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Study on the Synthesis and Surface Activities of Disodium Alkyl Polyglucoside Citrate

  • Z.-C. Zhou , X.-Q. Yang , Q.-L. Yang , Y.-J. Zhang and Y.-M. Cheng
Published/Copyright: July 4, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 45 Issue 6

Abstract

A new method of synthesizing disodium alkyl polyglucoside citrate surfactant has been reported in the paper, in which citric acid anhydride was firstly prepared, and then reacted with alkyl polyglucoside to obtain ester. The structures of products were indicated by infrared spectroscopy. Moreover, the surface activities of raw materials and their corresponding products were investigated. The results show that products exhibit low surface tension in 28 mN/m. Comparing with raw materials, the disodium alkyl polyglucoside citrate surfactants possess better emulsification stabilities to oil acid, good foam abilities and excellent hard water-resistant properties.

Kurzfassung

Es wird über ein neues Verfahren zur Herstellung von grenzflächenaktivem Dinatrium-alkylpolyglucosid-zitrat berichtet, bei dem zuerst Zitronensäureanhydrid gebildet wird, das dann mit Alkylpolyglucosid zum Ester umgesetzt wird. Die Struktur der Produkte wurde mittels IR-Spektroskopie ermittelt. Weiterhin wurde die Grenzflächenaktivität der eingesetzten Alkylpolyglucoside und deren Zitronensäureester bestimmt. Letztere zeigten niedrige Oberflächenspannungen bis zu 28 mN/m. Die Emulgatoreigenschaften, das Schaumbildungsvermögen und die Hartwasserbeständigkeit der Alkylpolyglucosidzitrate sind besser als die der reinen Alkylpolyglucoside.

Keywords:: Citric acid; alkyl polyglucoside; esterification; critical concentration for micelle formation
Schlüsselwörter:: Zitronensäure; Alkylpolyglucosid; Veresterung; kritische Mizellbildungskonzentration
∗ Correspondence to, Prof. Xiuquan Yang, National Engineering Research Centre of Surfactants, China Research Institute of Daily Chemical Industry, 34 Wenyuan St., 030001 Taiyuan, P. R. China, E-mail:

Zhang-cai Zhou was born in 1979. He is a master student at China Research Institute of Daily-Chemical Industry. His main field of research is synthesis and properties on surfactant of citrate.

Prof. Xiu-quan Yang was born in 1966. He obtained his M.S. in fine chemicals from Dalian University of Technology in 1990. Since then, he has been teaching and working in China Research Institute of Daily-Chemical Industry. His focus is on synthesis, physical-chemistry properties and applications of surfactants, chemical engineering and green chemistry.

Qing-li Yang was born in 1971. He obtained his M.S. in China Research Institute of Daily Chemical Industry in 2004. Since then, he has been teaching and working in China Research Institute of Daily-Chemical Industry. His focus is on synthesis and applications of surfactants, chemical engineering and green chemistry.

Yuan-jun Zhang was born in 1982. He will obtain his Master's Degree of applied chemistry from China Research Institute of Daily-Chemical Industry in 2009. His main field of research is synthesis of surfactant.

Yu-mei Cheng was born in 1955. She is an engineer on analysis of surfactant. Her research interests are characteristics of surfactants.

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Received: 2008-5-12
Published Online: 2013-07-04
Published in Print: 2008-11-01

© 2008, Carl Hanser Verlag, Munchen

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https://doi.org/10.3139/113.100392
Keywords for this article
Citric acid; alkyl polyglucoside; esterification; critical concentration for micelle formation

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Highly Concentrated Cocamidopropyl Betaine – The Latest Developments for Improved Sustainability and Enhanced Skin Care
  7. Dye Fading in Laundry Washing Comparison of Washing Machine and Linitest Results
  8. The Impact of Fluorescent Compounds on the Change in Shade of Pastel Colored PES/Cotton Fabrics
  9. Physical Chemistry
  10. Phosphorylation of Mono- or Di-octadienyl-D-xylosides. Influence towards Surfactant Properties
  11. Polymer Chemistry
  12. Polymer-modified Microemulsions – a Template for the Formation of BaSO4 Nanoparticles
  13. Synthesis
  14. Study on the Synthesis and Surface Activities of Disodium Alkyl Polyglucoside Citrate
  15. Validation Processes
  16. Use of Biomonitors for the Validation of Chemo-thermal Disinfecting Washing Procedures
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