Abstract
Black shale-hosted vanadium (V) deposits account for about 80% vanadium resources in the world, but only <2% vanadium in the black shale can be extracted mainly due to insufficient recognition on the occurrence mode of vanadium. It is commonly agreed that most vanadium in the black shale is hosted in clay minerals and organic matters, but it is not clear how the other parts of vanadium exist and whether there exists a vanadium mineral, which has limited our understanding of metallogenic mechanism of black shale-hosted vanadium deposits. The Jiujiang Basin at the Lower Yangtze Block is a significant black shale-hosted vanadium metallogenic district. In this work, we conducted systematic studies of mineralogy, lithology and geochemistry on the occurrence of vanadium hosted in the black shales. Electron probe microanalysis (EPMA), Raman spectroscopy, and X-ray diffraction (XRD) show that the main vanadium-hosting mineral in the black shale is mannardite, with a structural formula of
Acknowledgments and Funding
The authors thank the team members from the East China of Technology and the Tenth Geological Brigade of Jiangxi Geological Bureau for their field support, constructive discussions, and comments. We also thank the team members of the State Key Laboratory of Nuclear Resources and Environment in East China University of Technology for their help with the EPMA, Raman spectroscopy, BSE, and EDS analysis, the team members of the Analytic & Testing Research Center of Yunnan for the help with XRD analysis, and the team members of Guangzhou Tuoyan Analytical Technology Co., Ltd. for help with whole-rock geochemistry and TIMA analysis. This research was jointly supported by the Natural Science Fund (Number: H202200072), the National Natural Science Foundation of China (Number: 92162101), Open Fund Projects of the Key Laboratory of Mass Spectrometry and Instrumentation (Number: JXMS202113), and the Natural Science Fund of East China University of Technology (Number: DHBK2019059).
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© 2024 by Mineralogical Society of America
Articles in the same Issue
- Crystal chemistry and thermodynamic properties of zircon structure-type materials
- Thermal and combined high-temperature and high-pressure behavior of a natural intermediate scapolite
- Crystal structure, hydrogen bonding, and high-pressure behavior of the hydroxide perovskite MgSi(OH)6: A phase relevant to deep subduction of hydrated oceanic crust
- Equilibrium Sn isotope fractionation between aqueous Sn and Sn-bearing minerals: Constrained by first-principles calculations
- Raman spectroscopic investigation of selected natural uranyl sulfate minerals
- Modified magnetite and hydrothermal apatite in banded iron-formations and implications for high-grade Fe mineralization during retrogressive metamorphism
- Apatite trace element composition as an indicator of ore deposit types: A machine learning approach
- Identifying serpentine minerals by their chemical compositions with machine learning
- Crystal habit (tracht) of groundmass pyroxene crystals recorded magma ascent paths during the 2011 Shinmoedake eruption
- Reconstructing diagenetic mineral reactions from silicified horizons of the Paleoproterozoic Biwabik Iron Formation, Minnesota
- Mannardite as the main vanadium-hosting mineral in black shale-hosted vanadium deposits, South China
- Molybdenite-bearing vugs in microgranite in the Preissac pluton, Québec, Canada: Relicts of aqueous fluid pockets?
- The equilibrium boundary of the reaction Mg3Al2Si3O12 + 3CO2 = Al2SiO5 + 2SiO2 + 3MgCO3 at 3–6 GPa
- Discussion
- Comment on Lee et al. (2022) “Reexamination of the structure of opal-A: A combined study of synchrotron X-ray diffraction and pair distribution function analysis”— Concerning opal
- Reply
- On “Reexamination of the structure of opal-A: A combined study of synchrotron X-ray diffraction and pair distribution function analysis”—Reply to de Jong
- American Mineralogist thanks the Reviewers for 2023
Articles in the same Issue
- Crystal chemistry and thermodynamic properties of zircon structure-type materials
- Thermal and combined high-temperature and high-pressure behavior of a natural intermediate scapolite
- Crystal structure, hydrogen bonding, and high-pressure behavior of the hydroxide perovskite MgSi(OH)6: A phase relevant to deep subduction of hydrated oceanic crust
- Equilibrium Sn isotope fractionation between aqueous Sn and Sn-bearing minerals: Constrained by first-principles calculations
- Raman spectroscopic investigation of selected natural uranyl sulfate minerals
- Modified magnetite and hydrothermal apatite in banded iron-formations and implications for high-grade Fe mineralization during retrogressive metamorphism
- Apatite trace element composition as an indicator of ore deposit types: A machine learning approach
- Identifying serpentine minerals by their chemical compositions with machine learning
- Crystal habit (tracht) of groundmass pyroxene crystals recorded magma ascent paths during the 2011 Shinmoedake eruption
- Reconstructing diagenetic mineral reactions from silicified horizons of the Paleoproterozoic Biwabik Iron Formation, Minnesota
- Mannardite as the main vanadium-hosting mineral in black shale-hosted vanadium deposits, South China
- Molybdenite-bearing vugs in microgranite in the Preissac pluton, Québec, Canada: Relicts of aqueous fluid pockets?
- The equilibrium boundary of the reaction Mg3Al2Si3O12 + 3CO2 = Al2SiO5 + 2SiO2 + 3MgCO3 at 3–6 GPa
- Discussion
- Comment on Lee et al. (2022) “Reexamination of the structure of opal-A: A combined study of synchrotron X-ray diffraction and pair distribution function analysis”— Concerning opal
- Reply
- On “Reexamination of the structure of opal-A: A combined study of synchrotron X-ray diffraction and pair distribution function analysis”—Reply to de Jong
- American Mineralogist thanks the Reviewers for 2023