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Phosphorylation of Mono- or Di-octadienyl-D-xylosides. Influence towards Surfactant Properties

  • S. Pradeau , I. Pezron , L. Komunjer and S. Bouquillon
Published/Copyright: July 4, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 45 Issue 6

Abstract

Phosphorylation of mono- or dioctadienyl-D-xylosides has been studied and led to mono- or dioctadienyl-D-xylosides phosphate derivatives. Comparison between monooctadienyl-D-xylosides and monooctadienyl-D-xyloside phosphate derivatives are not easy because of the complexity of having pure forms and corresponding data. However, comparison of dioctadienyl-D-xyloside diethoxyphosphate derivatives to dioctadienyl-D-xylosides indicates similar cmc values and surface activity. Dioctadienyl-D-xyloside phosphate derivatives, on the other hand, are characterized by a high hydrophilicity and a poor surface activity. Mostly, it was found that the introduction of these ethoxylated or non-ethoxylated phosphate groups influences the solubility and the surfactant properties of the mono- or dioctadienyl-D-xylosides.

Kurzfassung

Die Phosphorylierung von Mono- oder Dioctadienyl-D-Xylosiden wurde untersucht und führte zu Mono- oder Dioctadienyl-D-Xylosidphosphatderivaten. Vergleiche zwischen Monooctadienyl-D-Xyloside und Monooctadienyl-D-Xylosidphosphatderivate sind aufgrund der Komplexität in Reinform und korrespondierender Daten nicht einfach. Dagegen zeigt ein Vergleich zwischen Dioctadienyl-D-Xylosidphosphatderivat und Dioctadienyl-D-Xylosid ähnliche cmc-Werte und Oberflächenaktivitäten. Auf der anderen Seite sind die Dioctadienyl-D-Xylosidphosphatderivate durch eine hohe Hydrophilie und schwacher Oberflächenaktivität charakterisiert. Hauptsächlich wurde herausgefunden, dass die Einführung dieser ethoxylierten oder nicht ethoxylierten Phosphatgruppen die Löslichkeit und die Tensideigenschaften der Mono- oder Dioctadienyl-D-Xyloside beeinflusst.

Keywords:: Xylose; octadienyl pentosides; phosphorylation; interfacial properties; surfactants
Schlüsselwörter:: Xylose; Octadienylpentoside; Phosphorylierung; Grenzflächeneigenschaften; Tenside
∗ Correspondence to, Sandrine Bouquillon, Institut de Chimie Moléculaire de Reims, CNRS UMR 6229, Université de Reims Champagne-Ardenne, BP 1039, 51687 Reims Cedex, France, E-mail:

Stéphanie Pradeau was born in 1981, she has received her master's degree at the University of Limoges in 2005. She joined the University of Reims in 2005 for a training course where she had a position of engineer for six months in 2007.

Pr Isabelle Pezron was born in 1961; she graduated from the Ecole Supérieure de Physique et Chimie Industrielles de Paris (ESPCI) in 1985 and received her PhD from the Université Paris VI in 1987. After a post-doctoral year at the Institute for Surface Chemistry (YKI) in Stockholm, Sweden, she joined the Université de Technologie de Compiègne (UTC) as an assistant professor in 1991 and has now a position of full professor since 2005.

Pr Liepsa Komunjer was born in 1949; she graduated from the University of Zagreb, Croatia in 1972 and received her PhD from the University of Zagreb and Rudjer Boskovic Institute in 1990. From 1991 to 1993 she worked as a post-doctoral fellow at the Laboratoire de Minérallogie-Cristallographie, Université Paris VI et Paris VII, before joining the Université de Technologie de Compiègne (UTC) in 1994 as visiting professor. She holds full professor position at the UTC from 1997.

Pr Sandrine Bouquillon was born in 1967, she has received her engineer's degree at the European Chemistry School of Strasbourg in 1989 and her PhD at the University of Toulouse in 1993. After three postdoctoral years in Mülheim/Ruhr (MPI für Kohlenforschung, Germany), and at the University of Grenoble, she joined the University of Reims in 1996 as an assistant professor where she has a position of full professor since 2006.

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Received: 2008-7-8
Published Online: 2013-07-04
Published in Print: 2008-11-01

© 2008, Carl Hanser Verlag, Munchen

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https://doi.org/10.3139/113.100390
Keywords for this article
Xylose; octadienyl pentosides; phosphorylation; interfacial properties; surfactants

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Highly Concentrated Cocamidopropyl Betaine – The Latest Developments for Improved Sustainability and Enhanced Skin Care
  7. Dye Fading in Laundry Washing Comparison of Washing Machine and Linitest Results
  8. The Impact of Fluorescent Compounds on the Change in Shade of Pastel Colored PES/Cotton Fabrics
  9. Physical Chemistry
  10. Phosphorylation of Mono- or Di-octadienyl-D-xylosides. Influence towards Surfactant Properties
  11. Polymer Chemistry
  12. Polymer-modified Microemulsions – a Template for the Formation of BaSO4 Nanoparticles
  13. Synthesis
  14. Study on the Synthesis and Surface Activities of Disodium Alkyl Polyglucoside Citrate
  15. Validation Processes
  16. Use of Biomonitors for the Validation of Chemo-thermal Disinfecting Washing Procedures
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