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Synthesis, Separation and Adsorption of Naphthalene Sulphonate Formaldehyde Condensates

  • Li Yan , Dong Liangjun , Li Zongshi und Qiao Weihong
Veröffentlicht/Copyright: 8. Mai 2013
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Abstract

Ten components of NaNSF were separated by thin layer chromatography (TLC) by using F254 silica gel plates as fixed phase and acidic alcohol solution as mobile phase. Adsorption of naphthalene sulphonate formaldehyde (NaNSF) on titania surface was studied through fundamental principles of surface physical chemistry, and the saturation adsorption of NaNSF was found to be much lower than that of dispersant in disperse dyes. This study is of reference significance to the investigation of mechanism of adsorption of dispersant on dyes, cement, and so on.

Kurzfassung

Ein Gemisch von zehn homologen Natriumnaphthalinsulfonat-Formaldehyd-Kondensationsprodukten (NaNSF) wurde dünnschichtchromatographisch unter Verwendung von F-254 Silikagelplatten als stationäre und einer sauren Alkohollösung als mobile Phase in die Einzelverbindungen getrennt. Es wurde eine physikalisch chemische Untersuchung der Adsorption der Naphthalinsulfonat-Formaldehyd-Kondensationsprodukte an Titandioxid-Oberflächen durchgeführt. Dabei wurde gefunden, dass die Sättigungsadsorption der NaNSF-Verbindungen deutlich niedriger ist als die von gebräuchlichen Dispergenzien in Farbpigment-Dispersionen. Die Untersuchung ist von Bedeutung für das Studium des Mechanismus der Adsorption von Dispergenzien an Farbpigmenten, Zement und anderen Feststoffen.

Keywords:: β-naphthalene sulphonate formaldehyde condensates (NaNSF); separation; titania; saturation adsorption
Schlüsselwörter: Natriumnaphthalinsulfonat-Formaldehyd-Kondensationsprodukte (NaNSF); Trennung; Titandioxid; Sättigungsadsorption
1Master Li Yan, State Key Laboratory of Fine Chemicals Dalian University of Technology No. 158 Zhongshan Road Dalian, 116012 P. R. China E-mail:

Yan Li was born in 1980. Now she is a master student in Dalian University of Technology. Her main fields of research are the synthesis and physical chemistry of surfactants. E-Mail:

Liangjun Dong was born in 1973. Now he is a Ph D student in Dalian University of Technology. His main fields of research are the synthesis of dyes and their applications. E-Mail:

Prof. Zongshi Li was born in 1936. He obtained a BD from Dalian University of Technology in 1960. Since then he has been working in the department of fine chemicals at Dalian University of Technology. His focus is on synthesis of surfactants and their applications.

Weihong Qiao was born in 1968. She obtained an MSc from Dalian University of Technology in 1994 and a Ph D from the same university in 2000. Since 1994, she has been teaching and working in Dalian University of Technology. Now she is an associate professor. Her main field of research is the synthesis and physical chemistry of surfactants. E-Mail:

References

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4. KenichiHattori and YukioTanino: Condensate of β-NSF, Kogyo Kagaku Zasshi. Vol. 66 (1963) 55–58.10.1246/nikkashi1898.66.55Suche in Google Scholar

5. KenichiHattori and YukioTanino: The condensation products of β-naphthalenesulfonic acid and formaldehyde, Kogyo Kagaku Zasshi. Vol. 66 (1964) 55–58.Suche in Google Scholar

6. CarmenWolf, ThomasStorn and Frank ThomasLange: Analysis of Sulfonated Naphthalene–Formaldehyde Condensates by Ion-pair Chromatography and their quantitative determination from aqueous environmental samples. Anal. Chem, Vol. 72 (2000) 5466–5472.Suche in Google Scholar

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8. HuXiao-bo and ChenZhi-yuan: Study of the adsorption of PNS superplasticizer on the surface of the cement particles by using X-ray fluorescence analysis. Journal of the Chinese ceramic society, Vol. 31 (2003) 784–789.Suche in Google Scholar

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Received: 2004-10-18
Published Online: 2013-05-08
Published in Print: 2005-04-01

© 2005, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Interactions of Hardness Ions with Polymeric Scale Inhibitors in Aqueous Systems
  7. Commercial Surfactants for Use in CO2 – a Survey
  8. Physical Chemistry
  9. Spreading Characteristics of Aqueous Surfactant Solutions on Polymer Surfaces
  10. Studies on Flocculation of Egyptian Kaolin Suspensions by Anionic Polyacrylamide in the Presence of Surfactants
  11. The Influence of Hydrophobic Counterion on the Phase Behavior of Ionic Surfactants
  12. Synthesis
  13. Synthesis, Separation and Adsorption of Naphthalene Sulphonate Formaldehyde Condensates
https://doi.org/10.3139/113.100242
Schlagwörter für diesen Artikel
β-naphthalene sulphonate formaldehyde condensates (NaNSF); separation; titania; saturation adsorption

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Interactions of Hardness Ions with Polymeric Scale Inhibitors in Aqueous Systems
  7. Commercial Surfactants for Use in CO2 – a Survey
  8. Physical Chemistry
  9. Spreading Characteristics of Aqueous Surfactant Solutions on Polymer Surfaces
  10. Studies on Flocculation of Egyptian Kaolin Suspensions by Anionic Polyacrylamide in the Presence of Surfactants
  11. The Influence of Hydrophobic Counterion on the Phase Behavior of Ionic Surfactants
  12. Synthesis
  13. Synthesis, Separation and Adsorption of Naphthalene Sulphonate Formaldehyde Condensates
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