The effect of elemental diffusion on the application of olivine-composition-based magmatic thermometry, oxybarometry, and hygrometry: A case study of olivine phenocrysts from the Jiagedaqi basalts, northeast China
-
Le Zhang
, Lu-Bing Hong
, Sheng-Ping Qian , Peng-Li He , Miao-Hong He, Ya-Nan Yang
, Jin-Tuan Wang, Yan-Qiang Zhang
and Zhong-Yuan Ren
Abstract
Olivine compositions are widely used to constrain magmatic thermodynamic conditions such as magmatic temperature, oxygen fugacity, and H2O content. However, elemental diffusion may change the initial compositions and lead to large uncertainty on the estimation of these thermodynamic conditions. In this study, we conducted LA-ICP-MS elemental mapping and EPMA analysis of olivine phenocrysts and olivine-hosted spinel from the Jiagedaqi (JGD) alkaline basalts in northeast China to evaluate the influence of elemental difusion on olivine-composition-based geothermometry, oxybarometry, and hygrometry. The JGD olivines show normal Fo [Mg/(Mg + Fe) × 100 in moles] zoning, with cores having Fo of 77–87 and rims having Fo of 67–73. The constant P contents from core to rim indicate that these compositional zonings were caused mainly by difusion. Because Al is a slow-diffusing element and its content is relatively constant from core to rim, the temperature calculated by the Al-in-olivine thermometer is not influenced by elemental difusion and preserves the JGD olivine crystallization temperature up to 1150 °C. The temperatures calculated using the Sc/Y-in-olivine thermometer, the oxygen fugacity calculated using the olivine–spinel oxybarometer, and the H2O content calculated on the basis of Ca partitioning between olivine and melt are strongly influenced by the diffusion of Fo, Sc/Y, and Ca. However, the compositional plateaus in olivine cores, which were not influenced by elemental diffusion, preserve the magmatic temperature (1150 °C), oxygen fugacity (QFM+1.4), and H2O content (4 wt%) that applied during the formation of the JGD olivines. Together, these findings suggest that the mantle source of the JGD basalts was metasomatized by fluids released from the subducted slab. This study highlights that elemental difusion in olivine phenocrysts can strongly afect the application of olivine-composition-based geothermometers, oxybarometers, and hygrometers. However, primitive olivine cores that have not been influenced by difusion preserve the initial magmatic thermodynamic conditions.
Acknowledgments and funding
The authors thank Lin-Li Chen (GIG) for assistance with EPMA analysis. This manuscript benefited much from the very constructive comments from Diego González-García, Joe Boro, Marco Brenna, and an anonymous reviewer. This study was financially supported by the National Key Research and Development Program of China (2018YFA0702600), Guangdong Basic and Applied Basic Research Foundation (2021A1515017789), the Program of Guangzhou City (202102020614), and the Director’s Fund of Guangzhou Institute of Geochemistry (2022SZJJZD-03). This is contribution no. IS-3362 from GIGCAS.
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Articles in the same Issue
- Experimental study of apatite-fluid interaction and partitioning of rare earth elements at 150 and 250 °C
- Assimilation of xenocrystic apatite in peraluminous granitic magmas
- Cathodoluminescence of iron oxides and oxyhydroxides
- The effect of elemental diffusion on the application of olivine-composition-based magmatic thermometry, oxybarometry, and hygrometry: A case study of olivine phenocrysts from the Jiagedaqi basalts, northeast China
- Characterization of nano-minerals and nanoparticles in supergene rare earth element mineralization related to chemical weathering of granites
- Atomic-scale interlayer friction of gibbsite is lower than brucite due to interactions of hydroxyls
- The spatial and temporal evolution of mineral discoveries and their impact on mineral rarity
- The role of parent lithology in nanoscale clay-mineral transformations in a subtropical monsoonal climate
- Discovery of terrestrial andreyivanovite, FeCrP, and the effect of Cr and V substitution on the low-pressure barringerite-allabogdanite transition
- Microstructural changes and Pb mobility during the zircon to reidite transformation: Implications for planetary impact chronology
- Thermal equation of state of ice-VII revisited by single-crystal X-ray diffraction
- Empirical electronic polarizabilities for use in refractive index measurements at 589.3 nm: Hydroxyl polarizabilities
- High-pressure behavior of 3.65 Å phase: Insights from Raman spectroscopy
- High-pressure phase transition and equation of state of hydrous Al-bearing silica
- Memorial of Maryellen Cameron (1943−2022)
- New Mineral Names
Articles in the same Issue
- Experimental study of apatite-fluid interaction and partitioning of rare earth elements at 150 and 250 °C
- Assimilation of xenocrystic apatite in peraluminous granitic magmas
- Cathodoluminescence of iron oxides and oxyhydroxides
- The effect of elemental diffusion on the application of olivine-composition-based magmatic thermometry, oxybarometry, and hygrometry: A case study of olivine phenocrysts from the Jiagedaqi basalts, northeast China
- Characterization of nano-minerals and nanoparticles in supergene rare earth element mineralization related to chemical weathering of granites
- Atomic-scale interlayer friction of gibbsite is lower than brucite due to interactions of hydroxyls
- The spatial and temporal evolution of mineral discoveries and their impact on mineral rarity
- The role of parent lithology in nanoscale clay-mineral transformations in a subtropical monsoonal climate
- Discovery of terrestrial andreyivanovite, FeCrP, and the effect of Cr and V substitution on the low-pressure barringerite-allabogdanite transition
- Microstructural changes and Pb mobility during the zircon to reidite transformation: Implications for planetary impact chronology
- Thermal equation of state of ice-VII revisited by single-crystal X-ray diffraction
- Empirical electronic polarizabilities for use in refractive index measurements at 589.3 nm: Hydroxyl polarizabilities
- High-pressure behavior of 3.65 Å phase: Insights from Raman spectroscopy
- High-pressure phase transition and equation of state of hydrous Al-bearing silica
- Memorial of Maryellen Cameron (1943−2022)
- New Mineral Names