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Dynamics of Formation of Vesicles Studied by Highly Time-resolved Stopped-flow Experiments

  • A. Barth , I. Grillo und M. Gradzielski
Veröffentlicht/Copyright: 5. April 2013
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 47 Heft 5

Abstract

Phase behaviour and static structure of surfactant systems have been studied in much detail, but this applies much less so to their dynamic properties. Structural transitions in amphiphilic systems can be triggered by mixing different amphiphiles. Employing the stopped-flow technique we have studied the kinetics of formation of multilamellar vesicles starting from a micellar solution and a microemulsion containing a semipolar oil. This process has been investigated for various starting conditions and as a function of the charging of the amphiphilic system. The formation process is the faster the closer the starting solution is in composition to the final state and can be slowed down by the presence of ionic surfactant.

Kurzfassung

Phasenverhalten und statische Struktur von Tensidsystemen sind umfassend untersucht worden, aber das gilt sehr viel weniger für ihre dynamischen Eigenschaften. Strukturelle Änderungen amphiphiler Systeme können durch Mischen unterschiedlicher Amphiphile herbeigeführt werden. Mit Hilfe der Stopped-Flow-Methode untersuchten wir die Bildung multilamellarer Vesikel aus mizellarer Lösung und Mikroemulsion mit solubilisiertem Additiv. Dieser Prozess wurde für unterschiedliche Ausgangsbedingungen und als Funktion der Aufladung des Systems untersucht. Dabei zeigte sich, dass der Bildungsprozess umso schneller ist je geringer die Änderung der Zusammensetzung ist und dass er durch Zusatz eines ionischen Tensids verlangsamt werden kann.

Key words:: Stopped-flow method; vesicle; microemulsion; semipolar additive; formation kinetics
Stichwörter:: Stopped-Flow-Methode; Vesikel; Mikroemulsion; semipolare Additive; Bildungskinetik
∗ Michael Gradzielski, Straße des 17. Juni 124, 10623 Berlin, Tel.: 0049-30-314-24934, Fax: 0049-30-314-26602. E-Mail:

Anina Barth studied chemistry at the Technische Universität Chemnitz and did her Diploma work on the topic of dyes at the Max-Planck Institut für Kolloide und Grenzflächen in the group of Prof. M. Antonietti. Since 2005 she is a working on her Ph.D. in the research group of Prof. M. Gradzielski at the Technische Universität Berlin on the topic of dynamics of solubilisation in amphiphilic systems.

Isabelle Grillo did her studies and degree at the Ecole Nationale Supérieure de Chimie et de Physique de Bordeaux. Directly afterward she did her Ph.D. in Physical Chemistry in 1998 on the topic “Insertion de particules anisotropes dans des phases lamellaires tensioactives”, supervised by P. Levitz (CRMD-CNRS Orléans) and Th. Zemb (Service de Chimie Moléculaire, CEA Saclay). Since that time she is working at the Institute Laue-Langevin (Grenoble) first as a co-responsible of D22 and now as the responsible of the Chemistry Laboratory.

Michael Gradzielski studied chemistry at the Universität Bayreuth and at the University of Wisconsin – Madison (UW). He did his dissertation at the Universität Bayreuth on the topic of microemulsions and micromulsion gels in 1992 in the group of Prof. H. Hoffmann. After a post-doctoral stay at the Ecole Normale Superieure, Paris in the group of Prof. D. Langevin, he finished his habilitation for Physical Chemistry at the Universität Bayreuth in 2000. Since 2004 he is full professor for Physical Chemistry at the Technische Universität Berlin and is responsible for the field “Physikalische Chemie/Molekulare Materialwissenschaften”.

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Received: 2010-02-10
Published Online: 2013-04-05
Published in Print: 2010-09-01

© 2010, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Environmental/Technical Chemistry
  6. Alkyl Polyglycoside-Sorbitan Ester Formulations for Improved Oil Recovery
  7. Novel Surfactants
  8. Photosynthesis-inhibiting Effects of Cationic Biodegradable Gemini Surfactants
  9. Synthesis and Characterization of a New Cationic Galactolipid with Carbamate for Gene Delivery
  10. Physical Chemistry
  11. Dynamics of Formation of Vesicles Studied by Highly Time-resolved Stopped-flow Experiments
  12. Ion Extractant as Cosurfactant at the Water-Oil Interface in Microemulsions
  13. Microemulsions with Mixed Nonionic Surfactants and Isopropylmyristate
  14. Micellization and Interfacial Behaviour of Amitriptyline-Nonionic Surfactant Systems in Aqueous Medium
  15. Synthesis
  16. Ordered Ferrocene-containing Mesoporous Materials with Tailor-made Pore Size
  17. Cleaning Technology
  18. Comparison of Standards for Testing Electrical Dishwashers or Dishwashing Detergents
  19. Manual Dishwashing – How can it be Optimized?
https://doi.org/10.3139/113.110081
Schlagwörter für diesen Artikel
Stopped-flow method; vesicle; microemulsion; semipolar additive; formation kinetics

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Environmental/Technical Chemistry
  6. Alkyl Polyglycoside-Sorbitan Ester Formulations for Improved Oil Recovery
  7. Novel Surfactants
  8. Photosynthesis-inhibiting Effects of Cationic Biodegradable Gemini Surfactants
  9. Synthesis and Characterization of a New Cationic Galactolipid with Carbamate for Gene Delivery
  10. Physical Chemistry
  11. Dynamics of Formation of Vesicles Studied by Highly Time-resolved Stopped-flow Experiments
  12. Ion Extractant as Cosurfactant at the Water-Oil Interface in Microemulsions
  13. Microemulsions with Mixed Nonionic Surfactants and Isopropylmyristate
  14. Micellization and Interfacial Behaviour of Amitriptyline-Nonionic Surfactant Systems in Aqueous Medium
  15. Synthesis
  16. Ordered Ferrocene-containing Mesoporous Materials with Tailor-made Pore Size
  17. Cleaning Technology
  18. Comparison of Standards for Testing Electrical Dishwashers or Dishwashing Detergents
  19. Manual Dishwashing – How can it be Optimized?
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