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Microstructural changes and Pb mobility during the zircon to reidite transformation: Implications for planetary impact chronology

  • Ian Szumila , Dustin Trail , Timmons Erickson , Justin I. Simon , Matthew M. Wielicki , Tom Lapen , Miki Nakajima , Marc Fries and Elizabeth A. Bell
Published/Copyright: July 27, 2023
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Abstract

Impact events modify and leave behind a complex history of rock metamorphism on terrestrial planets. Evidence for an impact event may be recorded in physical changes to minerals, such as mineral deformation and formation of high P-T polymorphs, but also in the form of chemical fingerprints, such as enhanced elemental diffusion and isotopic mixing. Here we explore laboratory shock-induced physical and chemical changes to zircon and feldspar, the former of which is of interest because its trace elements abundances and isotope ratios are used extensively in geochemistry and geochronology. To this end, a granular mixture of Bishop Tuff sanidine and Kuehl Lake zircon, both with well characterized Pb isotope compositions, was prepared and then shocked via a flat plate accelerator. The peak pressure of the experiment, as calculated by the impedance matching method, was ~24 GPa although a broader range of P-T conditions is anticipated due to starting sample porosity. Unshocked and shocked materials were characterized via scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), and Raman spectroscopy. These methods show that the starting zircon material had abundant metamict regions, and the conversion of the feldspar to glass in the post-shock material. Analyses of the shocked product also yielded multiple occurrences of the high-pressure ZrSiO4 polymorph reidite, with some domains up to 300 μm across. The possibility of U-Pb system disturbance was evaluated via laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and secondary ion mass spectrometry (SIMS). The isotopic data reveal that disturbance of the U-Pb geochronometer in the reidite was minimal (<2% for the main U-Pb geochronometers). To better constrain the P-T conditions during the shock experiment, we complement impedance matching pressure calculations with iSALE2D impact simulations. The simulated results yield a range of P-T conditions experienced during the experiment and show that much of the sample may have reached >30 GPa, which is consistent with formation of reidite. In the recovered shocked material, we identified lamellae of reidite, some of which interlock with zircon lamellae. Reidite {112} twins were identified, which we interpret to have formed to reduce stress between the crystal structure of the host zircon and reidite. These two findings support the interpretation that shear transformation enabled the transition of zircon to reidite. The size and presence of reidite found here indicate that this phase is probably common in impact-shocked crustal rocks that experienced ~25 to ~35 GPa, especially when the target material has porosity. Additionally, shock loading of the zircon and transformation to reidite at these pressures in porous materials is unlikely to significantly disturb the U-Pb system in zircon and that the reidite inherits the primary U and Pb elemental and isotopic ratios from the zircon.

Funding statement: This project was partially supported by the Earth’s First Origins NASA grant 80NSSC19M0069, 80NSSC22K0107, and NASA Planetary Science funding, NASA Solar System Workings grant 80NSSC20K1039, and by NSF EAR-2102143. The ion microprobe laboratory at UCLA is partially funded by a grant from NSFEAR’s Instrumentation and Facilities Program (1734856).

Acknowledgments

We are grateful to Jacobs, the JETS contract, NASA ARES, University of Houston and University of Alabama. Many thanks are due to Roland Montes and Frank Cardenas for assistance with the mechanics and gunning of the shot and Mark Cintala for input on gunning the shot. This project benefitted from fruitful discussions with Fred Hörz. Thanks are due to Zia Rahman for FIB liftout of material for transmission-Kikuchi-diffraction EBSD at NASA JSC. The assistance of Loan Le with spot Raman analyses was beneficial. The assistance of Minako Righter with LA-ICP-MS at the University of Houston was valuable. Grain sorting and grain mounting was done by Martha Miller at the University of Rochester and this project greatly benefitted from these efforts. We appreciate Rich Martens sample preparation assistance at the University of Alabama. Thanks for laboratory assistance are due to Nicole Haney, Rick Roland, Kathleen Vander Kaaden at Johnson Space Center, and Wriju Chowdhury at the University of Rochester. We are grateful to Jay Thomas for assistance with additional Raman analyses during revisions at Syracuse University. For the impact simulations using the iSALE2D software, we gratefully acknowledge the developers of iSALE-2D, including Gareth Collins, Kai Wünnemann, Dirk Elbeshausen, Tom Davison, Boris Ivanov, and Jay Melosh.

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Received: 2022-05-19
Accepted: 2022-09-17
Published Online: 2023-07-27
Published in Print: 2023-08-28

© 2023 by Mineralogical Society of America

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