Surface-Active Properties of a Trimeric Sulfate-type Surfactant Derived from Glycerol
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Fan Liu
Abstract
A trimeric sulfate-type surfactant was synthesized and the surface chemical properties and micellar behavior of this surfactant were investigated by surface tension and fluorescence measurements. The critical micelle concentration (CMC) and the surface tension at CMC both decreased with the increase of NaCl concentration. The thermodynamic parameters indicate that the micelle formation is entropy-driven. The micelle aggregation number was determined and changed little between 303 K and 313 K. All the experimental results show that the surface-active properties of the surfactant are insensitive to the temperature compared with conventional surfactants.
Kurzfassung
Ein trimeres Sulfattensid wurde synthetisiert und die Oberflächeneigenschaften und das mizellare Verhalten dieses Tensids wurden mittels Messung der Oberflächenspannung und der Fluoreszenz bestimmt. Die kritische Mizellenbildungskonzentration (CMC) und die Oberflächenspannung bei der CMC werden mit zunehmender NaCl-Konzentration reduziert. Die thermodynamischen Parameter zeigen, dass die Mizellenbildung von der Entropie gesteuert wird. Die Mizellenaggregationszahl wurde bestimmt und änderte sich zwischen 303 K und 313 K nur wenig. Alle experimentellen Ergebnisse zeigen, dass die oberflächenaktiven Eigenschaften des Tensids im Vergleich zu konventionellen Tensiden temperaturunempfindlich sind.
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© 2016, Carl Hanser Publisher, Munich
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Physical Chemistry
- Surface-Active Properties of a Trimeric Sulfate-type Surfactant Derived from Glycerol
- Interface Activity and Thermodynamic Properties of Cardanol Polyoxyethylene Ether Carboxylates
- Synthesis and Properties of Dioctyl Diphenyl Ether Disulfonate Gemini Surfactant
- Synthesis and Biological Activity of Alkyl Pyridinium Aldoxime Based Surfactants
- Application
- Enhanced Soil Remediation via Plant-Based Surfactant Compounds from Acanthophyllum Laxiusculum
- Micellar Catalysis
- Picolinic Acid Promoted Permanganate Oxidation of D-Mannitol in Micellar Medium
- Micelle Catalyzed Oxidative Degradation of Paracetamol by Water Soluble Colloidal MnO2 in Acidic Medium
- Corrosion Inhibition
- Adsorption and Corrosion Inhibition Behaviour of Zwitterionic Gemini Surfactant for Mild Steel in 0.5 M HCl
- Laundry/Cleaning Agents
- Effect of the Concentration of Hop Cone Extract on the Antibacterial, Physico-Chemical and Functional Properties of Adhesive Toilet Cleaners
- Laundry Performance: Effect of Detergent and Additives on Consumer Satisfaction
- Deposition of Solid Impurity During Washing of Softented Cotton in Function of the Mixtures of Surfactants
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Physical Chemistry
- Surface-Active Properties of a Trimeric Sulfate-type Surfactant Derived from Glycerol
- Interface Activity and Thermodynamic Properties of Cardanol Polyoxyethylene Ether Carboxylates
- Synthesis and Properties of Dioctyl Diphenyl Ether Disulfonate Gemini Surfactant
- Synthesis and Biological Activity of Alkyl Pyridinium Aldoxime Based Surfactants
- Application
- Enhanced Soil Remediation via Plant-Based Surfactant Compounds from Acanthophyllum Laxiusculum
- Micellar Catalysis
- Picolinic Acid Promoted Permanganate Oxidation of D-Mannitol in Micellar Medium
- Micelle Catalyzed Oxidative Degradation of Paracetamol by Water Soluble Colloidal MnO2 in Acidic Medium
- Corrosion Inhibition
- Adsorption and Corrosion Inhibition Behaviour of Zwitterionic Gemini Surfactant for Mild Steel in 0.5 M HCl
- Laundry/Cleaning Agents
- Effect of the Concentration of Hop Cone Extract on the Antibacterial, Physico-Chemical and Functional Properties of Adhesive Toilet Cleaners
- Laundry Performance: Effect of Detergent and Additives on Consumer Satisfaction
- Deposition of Solid Impurity During Washing of Softented Cotton in Function of the Mixtures of Surfactants
