Abstract
A natural high-pressure phase of titanium oxide with α-PbO2-structure has been found in omphacite from coesite-bearing eclogite at Shima in the Dabie Mountains, China. High-resolution transmission electron microscope observations have revealed an orthorhombic lattice, corresponding to α-PbO2- type TiO2 with cell parameters a = 0.461 nm, b = 0.540 nm, c = 0.497 nm and space group Pbcn. It occurs as nanometer-thick (<2 nm) lamellae between multiple twinned rutile crystals, providing additional evidence of very high-pressure, metamorphism at 7 GPa, 900°C. This implies subduction of continental material to a depth of more than 200 kilometers. α-PbO2-type TiO2 could be an extremely useful index mineral for ultrahigh-pressure
© 2015 by Walter de Gruyter Berlin/Boston
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Articles in the same Issue
- Crystal-size and shape distributions of magnetite from uncultured magnetotactic bacteria as a potential biomarker
- Tourmaline-bearing rocks in the Singhbhum shear zone, eastern India: Evidence of boron infiltration during regional metamorphism
- High-resolution transmission electron microscopy (HRTEM) study of the 4a and 6a superstructure of bornite Cu5FeS4
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- Mixing and ordering behavior in manganocolumbite-ferrocolumbite solid solution: A single-crystal X-ray diffraction study
- Structure change of MgSiO3, MgGeO3, and MgTiO3 ilmenites under compression
- Dehydration processes in the meta-autunite group minerals meta-autunite, metasaléeite, and metatorbernite
- Investigation of the martensitic-like transformation from Mg2GeO4 olivine to its spinel structure polymorph
- A high-temperature diffraction study of the solid solution CaTiOSiO4-CaTiOGeO4
- The vibrational spectrum of synthetic hydrogrossular (katoite) Ca3Al2(O4H4)3: A low-temperature IR and Raman spectroscopic study
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- Synthesis and crystal-chemistry of alkali amphiboles in the system Na2O-MgO-FeO-Fe2O3- SiO2-H2O as a function of fO2
- Compositional zoning in sphalerite crystals
- Structure and the extent of disorder in quaternary (Ca-Mg and Ca-Na) aluminosilicate glasses and melts
- Makarochkinite, Ca2Fe42+Fe3+TiSi4BeAlO20, a new beryllosilicate member of the aenigmatite-sapphirine-surinamite group from the Ilʼmen Mountains (southern Urals), Russia
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