Raman spectroscopy and vibrational analyses of albite: From 25 °C through the melting temperature
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David A. Mckeown
Abstract
Raman spectra were collected for crystalline albite from 25 °C to above the 1118 °C melting temperature, where vibrational assignments for the crystal spectra were determined by lattice dynamics (LD). The Raman spectra and associated vibrational assignments are reported for triclinic albite (NaAlSi3O8) at 25 °C and monoclinic albite at 1060 °C. The 25 °C calculations determined that localized T-O stretch and O-T-O bend modes are above 900 cm-1 (where T = Si,Al), while motions from the aluminosilicate tetrahedral cage mixed with Na displacements occur in modes as high as 814 cm-1. Vibrational modes for the most prominent peaks in the spectrum, between 350 and 550 cm-1, are dominated by four-membered tetrahedral ring deformations. For completeness, calculated infrared mode frequencies and their atomic displacements are reported for the 25 °C structure and compared with normal mode calculation results and observed infrared mode frequencies presented by von Stengel (1977). At higher temperatures, modes above 550 cm-1 broaden and shift to lower frequencies by 15 to 27 cm-1; modes below 550 cm-1 broaden, but experience little, if any frequency shifts. Albite melted sluggishly, was completely liquid at 1320 °C, and remained amorphous upon cooling to room temperature. At frequencies above 550 cm-1, the crystalline albite peaks, and possibly their vibrational assignments, can be correlated to Raman bands for albite glass. Spectral differences below 550 cm-1 between crystal and glass correspond to changes of average tetrahedral ring type upon melting, as shown by Taylor and Brown (1979).
© 2015 by Walter de Gruyter Berlin/Boston
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Articles in the same Issue
- Presidential Address To The Mineralogical Society Of Amrica, Boston, November 6, 2001: Some Precambrian Banded Iron-Formations (BiIFs) From Around The World: Their Age, Geologic Setting, Mineralogy, Metamorphism, Geochemistry, And Origin
- Effects of high pressure and high temperature on cation ordering in magnesioferrite, MgFe2O4, using in situ synchrotron X-ray powder diffraction up to 1430 K and 6 GPa
- Raman spectroscopy and vibrational analyses of albite: From 25 °C through the melting temperature
- A new occurrence of xitieshanite [Fe3+(SO4)Cl⋅6H2O] crystals in acid-mine seepways, Green Valley, Vigo County, Indiana, U.S.A.
- Effect of A-site cation radius on ordering of BX6 octahedra in (K,Na)MgF3 perovskite
- Crystal chemistry of NaMgF3 perovskite at high pressure and temperature
- Hyperfine electric field gradient tensors at Fe2+ sites in octahedral layers: Toward understanding oriented single-crystal Mössbauer spectroscopy measurements of micas
- Does the bazhenovite structure really contain a thiosulfate group? A structural and spectroscopic study of a sample from the type locality
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- Absolute quantification by powder X-ray diffraction of complex mixtures of crystalline and amorphous phases for applications in the Earth sciences
- Detrital illite crystals identified from crystallite thickness measurements in siliciclastic sediments
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- The effect of zoned garnet on metapelite pseudosection topology and calculated metamorphic P-T paths
- Low-pressure and low-temperature K-bearing kosmochloric diopside from the Osayama serpentinite mélange, SW Japan
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- Structural changes accompanying the phase transformation between leadhillite and susannite: A structural study by means of in situ high-temperature single-crystal X-ray diffraction
- Optic properties of centimeter-sized crystals determined in air with the spindle stage using EXCALIBRW
- Zoltaiite, a new barium-vanadium nesosubsilicate mineral from British Columbia: Description and crystal structure
- Mn-tourmaline from island of Elba (Italy): Crystal chemistry
- Letter: An infrared study of carbon-oxygen bonding in magnesite to 60 GPa
- Letter: Metals in quartz-hosted melt inclusions: Natural facts and experimental artifacts
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