Article
Licensed
Unlicensed
Requires Authentication
Letter: Ion irradiation of the TiO2 polymorphs and cassiterite
-
Gregory R. Lumpkin
,
Mark G. Blackford
Published/Copyright:
April 2, 2015
Abstract
Thin crystals of rutile, brookite, anatase, and cassiterite were irradiated in situ in the transmission electron microscope using 1.0 MeV Kr ions at 50-300 K. Synthetic rutile and natural cassiterite, with 0.1-0.2 wt% impurities, remain crystalline up to a fluence of 5 × 1015 ions cm-2 without evidence for amorphization at 50 K. Natural brookite and anatase, with 0.3-0.5 wt% impurities, become amorphous at fluences of 8.1 × 1014 and 2.3 × 1014 ions cm-2, respectively. We have also studied two natural rutile samples containing ~1.7 and 1.2 wt% impurities. These samples became amorphous at 9.2 × 1014 and 8.6 × 1014 ions cm-2 at 50 K, respectively. Further analyses of the fluence-temperature data for natural brookite, rutile, and anatase give critical amorphization temperatures of 168 ± 11, 209 ± 8, and 242 ± 6 K, respectively. Results are briefly discussed with respect to several criteria for radiation resistance, including aspects of the structure, bonding, and energetics of defect formation and migration.
Keywords: TiO2 polymorphs; anatase; brookite; rutile; cassiterite; ion irradiation; defect migration
Received: 2009-6-25
Accepted: 2009-8-10
Published Online: 2015-4-2
Published in Print: 2010-1-1
© 2015 by Walter de Gruyter Berlin/Boston
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Metamorphic ultrahigh-pressure tourmaline: Structure, chemistry, and correlations to P-T conditions
- Slavikite—Revision of chemical composition and crystal structure
- Anisotropic elasticity of jarosite: A high-P synchrotron XRD study
- Tourmaline of the elbaite-schorl series from the Himalaya Mine, Mesa Grande, California: A detailed investigation
- Characterization of Al-Si ordering state in an alkali feldspar using atom location by channeling-enhanced microanalysis (ALCHEMI)
- The relative stability of stoichiometrically related natural and synthetic double salts
- Free energy of formation of zircon based on solubility measurements at high temperature and pressure
- Structure refinement of a synthetic knorringite, Mg3(Cr0.8Mg0.1Si0.1)2(SiO4)3
- A mineral tracer toward high-resolution dust provenance on the Chinese Loess Plateau: SEM, TEM, and sulfur isotopes of sulfate inclusions in biotite
- High-resolution TEM study of jimthompsonite, chesterite, and chain-width disorder in Archean ultramafic rocks from Isua, West Greenland
- Retrograde hydration sequence in disordered Mg amphiboles: A TEM investigation
- Can electron energy-loss spectroscopy (EELS) be used to quantify hydrogen in minerals from the O K edge?
