Trace analysis of lead by anodic stripping voltammetry with collection at interdigitated microelectrodes in small-volume samples
-
M. Rievaj
,
Z. Dovalovská
Abstract
A simple and sensitive electroanalytical method was developed for microvolume trace elements determination. Commercially available interdigitated microelectrodes (IDA) from ALS Japan Inc. based on a thin carbon film technology were used. Anodic stripping voltammetry with collection at IDA was applied. Carbon IDA microbands were coated with a pre-deposited mercury film for better performance. The method with this sensor enables analysis of some heavy metals in total sample volumes as small as 0.05 cm3. The method was applied to Pb in blood samples determination by a standard addition method.
[1] Wang, J., Rongrong, X., Tian, B., Wang, Ji., Renschler, C. L., and White, C. A., Anal. Chim. Acta 293, 43 (1994). http://dx.doi.org/10.1016/0003-2670(94)00098-010.1016/0003-2670(94)00098-0Suche in Google Scholar
[2] Wang, J., Lu, J., Tian, B., and Yarnicky, Ch., J. Electroanal. Chem. 361, 77 (1993). http://dx.doi.org/10.1016/0022-0728(93)87040-310.1016/0022-0728(93)87040-3Suche in Google Scholar
[3] Brainina, Kh., Schafer, H., Ivanova, A., and Khanina, R., Analyst 121, 345 (1996). http://dx.doi.org/10.1039/an996210034510.1039/an9962100345Suche in Google Scholar
[4] Wang, J., Tian, B., Wang, Ji., Lu, J., Olsen, C., Yarnicky, Ch., Olsen, K., Hammerstrom, D., and Bennett, W., Anal. Chim. Acta 385, 429 (1999). http://dx.doi.org/10.1016/S0003-2670(98)00664-310.1016/S0003-2670(98)00664-3Suche in Google Scholar
[5] Niwa, O., Electroanalysis 7, 606 (1995). http://dx.doi.org/10.1002/elan.114007070210.1002/elan.1140070702Suche in Google Scholar
[6] Tabei, H., Morita, M., Niwa, O., and Horiuchi, T., J. Electroanal. Chem. 334, 25 (1992). http://dx.doi.org/10.1016/0022-0728(92)80558-L10.1016/0022-0728(92)80558-LSuche in Google Scholar
[7] Electrochemical electrodes and accessories, ALS Brosure, 11 (2004). Suche in Google Scholar
[8] Rievaj, M., Lietava, J., and Bustin, D., Chem. Pap. 58, 306 (2004). Suche in Google Scholar
[9] Wang, J., Luo, D., and Horiuchi, T., Electroanalysis 10, 107 (1998). http://dx.doi.org/10.1002/(SICI)1521-4109(199802)10:2<107::AID-ELAN107>3.0.CO;2-B10.1002/(SICI)1521-4109(199802)10:2<107::AID-ELAN107>3.0.CO;2-BSuche in Google Scholar
[10] Yee, H. Y., Nelson, J. D., and Jackson, B., J. Anal. Toxicol. 18, 415 (1994). Suche in Google Scholar
[11] Pineau, A., Fauconneau, B., Rafael, M., Viallefont, A., and Guillard, O., J. Trace Elem. Med. Biol. 16, 113 (2002). http://dx.doi.org/10.1016/S0946-672X(02)80037-210.1016/S0946-672X(02)80037-2Suche in Google Scholar
© 2006 Institute of Chemistry, Slovak Academy of Sciences
Artikel in diesem Heft
- Chemistry for the design and better understanding of cement-based materials and composites
- Surface modifications of natural clinoptilolite-dominated zeolite for phenolic pollutant mitigation
- Flame retardant property of nanopowder aerosols toward methane
- Trace analysis of lead by anodic stripping voltammetry with collection at interdigitated microelectrodes in small-volume samples
- Investigation of the solid samples evaporation from the auxiliary DC arc discharge in the atomic emission spectroscopy
- Determination of bioavailable iron in noncontaminated Slovak soils by flame atomic absorption spectrometry
- Determination of technetium-99 in soils and radioactive wastes using ICP-MS
- Synthesis and characterization of the rare-earth complexes with salicylic acid
- Spectrophotometric determination of nickel(II) in different samples by complexation with some triazolylazo dyes
- Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates
- Effects of Cd(II) and Zn(II) complexes with bioactive ligands on some photosynthesizing organisms
- Efficiency of a fixed-bed and a gas-lift three-column reactor for continuous production of ethanol by pectate-and alginate-immobilized Saccharomyces cerevisiae cells
- Reactions and applications of trans-1,2-epoxy-(Z,E)-cyclododeca-5,9-diene
- Dictionary of Carbohydrates. Edited by P. M. Collins. Second Edition
- In memoriam Associate Professor Ing. Vladimír Daněk, DrSc
Artikel in diesem Heft
- Chemistry for the design and better understanding of cement-based materials and composites
- Surface modifications of natural clinoptilolite-dominated zeolite for phenolic pollutant mitigation
- Flame retardant property of nanopowder aerosols toward methane
- Trace analysis of lead by anodic stripping voltammetry with collection at interdigitated microelectrodes in small-volume samples
- Investigation of the solid samples evaporation from the auxiliary DC arc discharge in the atomic emission spectroscopy
- Determination of bioavailable iron in noncontaminated Slovak soils by flame atomic absorption spectrometry
- Determination of technetium-99 in soils and radioactive wastes using ICP-MS
- Synthesis and characterization of the rare-earth complexes with salicylic acid
- Spectrophotometric determination of nickel(II) in different samples by complexation with some triazolylazo dyes
- Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates
- Effects of Cd(II) and Zn(II) complexes with bioactive ligands on some photosynthesizing organisms
- Efficiency of a fixed-bed and a gas-lift three-column reactor for continuous production of ethanol by pectate-and alginate-immobilized Saccharomyces cerevisiae cells
- Reactions and applications of trans-1,2-epoxy-(Z,E)-cyclododeca-5,9-diene
- Dictionary of Carbohydrates. Edited by P. M. Collins. Second Edition
- In memoriam Associate Professor Ing. Vladimír Daněk, DrSc
