Fluorescence Study of Aggregation Behaviour of Cationic Surfactant Carbethopendecinium Bromide and its Comparison with Cetyltrimethylammonium Bromide
-
Petra Holínková
and Miloslav Pekař
Abstract
The aggregation behaviour of the cationic surfactant carbethopendecinium bromide (Septonex) and cetyltrimethylammonium bromide (CTAB) in aqueous solution was investigated by steady-state and time-resolved fluorescence experiments. Values of critical micelle concentration were obtained from the pyrene emission polarity index. The micellar aggregation numbers for four different concentrations of both surfactants were determined by steady-state and time-resolved fluorescence quenching methods, using pyrene as a probe and cetylpyridinium chloride as a quencher. The results obtained for Septonex were compared with the aggregation parameters of CTAB. Generally, Septonex micelles were formed by a smaller number of surfactant monomers than in the case of CTAB and the critical micelle concentration of Septonex is lower than that of CTAB. Also, the concentration dependence of the micelle aggregation number was found.
Kurzfassung
Das Aggregationsverhalten des kationischen Tensids Carbethopendeciniumbromid (Septonex) und Cetyltrimethylammoniumbromid (CTAB) in wässriger Lösung wurde in stationären und zeitaufgelösten Fluoreszenzexperimenten untersucht. Die Werte der kritischen Mizellenbildungskonzentration wurden aus dem Pyrenemissionspolaritätsindex erhalten. Die mizellaren Aggregationszahlen für vier verschiedene Konzentrationen der beiden Tenside wurden durch ein stationäres und zeitaufgelöstes Fluoreszenzlöschverfahren unter Verwendung von Pyren als Sonde und Cetylpyridiniumchlorid als Quencher bestimmt. Die für Septonex erhaltenen Ergebnisse wurden mit den Aggregationsparametern von CTAB verglichen. Im Allgemeinen wurden Septonex-Mizellen durch eine geringere Anzahl von Tensidmonomeren gebildet als im Fall von CTAB und die kritische Mizellenbildungskonzentration von Septonex ist niedriger als die von CTAB. Auch die Konzentrationsabhängigkeit der Mizellenaggregationszahl wurde gefunden.
References
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© 2019, Carl Hanser Publisher, Munich
Articles in the same Issue
- Contents/Inhalt
- Contents
- Review Article
- Review on Silicone Surfactants: Silicone-based Gemini Surfactants, Physicochemical Properties and Applications
- Cleaning Agents
- Evaluation of Ethoxylated Rapeseed Oil Fatty Acids Methyl Esters as Nonionic Co-Surfactants in Hand Dishwashing Liquids
- Evaluation of the Bactericidal Activity of Didecyl Dimethyl Ammonium Chloride in 2-Propanol against Pseudomonas aeruginosa Strains with Adaptive Resistance to this Active Substance According to European Standards
- Environmental Chemistry
- Production of Bioemulsifier by Yeast from the Meyerozyma guilliermondii Complex Isolated from Soil Contaminated with Diesel Oil
- Physical Chemistry
- Fluorescence Study of Aggregation Behaviour of Cationic Surfactant Carbethopendecinium Bromide and its Comparison with Cetyltrimethylammonium Bromide
- Wettability of Phosphonium Benzene Sulfonate on Parafilm
- Study of Zinc-glycylglycine Complex with Ninhydrin in Aqueous and Cationic Micellar Media: A Spectrophotometric Technique
- Study on a Class of Cationic Gemini Surfactants
- Application
- The Performance Comparison Of Branched Methyl Stearate Ethoxylate and Linear Methyl Stearate Ethoxylate
- Study of the Rheological Behavior of a Spent Solution of Viscoelastic Surfactant in the Presence of Iron Ions
- Micellar Catalysis
- Synthesis of 2-(Prop-2-ynyloxy) Benzaldehyde using Salicyl Aldehyde and Propargyl Bromide in Aqueous Micellar Media
- Novel Surfactant
- Synthesis and Properties of Amphoteric Amide Surfactants with Reactive Group
Articles in the same Issue
- Contents/Inhalt
- Contents
- Review Article
- Review on Silicone Surfactants: Silicone-based Gemini Surfactants, Physicochemical Properties and Applications
- Cleaning Agents
- Evaluation of Ethoxylated Rapeseed Oil Fatty Acids Methyl Esters as Nonionic Co-Surfactants in Hand Dishwashing Liquids
- Evaluation of the Bactericidal Activity of Didecyl Dimethyl Ammonium Chloride in 2-Propanol against Pseudomonas aeruginosa Strains with Adaptive Resistance to this Active Substance According to European Standards
- Environmental Chemistry
- Production of Bioemulsifier by Yeast from the Meyerozyma guilliermondii Complex Isolated from Soil Contaminated with Diesel Oil
- Physical Chemistry
- Fluorescence Study of Aggregation Behaviour of Cationic Surfactant Carbethopendecinium Bromide and its Comparison with Cetyltrimethylammonium Bromide
- Wettability of Phosphonium Benzene Sulfonate on Parafilm
- Study of Zinc-glycylglycine Complex with Ninhydrin in Aqueous and Cationic Micellar Media: A Spectrophotometric Technique
- Study on a Class of Cationic Gemini Surfactants
- Application
- The Performance Comparison Of Branched Methyl Stearate Ethoxylate and Linear Methyl Stearate Ethoxylate
- Study of the Rheological Behavior of a Spent Solution of Viscoelastic Surfactant in the Presence of Iron Ions
- Micellar Catalysis
- Synthesis of 2-(Prop-2-ynyloxy) Benzaldehyde using Salicyl Aldehyde and Propargyl Bromide in Aqueous Micellar Media
- Novel Surfactant
- Synthesis and Properties of Amphoteric Amide Surfactants with Reactive Group