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Ordered Ferrocene-containing Mesoporous Materials with Tailor-made Pore Size

  • T. Zhang , P. Gao , C.-G. Gao , H. Yang und Y. Zhao
Veröffentlicht/Copyright: 5. April 2013
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 47 Heft 5

Abstract

Ordered ferrocene-containing mesoporous hybrid materials were prepared by the use of quaternary ammonium surfactants CnH2n+1(CH3)3NBr and organic additives during the hydrothermal synthesis process. The characterization results showed all the materials exhibit an ordered two-dimensional hexagonal pore structure with pore diameter from 2.04 nm to 4.01 nm. It was found that the pore diameter of the materials is strongly dependent on the surfactant chain length and the content of the organic additives. The fourier transform infrared spectra revealed that the organic bridge is preserved during the hydrothermal synthesis and subsequent extraction procedure.

Kurzfassung

Geordnete, Ferrocen enthaltende, mesoporöse Materialien wurden in einem hydrothermalen Prozess aus quaternären Ammoniumtensiden CnH2n+1(CH3)3NBr und organischen Additiven hergestellt. Die Charakterisierung zeigte, dass alle Materialien eine geordnete, zweidimensionale hexagonale Porenstruktur mit einem Porendurchmesser von 2,04 nm bis 4,01 nm aufweisen. Die Porendurchmesser der Materialien sind von der Tensidkettenlänge und dem Gehalt der organischen Additive stark abhängig. Die Fourier-Transform-Infrarot-Spektren machen deutlich, dass die organische Brücke während der hydrothermalen Synthese und der nachfolgenden Extraktion erhalten bleibt.

Key words:: Ferrocene; tailor-made; swelling agents; surfactant
Stichwörter:: Ferrocen; maßgeschneidert; Quellmittel; Tensid
∗ Dr. Yongxiang Zhao, School of Chemistry and Chemical Engineering, Engineering Reseach Center of Ministry of Education for Fine Chemicals, Shanxi University Taiyuan 030006 China, Tel.: 086-351-76011587, Fax: 086-351-76011688. E-Mail:

Tieming Zhang and Pengfei Gao completed their master degrees in Shanxi University in 2006. Now they work on their doctor degrees also in Shanxi University.

Chuanguang Gao completed his master degree and doctor degree in Shanxi University, and now he joined Shanxi University as professor of School of Chemistry and Chemical Engineering.

Hengquan Yang completed his master degree in Wuhan University, then he obtained his doctor and post doctor degrees in Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Now he joined Shanxi University as professor of School of Chemistry and Chemical Engineering.

Yongxiang Zhao was born in 1965. He received his bachelor degree in Shanxi University in 1988. he completed his master and doctor degrees in Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences in 2002. Now, he joined Shanxi University as a professor of School of Chemistry and Chemical Engineering. His current research interests include heterogeneous catalysis and synthesis of porous hybrid materials.

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Received: 2010-05-27
Published Online: 2013-04-05
Published in Print: 2010-09-01

© 2010, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Environmental/Technical Chemistry
  6. Alkyl Polyglycoside-Sorbitan Ester Formulations for Improved Oil Recovery
  7. Novel Surfactants
  8. Photosynthesis-inhibiting Effects of Cationic Biodegradable Gemini Surfactants
  9. Synthesis and Characterization of a New Cationic Galactolipid with Carbamate for Gene Delivery
  10. Physical Chemistry
  11. Dynamics of Formation of Vesicles Studied by Highly Time-resolved Stopped-flow Experiments
  12. Ion Extractant as Cosurfactant at the Water-Oil Interface in Microemulsions
  13. Microemulsions with Mixed Nonionic Surfactants and Isopropylmyristate
  14. Micellization and Interfacial Behaviour of Amitriptyline-Nonionic Surfactant Systems in Aqueous Medium
  15. Synthesis
  16. Ordered Ferrocene-containing Mesoporous Materials with Tailor-made Pore Size
  17. Cleaning Technology
  18. Comparison of Standards for Testing Electrical Dishwashers or Dishwashing Detergents
  19. Manual Dishwashing – How can it be Optimized?
https://doi.org/10.3139/113.110085
Schlagwörter für diesen Artikel
Ferrocene; tailor-made; swelling agents; surfactant

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Environmental/Technical Chemistry
  6. Alkyl Polyglycoside-Sorbitan Ester Formulations for Improved Oil Recovery
  7. Novel Surfactants
  8. Photosynthesis-inhibiting Effects of Cationic Biodegradable Gemini Surfactants
  9. Synthesis and Characterization of a New Cationic Galactolipid with Carbamate for Gene Delivery
  10. Physical Chemistry
  11. Dynamics of Formation of Vesicles Studied by Highly Time-resolved Stopped-flow Experiments
  12. Ion Extractant as Cosurfactant at the Water-Oil Interface in Microemulsions
  13. Microemulsions with Mixed Nonionic Surfactants and Isopropylmyristate
  14. Micellization and Interfacial Behaviour of Amitriptyline-Nonionic Surfactant Systems in Aqueous Medium
  15. Synthesis
  16. Ordered Ferrocene-containing Mesoporous Materials with Tailor-made Pore Size
  17. Cleaning Technology
  18. Comparison of Standards for Testing Electrical Dishwashers or Dishwashing Detergents
  19. Manual Dishwashing – How can it be Optimized?
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