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Micellization of Cetyltributylphosphonium Bromide in some Binary Aqueous Solvents Mixtures

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Published/Copyright: April 5, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 45 Issue 5

Abstract

The micellization behavior of cetyltributylphosphonium bromide (CTBPB) has been studied in aqueous ethylene glycol, dimethyl formamide, dimethyl sulfoxide, acetonitrile, 1-propanol, methanol, 1,4-dioxane and tetrahydrofuran mixtures (10–20% v/v) over the temperature range (300–320 K) by conductometry. The critical micelle concentration (cmc), extent of counterion binding (α) and thermodynamic parameters (ΔGom, ΔHom, ΔSom) for micellization process have been reported and discussed. The cmc values were found to increase with an increase in temperature and % of organic solvent.

Kurzfassung

Das Mizellbildungsverhalten von Cetyltributylphosphoniumbromid (CTBPB) wurde in wässrigen Ethylenglycol, Dimethylformamid, Dimethylsulfoxid, Acetonitril, 1-Propanol, Methanol, 1,4-Dioxan und Tetrahydrofuran-Mischungen (10–20% v/v) über einen Temperaturbereich von 300–320 K mittels Konduktometrie untersucht. Über die kritische Mizellbildungskonzentration (cmc), das Ausmaß der Gegenionenbindung (α) und die thermodynamischen Parameter (ΔGom, ΔHom, ΔSom) des Mizellbildungsprozesses wurde berichtet und diskutiert. Gefunden wurde eine Erhöhung der cmc-Werte bei steigender Temperatur und prozentualer Zunahme an organischem Lösungsmittel.

Key words:: cmc; cetyltributylphosphonium bromide; solvent effect and micellization
Stichwörter:: cmc; Cetyltributylphosphoniumbromid; Lösungsmitteleinfluss und Mizellbildung
∗ Kallol K. Ghosh, School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur (C.G.), 492010, India. E-Mail:

Dr. Kallol K Ghosh is presently a reader of physical chemistry at Pt. Ravishankar Shukla University, Raipur, India since 1998. He had been INSA/JSPS fellow at Seikei University, Tokyo, Japan and James Chair visiting fellow at St. Francis Xavier University, Antigonish, Canada. He has published 85 research papers. His research is focused on micellar catalysis, reaction mechanisms, hydroxamic acids and detoxification.

Mrs. Shuchi Tiwari is a Ph.D student of School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, India.

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Received: 2008-04-15
Published Online: 2013-04-05
Published in Print: 2008-09-01

© 2008, Carl Hanser Publisher, Munich

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https://doi.org/10.3139/113.100384
Keywords for this article
cmc; cetyltributylphosphonium bromide; solvent effect and micellization

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Synthesis of an Imidazoline Phosphate Surfactant and its Application on Corrosion Inhibition
  7. Properties of Oxyethylenated Fatty Acid Methyl Esters and Ethyl Esters; Hydrolysis, Critical Micelle Concentrations and Foaming
  8. Effect of Nano and Micro Emulsion Silicone Softeners on Properties of Polyester Fibers
  9. Novel Surfactants
  10. Synthesis, Characterization and Surface Active Properties of Imidazolinium Surfactant Derived from Oleic Acid and Diethylenetriamine
  11. Physical Chemistry
  12. Micellization of Cetyltributylphosphonium Bromide in some Binary Aqueous Solvents Mixtures
  13. Micellar Studies of Magnesium Soaps Using Ion-selective Electrode
  14. Influence of the Cross-sectional Geometry on Wettability and Cleanability of Polyester Woven Fabrics
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