- Texture analysis of a turbostratically disordered Ca-montmorillonite
- Packing systematics of the silica polymorphs: The role played by O-O nonbonded interactions in the compression of quartz
- Calorimetric study of the surface energy of forsterite
- Crystallographic texture of the magnetite-hematite transformation: Evidence for topotactic relationships in natural samples from Quadrilátero Ferrífero, Brazil
- Semi-ordered crystalline structure of the Santa Olalla vermiculite inferred from X-ray powder diffraction
- Stishovite single-crystal growth and application to silicon self-diffusion measurements
- Density of dry peridotite magma at high pressure using an X-ray absorption method
- The crystal-structure and vacancy distribution in 6C pyrrhotite
- Thermal modification of hematite-ilmenite intergrowths in the Ecstall pluton, British Columbia, Canada
- A new Al-rich hydroxylian pseudorutile from Kalimantan, Indonesia
- Lapeyreite, Cu3O[AsO3(OH)]2·0.75H2O, a new mineral: Its description and crystal structure
- High P-T phase relation of magnesian (Mg0.7Fe0.3) staurolite compositon in the system FeO-MgO-Al2O3-SiO2-H2O: Implications for prograde high-pressure history of ultrahigh-temperature metamorphic rocks
- Letter: Hibonite-(Fe), (Fe,Mg)Al12O19, a new alteration mineral from the Allende meteorite
- Letter: Ion irradiation of the TiO2 polymorphs and cassiterite
- Letter: Corundum + orthopyroxene ± spinel intergrowths in an ultrahigh-temperature Al-Mg granulite from the Southern Marginal Zone, Limpopo Belt, South Africa
- Letter: Fe3+ spin transition in CaFe2O4 at high pressure
- Density functional theory and Monte Carlo study of octahedral cation ordering of Al/Fe/Mg cations in dioctahedral 2:1 phyllosilicates
Keywords for this article
TiO2 polymorphs;
anatase;
brookite;
rutile;
cassiterite;
ion irradiation;
defect migration
Articles in the same Issue
- Metamorphic ultrahigh-pressure tourmaline: Structure, chemistry, and correlations to P-T conditions
- Slavikite—Revision of chemical composition and crystal structure
- Anisotropic elasticity of jarosite: A high-P synchrotron XRD study
- Tourmaline of the elbaite-schorl series from the Himalaya Mine, Mesa Grande, California: A detailed investigation
- Characterization of Al-Si ordering state in an alkali feldspar using atom location by channeling-enhanced microanalysis (ALCHEMI)
- The relative stability of stoichiometrically related natural and synthetic double salts
- Free energy of formation of zircon based on solubility measurements at high temperature and pressure
- Structure refinement of a synthetic knorringite, Mg3(Cr0.8Mg0.1Si0.1)2(SiO4)3
- A mineral tracer toward high-resolution dust provenance on the Chinese Loess Plateau: SEM, TEM, and sulfur isotopes of sulfate inclusions in biotite
- High-resolution TEM study of jimthompsonite, chesterite, and chain-width disorder in Archean ultramafic rocks from Isua, West Greenland
- Retrograde hydration sequence in disordered Mg amphiboles: A TEM investigation
- Can electron energy-loss spectroscopy (EELS) be used to quantify hydrogen in minerals from the O K edge?
- Texture analysis of a turbostratically disordered Ca-montmorillonite
- Packing systematics of the silica polymorphs: The role played by O-O nonbonded interactions in the compression of quartz
- Calorimetric study of the surface energy of forsterite
- Crystallographic texture of the magnetite-hematite transformation: Evidence for topotactic relationships in natural samples from Quadrilátero Ferrífero, Brazil
- Semi-ordered crystalline structure of the Santa Olalla vermiculite inferred from X-ray powder diffraction
- Stishovite single-crystal growth and application to silicon self-diffusion measurements
- Density of dry peridotite magma at high pressure using an X-ray absorption method
- The crystal-structure and vacancy distribution in 6C pyrrhotite
- Thermal modification of hematite-ilmenite intergrowths in the Ecstall pluton, British Columbia, Canada
- A new Al-rich hydroxylian pseudorutile from Kalimantan, Indonesia
- Lapeyreite, Cu3O[AsO3(OH)]2·0.75H2O, a new mineral: Its description and crystal structure
- High P-T phase relation of magnesian (Mg0.7Fe0.3) staurolite compositon in the system FeO-MgO-Al2O3-SiO2-H2O: Implications for prograde high-pressure history of ultrahigh-temperature metamorphic rocks
- Letter: Hibonite-(Fe), (Fe,Mg)Al12O19, a new alteration mineral from the Allende meteorite
- Letter: Ion irradiation of the TiO2 polymorphs and cassiterite
- Letter: Corundum + orthopyroxene ± spinel intergrowths in an ultrahigh-temperature Al-Mg granulite from the Southern Marginal Zone, Limpopo Belt, South Africa
- Letter: Fe3+ spin transition in CaFe2O4 at high pressure
- Density functional theory and Monte Carlo study of octahedral cation ordering of Al/Fe/Mg cations in dioctahedral 2:1 phyllosilicates
