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Interactions between Dyes and Cetyl-trimethyl Ammonium Bromide

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Published/Copyright: April 11, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 48 Issue 3

Abstract

Surfactants have been widely used as auxiliaries in many areas of textile finishing. The nature of the interactions between dyes and surfactants is one of the basic piece of information for understanding the process of dyeing and finishing of textile material. The role of attractive interactions between the hydrocarbon tails and repulsive interactions between the surfactant head groups on the micellar association process have been studied. The presented work is oriented on the determination of the critical micelle concentration and molar conductance, in aqueous solution of cationic surfactant cetyltrimethyl ammonium bromide by using the electric conductivity method. From conductivity data parameters for dyes – surfactant interaction such as micellar ionization degree α, counter ion binding and free energy of micellization have been calculated. On the basis of results it is clear that critical micelle concentration depends on the nature of ionic group and concentration of counter ion in solution.

Kurzfassung

Tenside sind in vielen Bereichen der Textilherstellung als Hilfsmittel weit verbreitet. Die Art der Wechselwirkung zwischen Farbstoffen und Tensiden ist grundlegend für das Verständnis der Färbe- und Finishing-Prozesse von Textilien. Die Rolle der anziehenden Wechselwirkungen zwischen Kohlenwasserstoffketten und abstoßenden Wechselwirkungen zwischen den Kopfgruppen bei der Mizellenbildung wurde untersucht. Im Rahmen dieser Arbeit wurde die kritische Mizellbildungskonzentration (CMC) und die molare Leitfähigkeit wässriger Lösungen mit dem kationischen Cetyltrimethylammoniumbromid mittels der elektrischen Leitfähigkeit bestimmt. Aus den Leitfähigkeitswerten wurden Parameter für die Wechselwirkung von Farbstoff und Tensid berechnet wie z.B. der mizellare Ionisierungsgrad α, Bindungsenergie des Gegenions und die freie Energie der Mizellenbildung. Auf Basis der Ergebnisse wird deutlich, dass die kritische Mizellbildungskonzentration von der Art der ionischen Kopfgruppe und der Konzentration des Gegenions in der Lösung abhängt.

Key words:: Critical micelle concentration (CMC); micelle ionization degree; free energy of micellization; molar conductance; dye; CTAB
Stichwörter:: Kritische Mizellbildungskonzentration (CMC); mizellarer Ionisierungsgrad; freie Energie der Mizellenbildung; molare Leitfähigkeit; Farbstoff; CTAB
∗ Dr. Sangeeta Patil, Department of Applied Chemistry, Rungta College of Engineering & Technology, Bhilai, India, Tel.: +91788-2286476. E-Mail:

Dr. Sangeeta Patil received her M.Sc. in 1994 from RSS University, India, and her M.Phil in 2007 and Ph.D. in 2009 from P. University and K. College. She has been an assistant professor of chemistry in Rungta Engineering College of Engineering and Technology, where she continues her research work, which is mainly related to oxidation, kinetics as well as micellar oxidation kinetics. She is the author of more than 15 international papers related to this field.

Dr. Manisha Agrawal received her M.Sc. in 1994 and Ph.D. from RSS University, India. She has been an assistant professor of chemistry in Rungta Engineering College of Engineering and Technology, where she continues her research work, which is mainly related to synthesis and analysis.

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Received: 2010-08-21
Published Online: 2013-04-11
Published in Print: 2011-05-01

© 2011, Carl Hanser Publisher, Munich

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  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Impact of Surfactants on the Efficacy of Iron Oxide Dispersants
  7. Influence of Surfactants on the Morphologies of CdS Nanorods
  8. Optimization of Parameters for the Preparation of Au/TiO2 with Photodegradation of NPE-10 in Aqueous Solution
  9. Synthesis
  10. Synthesis of Disk-Like and Flower-Like ZnO Nanostructures by Sodium Dodecyl Sulfate-Assisted non-Basic Solution Process
  11. Cleaning Technology
  12. Using Fabric Softeners, Drying and Ironing in Germany
  13. Physical Chemistry
  14. AOT-Vesicles Produced at the Oil-Water Interface
  15. Interactions between Dyes and Cetyl-trimethyl Ammonium Bromide
  16. Effects of Electrolytes on Interfacial and Micelle Properties of C.I. Reactive Orange 16 – Dodecylpyridinium Chloride Binary System
  17. Novel Surfactants
  18. Bis(Diquaternary Ammonium)Salts: Synthesis, Effect of Spacer on Surface Activities and Aggregation Properties of Reactive Red 198 in Aqueous – Surfactants Solutions
  19. Research Group Portrait
  20. Colloid and Interfacial Chemistry at Stuttgart University
https://doi.org/10.3139/113.110126
Keywords for this article
Critical micelle concentration (CMC); micelle ionization degree; free energy of micellization; molar conductance; dye; CTAB

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Impact of Surfactants on the Efficacy of Iron Oxide Dispersants
  7. Influence of Surfactants on the Morphologies of CdS Nanorods
  8. Optimization of Parameters for the Preparation of Au/TiO2 with Photodegradation of NPE-10 in Aqueous Solution
  9. Synthesis
  10. Synthesis of Disk-Like and Flower-Like ZnO Nanostructures by Sodium Dodecyl Sulfate-Assisted non-Basic Solution Process
  11. Cleaning Technology
  12. Using Fabric Softeners, Drying and Ironing in Germany
  13. Physical Chemistry
  14. AOT-Vesicles Produced at the Oil-Water Interface
  15. Interactions between Dyes and Cetyl-trimethyl Ammonium Bromide
  16. Effects of Electrolytes on Interfacial and Micelle Properties of C.I. Reactive Orange 16 – Dodecylpyridinium Chloride Binary System
  17. Novel Surfactants
  18. Bis(Diquaternary Ammonium)Salts: Synthesis, Effect of Spacer on Surface Activities and Aggregation Properties of Reactive Red 198 in Aqueous – Surfactants Solutions
  19. Research Group Portrait
  20. Colloid and Interfacial Chemistry at Stuttgart University
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