. 6, pp. 1031–103910.1016/S0010-938X(00)00127-XSuche in Google Scholar

4 A. Y.El-Etre: Inhibition of aluminum corrosion using Opuntia extract, Corrosion Science45 (2003), No. 11, pp. 2485–249510.1016/S0010-938X(03)00066-0Suche in Google Scholar

5 A. M.Abdel-Gaber, B. A.Abd-El-Nabey, I. M.Sidahmed, A. M.El-Zayady, M.Saadawy: Inhibitive action of some plant extracts on the corrosion of steel in acidic media, Corrosion Science48 (2006), No. 9, pp. 2765–277910.1016/j.corsci.2005.09.017Suche in Google Scholar

6 I.Radojčić, K.Berković, S.Kovač, J.Vorkapić-Furač: Natural honey and black radish juice as tin corrosion inhibitors, Corrosion Science50 (2008), No. 5, pp. 1498–150410.1016/j.corsci.2008.01.013Suche in Google Scholar

7 L.Vrsalović, S.Gudić, M.Kliškić: Salvia officinalis L. honey as corrosion inhibitor for CuNiFe alloy in sodium chloride solution, Indian Journal of Chemical Technology19 (2012), pp. 96–102Suche in Google Scholar

8 W. B.Wan Nik, M. F.Zulkifli, R.Rosliza, M. J.Ghazali, K. F.Khaled: Potential of honey as corrosion inhibitor for aluminium alloy in seawater, World Applied Science Journal14 (2011), No. 2, pp. 215–220Suche in Google Scholar

9 S.Gudić, L.Vrsalović, M.Kliškić, I.Jerković, A.Radonić, M.Zekić: Corrosion inhibition of AA 5052 aluminium alloy in NaCl solution by different types of honey, International Journal of Electrochemical Science11 (2016), pp. 998–1011Suche in Google Scholar

10 H.Otmačić Curkovic, E.Stupnisek-Lisac, H.Takenouti: The influence of pH value on the efficiency of imidazole based corrosion inhibitors of copper, Corrosion Science52 (2010), No. 2, pp. 398–40510.1016/j.corsci.2009.09.026Suche in Google Scholar

11 F. G.Liu, M.Du, J.Zhang, M.Qiu: Electrochemical behavior of Q235 steel in saltwater saturated with carbon dioxide based on new imidazoline derivative inhibitor, Corrosion Science51 (2009), pp. 102–10910.1016/j.corsci.2008.09.036Suche in Google Scholar

12 Z.Wang: The inhibition effect of bis-benzimidazole compound for mild steel in 0.5 M HCl solution, International Journal of Electrochemical Science7 (2012), pp. 11149–11160Suche in Google Scholar

13 R. F. V.Villamil, P.Corio, J. C.Rubim, S. M. L.Agostinho: Effect of sodium dodecylsulfate on copper corrosion in sulfuric acid media in the absence and presence of benzotiazole. Journal of Electroanalytical Chemistry472 (1999), No. 2 pp. 112–11910.1016/S0022-0728(99)00267-3Suche in Google Scholar

14 E. E.Oguzie, B. N.Okolue, E. E.Ebenso, G. N.Onuoha, A. I.Onuchukwu: Evaluation of the inhibitory effect of methylene blue dye on the corrosion of aluminium in HCl, Materials Chemical and Physics87 (2004), pp. 394–40110.1016/j.matchemphys.2004.06.003Suche in Google Scholar

15 S. A.Umoren, Y.Li, F. H.Wang: Electrochemical study of corrosion inhibition and adsorption behavior for pure iron by polyacrylamide in H₂SO₄: Synergistic effect of iodide ions, Corrosion Science52 (2010), pp. 1777–178610.1016/j.corsci.2010.01.026Suche in Google Scholar

16 A. Y.El-Etre: Inhibition of acid corrosion of carbon steel using aqueous extract of olive leaves, Colloid Interface Science314 (2007), pp. 578–583, 10.1016/j.jcis.2007.05.077Suche in Google Scholar PubMed

17 R. M.Cornell, U.Schwertmann: The Iron-Oxides-Structure, Properties, Reactions, Occurences and Uses, Springer, Berlin (1996)Suche in Google Scholar

18 S.Hosseinpour, M.Johnson: Vibrational spectroscopy in studies of atmospheric corrosion, Materials10 (2017), No. 1, pp. 413–45010.3390/ma10040413Suche in Google Scholar PubMed PubMed Central

19 R.Jasinski, A.Lob: FTIR measurements of iron oxides on low alloy steel, Journal of Electrochemical Society135 (1988), No. 3, pp. 551–55610.1149/1.2095656Suche in Google Scholar

20 A. L.Andrade, D. M.Souza, M. C.Pereira, J. D.Fabris, R. Z.Domingues: Synthesis and characterization of magnetic nanoparticles coated with silica through a sol-gel approach, Cerâmica55 (2009), No. 336, pp. 420–42410.1590/S0366-69132009000400004Suche in Google Scholar

Published Online: 2019-08-30

Published in Print: 2019-08-30

Sie haben derzeit keinen Zugang zu diesem Inhalt.

Artikel in diesem Heft

https://doi.org/10.3139/120.111398