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CURIES: Compendium of uranium Raman and infrared experimental spectra

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Veröffentlicht/Copyright: 30. November 2023
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Abstract

Identification of radioactive materials is a critical goal of resource exploration, basic actinide science, and nuclear forensics, and we provide here new insights toward rapid, nondestructive analysis of uranium-containing minerals and technogenic phases. Raman and infrared spectroscopic data are powerful indicators of solid-phase U(VI) coordination chemistry. In addition, U(VI) minerals exhibit high chemical and structural diversity as artifacts of geochemical processes leading to ore formation. Spectral signals of axial U O 2 2 + U O y l bond lengths and the influences of additional oxyanions on these values are well documented for uranium oxide and oxysalt minerals and technogenic phases. Additional insight regarding the underlying crystallographic structure and chemical composition of uranium materials can be extracted through a survey of all available Raman spectroscopic data for these phases. To this end, we have developed the Compendium of Uranium Raman and Infrared Experimental Spectra (CURIES). CURIES was compiled via a thorough review of literature and databases, and for mineral species that lack measured and recorded spectra, data were obtained either from museum and academic collections or by direct syntheses. Characteristic Raman spectroscopic features for subgroups of uranyl minerals within CURIES were elucidated using multivariate statistical analyses. In addition, average spectra for groups of uranyl minerals were determined, providing insight into common spectroscopic characteristics that are indicative of the structural origins from which they arise. As of publication, 275 mineral species and technogenic phases have been entered in CURIES, and of these, 83 phases have published spectra that have been included in the CURIES database. Data collection is ongoing, and we have triaged missing data sets to assess CURIES for completion and to identify mineral groups that lack representation and should therefore be prioritized for data acquisition and inclusion in the database.

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Received: 2022-07-29
Accepted: 2022-12-20
Published Online: 2023-11-30
Published in Print: 2023-12-15

© 2023 by Mineralogical Society of America

Artikel in diesem Heft

  1. Evidence for abundant organic matter in a Neoarchean banded iron formation
  2. Electrical properties of iron sulfide-bearing dunite under pressure: Effect of temperature, composition, and annealing time
  3. Gas-mediated trace element incorporation into rhyolite-hosted topaz: A synchrotron microbeam XAS study
  4. 10.2138/am-2023-8927
  5. A dunite fragment in meteorite Northwest Africa (NWA) 11421: A piece of the Moon’s mantle
  6. 10.2138/am-2023-9054
  7. Hydrogen bond symmetrization and high-spin to low-spin transition of ε-FeOOH at the pressure of Earth’s lower mantle
  8. CURIES: Compendium of uranium Raman and infrared experimental spectra
  9. S 2 and S 3 radicals and the S 4 2 polysulfide ion in lazurite, haüyne, and synthetic ultramarine blue revealed by resonance Raman spectroscopy
  10. Efect of faceting on olivine wetting properties
  11. The obscuring efect of magma recharge on the connection of volcanic-plutonic rocks
  12. In-situ study of microstructures induced by the olivine to wadsleyite transformation at conditions of the 410 km depth discontinuity
  13. Effect of pre-existing crystals and melt homogeneity on the decompression-induced crystallization of hydrous rhyodacite magma
  14. Origin of clinopyroxene-ilmenite symplectites in mafic granulites from eastern parts of the Chotanagpur granite gneissic complex, East Indian shield
  15. Single-crystal analysis of La-doped pyromorphite [Pb5(PO4)3Cl]
  16. Crystal structure of calcium-ferrite type NaAlSiO4 up to 45 GPa
  17. Revision of the CaMgSi2O6-CO2 P-T phase diagram at 3–6 GPa
Heruntergeladen am 22.4.2026 von https://www.degruyterbrill.com/document/doi/10.2138/am-2022-8738/html
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