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Combination of Best Promoter and Micellar Catalyst for Cr(VI) Oxidation of Lactose to Lactobionic Acid in Aqueous Medium at Room Temperature

  • Susanta Malik , Aniruddha Ghosh , Kakali Mukherjee and Bidyut Saha
Published/Copyright: July 22, 2014
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 51 Issue 4

Abstract

In aqueous acidic media, picolinic acid, 2,3-dipicolinic acid, and 2,6-dipicolinic acid promoted Cr(VI) oxidation of lactose to lactobionic acid has been carried out at room temperature. A possible reaction mechanism, which is based on the kinetic results and the product analysis, has been proposed. The anionic surfactant sodium dodecyl sulphate (SDS) and nonionic surfactant Triton-X-100 (TX-100) accelerate the process while the cationic surfactant N-cetylpyridinium chloride (CPC) retards the reaction.

Kurzfassung

Die von Picolinsäure, 2,3-Dipicolinsäure und von 2,6-Dipicolinsäure im wässrigen, saurem Medium begünstigte Cr(VI)-Oxidation von Laktose zur Laktobionsäure wurde bei Raum temperatur durchgeführt. Es wurde ein möglicher Reaktions mechanismus auf Basis der kinetischen Ergebnisse und der Produktanalyse vorgeschlagen. Das anionische Tensid Natriumdodecylsulfat (SDS) und das nichtionische Tensid Triton-X-100 (TX-100) beschleunigen den Vorgang, während das kationische Tensid N-Cetylpyridiniumchlorid (CPC) die Reaktion verzögert.

Key words: Picolinic acid; lactose; lactobionic acid; Cr(VI); surfactant
Stichwörter: Picolinsäure; Laktose; Laktobionsäure; Cr(VI); Tensid
* Correspondence address Mr. Prof. Bidyut Saha, Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan, Golapbag, Burdwan, Pin 713104, WB, India, Mobile: +919476341691, Tel.: +91-342-2533913 (O), Fax: +91-342-2530452 (O), E-Mail:

Susanta Malik: He was born in Kalna, Burdwan in 1988. He passed his M.Sc degree from the University of Burdwan in 2011 and got UGC-RGNF fellowship on the year 2012. He is working in my lab in “Bio-remediation” division.

Aniruddha Ghosh: He was born in Raniganj, in 1988. He passed his M.Sc degree from the University of Burdwan in 2010 and got NET-UGC fellowship on the year 2010. He is working in my lab in “Bio-remediation” division.

Kakali Mukherjee: She was born in Bankura, in 1988. She passed her M.Sc degree from the University of Burdwan in 2011 and got NET-LS fellowship on the year 2010. She is working in my lab in “Bio-remediation” division.

Dr. Bidyut Saha: He was born in Birbhum, WB, India in 1975. He obtained his Ph.D degree from Visva Bharati University, India in 2007. He was a visiting scientist for the year 2009–2010 in the Department of Chemistry, UBC, Canada. Dr. Saha is presently working as an Assistant Professor in the Department of Chemistry, Burdwan University, India. His area of interests is bioremediation of toxic metal, micellar catalysis and inorganic reaction mechanism. He has already published thirty papers in international journals.

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Received: 2014-02-03
Revised: 2014-05-07
Published Online: 2014-07-22
Published in Print: 2014-07-15

© 2014, Carl Hanser Publisher, Munich

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Inactivation of Human Norovirus by Common Domestic Laundry Procedures
  7. Dispersion of Bioactive Glass using Cetyltrimethylammonium Bromide
  8. Novel/“Green” Surfactants
  9. Amphiphilic Choline Carboxylates as Demulsifiers of Water-in-Crude Oil Emulsions
  10. Synthesis and Antitumor and Surface Activity of Novel Tetrachloro Metallate Complexes of Sulfaquinoxaline with Co(II), Cu(II), or Sn(II) Chlorides
  11. Micellar Chemistry
  12. Combination of Best Promoter and Micellar Catalyst for Cr(VI) Oxidation of Lactose to Lactobionic Acid in Aqueous Medium at Room Temperature
  13. Physical Chemistry
  14. Cloud Point Extraction of Polycyclic Aromatic Hydrocarbons in Aqueous Solution with Nonionic Surfactants
  15. Influence of Alcohols on Micellar and Release Balances of Cationic Surfactant – Carbethopendecinium Bromide (Septonex)
  16. Synthesis
  17. Synthesis and Characterization of Series of Soft-Template Agents for Mesoporous Materials
  18. The Role of Surface Active Agents in Sulfonation of Double Bonds
https://doi.org/10.3139/113.110314
Keywords for this article
Picolinic acid; lactose; lactobionic acid; Cr(VI); surfactant

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Inactivation of Human Norovirus by Common Domestic Laundry Procedures
  7. Dispersion of Bioactive Glass using Cetyltrimethylammonium Bromide
  8. Novel/“Green” Surfactants
  9. Amphiphilic Choline Carboxylates as Demulsifiers of Water-in-Crude Oil Emulsions
  10. Synthesis and Antitumor and Surface Activity of Novel Tetrachloro Metallate Complexes of Sulfaquinoxaline with Co(II), Cu(II), or Sn(II) Chlorides
  11. Micellar Chemistry
  12. Combination of Best Promoter and Micellar Catalyst for Cr(VI) Oxidation of Lactose to Lactobionic Acid in Aqueous Medium at Room Temperature
  13. Physical Chemistry
  14. Cloud Point Extraction of Polycyclic Aromatic Hydrocarbons in Aqueous Solution with Nonionic Surfactants
  15. Influence of Alcohols on Micellar and Release Balances of Cationic Surfactant – Carbethopendecinium Bromide (Septonex)
  16. Synthesis
  17. Synthesis and Characterization of Series of Soft-Template Agents for Mesoporous Materials
  18. The Role of Surface Active Agents in Sulfonation of Double Bonds
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