Article
Licensed
Unlicensed
Requires Authentication
Letter. Aluminum coordination and the densification of high-pressure aluminosilicate glasses
-
Jeffrey R. Allwardt
,
Jonathan F. Stebbins
Published/Copyright:
March 28, 2015
Abstract
To better understand the relationship between atomic-scale structures and densities of aluminosilicate glasses and liquids, we used 27Al MAS NMR to determine the speciation of aluminum ions in K3AlSi3O9, Na3AlSi3O9, and Ca3Al2Si6O18 glasses quenched from melts at 3 to 10 GPa. These data are a first approximation of high-pressure melt structure and illustrate the effects of the type of modifier cation. High field strength modifier cations (e.g., Ca) clearly induce more high-coordinated Al than lower field strength cations (e.g., Na and K). Measured glass densities show that, especially with rapid decompression, a significant portion of the total densification observed in-situ in melts is retained on return to ambient temperature and pressure. Observed increases in Al coordination are well correlated with decreased volume, which suggests that this structural change is a major part of the mechanism for recovered densification of high-pressure melts. Additionally, 23Na MAS NMR, combined with the 27Al MAS spectra and density determinations, reveal that other changes, such as the compression of modifier cation sites and/or decreased network bond angles, must also be significant, especially at low pressure.
Received: 2004-10-22
Accepted: 2005-3-8
Published Online: 2015-3-28
Published in Print: 2005-7-1
© 2015 by Walter de Gruyter Berlin/Boston
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- A synthesis of systematic mineralogy
- Oxidation/alteration of pentlandite and pyrrhotite surfaces at pH 9.3: Part 1. Assignment of XPS spectra and chemical trends
- Oxidation of pentlandite and pyrrhotite surfaces at pH 9.3: Part 2. Effect of xanthates and dissolved oxygen
- X-ray Rietveld refinement and FTIR spectra of synthetic (Si,Ge)-richterites
- Influence of crystal chemistry on ideal plastic shear anisotropy in forsterite: First principle calculations
- High-temperature Mössbauer study of Fe-substituted mullite
- Pressure and temperature-dependence of water solubility in Fe-free wadsleyite
- Quartz exsolution in clinopyroxene is not proof of ultrahigh pressures: Evidence from eclogites from the Eastern Blue Ridge, Southern Appalachians, U.S.A.
- The visible and infrared spectral properties of jarosite and alunite
- Wakabayashilite, [(As,Sb)6S9][As4S5]: Crystal structure, pseudosymmetry, twinning, and revised chemical formula
- Compression of albite, NaAlSi3O8
- Effect of polymorphic transition on oxygen isotope fractionation between aragonite, calcite, and water: A low-temperature experimental study
- Effect of current density on the electron microprobe analysis of alkali aluminosilicate glasses
- A high-pressure polytypic transformation in type-I chlorite
- Experimental determination of crystal growth rates in highly supercooled aluminosilicate liquids: Implications for rate-controlling processes
- P-V equation of State, thermal expansion, and P-T stability of synthetic zincochromite (ZnCr2O4 spinel)
- Niksergievite, [Ba1.33Ca0.67Al(CO3)(OH)4][Al2(AlSi3O10)(OH)2]·nH2O, a new phyllosilicate related to the surite-ferrisurite series
- The crystal-chemistry of holmquistites: Ferroholmquistite from Greenbushes (Western Australia) and hints for compositional constraints in BLi amphiboles
- Dissakisite-(La) from the Ulten zone peridotite (Italian Eastern Alps): A new end-member of the epidote group
- Mazzite-Na, a new zeolite from Boron, California: Its description and crystal structure
- Low-temperature illitization of smectite in the late eocene and early oligocene of the Isle of Wight (Hampshire basin), U.K.
- First reported sedimentary occurrence of berlinite (AlPO4) in phosphate-bearing sediments from Cioclovina Cave, RomaniaComment
- Optical and near infrared spectra of ringwoodite to 21.5 GPa: Implications for radiative heat transport in the mantle
- Letter. Observation of nano-clustered calcite growth via a transient phase mediated by organic polyanions: A close match for biomineralization
- Letter. Aluminum coordination and the densification of high-pressure aluminosilicate glasses
- Letter. Crystal chemistry of a high-pressure C2/c clinopyroxene with six-coordinated silicon
Articles in the same Issue
- A synthesis of systematic mineralogy
- Oxidation/alteration of pentlandite and pyrrhotite surfaces at pH 9.3: Part 1. Assignment of XPS spectra and chemical trends
- Oxidation of pentlandite and pyrrhotite surfaces at pH 9.3: Part 2. Effect of xanthates and dissolved oxygen
- X-ray Rietveld refinement and FTIR spectra of synthetic (Si,Ge)-richterites
- Influence of crystal chemistry on ideal plastic shear anisotropy in forsterite: First principle calculations
- High-temperature Mössbauer study of Fe-substituted mullite
- Pressure and temperature-dependence of water solubility in Fe-free wadsleyite
- Quartz exsolution in clinopyroxene is not proof of ultrahigh pressures: Evidence from eclogites from the Eastern Blue Ridge, Southern Appalachians, U.S.A.
- The visible and infrared spectral properties of jarosite and alunite
- Wakabayashilite, [(As,Sb)6S9][As4S5]: Crystal structure, pseudosymmetry, twinning, and revised chemical formula
- Compression of albite, NaAlSi3O8
- Effect of polymorphic transition on oxygen isotope fractionation between aragonite, calcite, and water: A low-temperature experimental study
- Effect of current density on the electron microprobe analysis of alkali aluminosilicate glasses
- A high-pressure polytypic transformation in type-I chlorite
- Experimental determination of crystal growth rates in highly supercooled aluminosilicate liquids: Implications for rate-controlling processes
- P-V equation of State, thermal expansion, and P-T stability of synthetic zincochromite (ZnCr2O4 spinel)
- Niksergievite, [Ba1.33Ca0.67Al(CO3)(OH)4][Al2(AlSi3O10)(OH)2]·nH2O, a new phyllosilicate related to the surite-ferrisurite series
- The crystal-chemistry of holmquistites: Ferroholmquistite from Greenbushes (Western Australia) and hints for compositional constraints in BLi amphiboles
- Dissakisite-(La) from the Ulten zone peridotite (Italian Eastern Alps): A new end-member of the epidote group
- Mazzite-Na, a new zeolite from Boron, California: Its description and crystal structure
- Low-temperature illitization of smectite in the late eocene and early oligocene of the Isle of Wight (Hampshire basin), U.K.
- First reported sedimentary occurrence of berlinite (AlPO4) in phosphate-bearing sediments from Cioclovina Cave, RomaniaComment
- Optical and near infrared spectra of ringwoodite to 21.5 GPa: Implications for radiative heat transport in the mantle
- Letter. Observation of nano-clustered calcite growth via a transient phase mediated by organic polyanions: A close match for biomineralization
- Letter. Aluminum coordination and the densification of high-pressure aluminosilicate glasses
- Letter. Crystal chemistry of a high-pressure C2/c clinopyroxene with six-coordinated silicon
