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Experimental investigation of trace element partitioning between amphibole and alkali basaltic melt: Toward a more general partitioning model with implications for amphibole fractionation at deep crustal levels

  • Barbara Bonechi ORCID logo , Alessandro Fabbrizio , Cristina Perinelli ORCID logo , Mario Gaeta and Maurizio Petrelli ORCID logo
Published/Copyright: August 31, 2023
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American Mineralogist
From the journal American Mineralogist Volume 108 Issue 9

Abstract

Time-series experiments were carried out in a piston-cylinder apparatus at 0.8 GPa and 1030–1080 °C using a hydrous K-basalt melt as the starting material to determine the element partition coefficients between amphibole and silicate glass. Major, minor, and trace element compositions of amphibole and glass were determined with a combination of electron microprobe and laser ablation inductively coupled plasma mass spectrometry. Results show that the main mineral phase is calcic amphibole, and the coexisting glass compositions range from basaltic trachyandesite to andesite. We estimated the ideal radius, the maximum partition coefficient and the apparent Young’s modulus of the A, M1-M2-M3, and M4-M4′ sites of amphibole. The influence of melt and amphibole composition, temperature, and pressure on the partition coeficients between amphiboles and glasses has also been investigated by comparing our data with a literature data set spanning a wide range of pressures (0.6–2.5 GPa), temperatures (780–1100 °C), and compositions (from basanite to rhyolite). Finally, we modeled a deep fractional crystallization process using the amphibole-melt partition coeficients determined in this study, observing that significant amounts of amphibole crystallization (>30 wt%) well reproduce the composition of an andesitic melt similar to that of the calc-alkaline volcanic products found in Parete and Castelvolturno boreholes (NW of Campi Flegrei, Italy).

Keywords: Amphibole; trace element partition coefficient; lattice strain model; Campi Flegrei

Acknowledgments and funding

We warmly thank the reviewers K. Putirka and J. Brenan, for their very helpful, constructive, and resolutive comments. The Associate Editor, C.E. Lesher, is acknowledged for the editorial work. We thank M. Albano and M. Serracino (CNR-IGAG), and R. Jedlicka and M. Racek (Institute of Petrology and Structural Geology, Charles University of Prague) for assistance during SEM and EPMA analytical sessions. This research has been conducted with the financial support of the HP-HT Laboratory at the Department of Earth Sciences of Sapienza, University of Rome. B.B. acknowledges financial support from “Fondi Avvio alla ricerca Tipo 2”. This research was supported by the Grant Agency of Czech Republic (GAČR, grant number 23-04734S to A.F.). M.P. acknowledges the MIUR-PRIN 2020 (202037YPCZ_001), Project “Dynamics and timescales of volcanic plumbing systems: a multidisciplinary approach to multifaceted problem.”

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Received: 2022-03-23
Accepted: 2022-10-12
Published Online: 2023-08-31
Published in Print: 2023-09-26

© 2023 by Mineralogical Society of America

Articles in the same Issue

  1. Fluorine-rich mafic lower crust in the southern Rocky Mountains: The role of pre-enrichment in generating fluorine-rich silicic magmas and porphyry Mo deposits
  2. Apatite in brachinites: Insights into thermal history and halogen evolution
  3. A high-pressure structural transition of norsethite-type BaFe(CO3)2: Comparison with BaMg(CO3)2 and BaMn(CO3)2
  4. An evolutionary system of mineralogy, Part VII: The evolution of the igneous minerals (>2500 Ma)
  5. Oriented secondary magnetite micro-inclusions in plagioclase from oceanic gabbro
  6. A multi-methodological study of the bastnäsite-synchysite polysomatic series: Tips and tricks of polysome identification and the origin of syntactic intergrowths
  7. Petrogenesis of Chang’E-5 mare basalts: Clues from the trace elements in plagioclase
  8. Experimental investigation of trace element partitioning between amphibole and alkali basaltic melt: Toward a more general partitioning model with implications for amphibole fractionation at deep crustal levels
  9. Grain-scale zircon Hf isotope heterogeneity inherited from sediment-metasomatized mantle: Geochemical and Nd-Hf-Pb-O isotopic constraints on Early Cretaceous intrusions in central Lhasa Terrane, Tibetan Plateau
  10. Mechanism and kinetics of the pseudomorphic replacement of anhydrite by calcium phosphate phases at hydrothermal conditions
  11. Vacancy infilling during the crystallization of Fe-deficient hematite: An in situ synchrotron X-ray diffraction study of non-classical crystal growth
  12. Simulated diagenesis of the iron-silica precipitates in banded iron formations
  13. Wave vector and field vector orientation dependence of Fe K pre-edge X-ray absorption features in clinopyroxenes
  14. Structure and compressibility of Fe-bearing Al-phase D
  15. Synthesis of boehmite-type GaOOH: A new polymorph of Ga oxyhydroxide and geochemical implications
  16. Scheelite U-Pb geochronology and trace element geochemistry fingerprint W mineralization in the giant Zhuxi W deposit, South China
  17. A rare sekaninaite occurrence in the Nenana Coal Basin, Alaska Range, Alaska
  18. Slyudyankaite, Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2)·2H2O, a new sodalite-group mineral from the Malo-Bystrinskoe lazurite deposit, Baikal Lake area, Russia
  19. Ruizhongite, (Ag2□)Pb3Ge2S8, a thiogermanate mineral from the Wusihe Pb-Zn deposit, Sichuan Province, Southwest China
https://doi.org/10.2138/am-2022-8536
Keywords for this article
Amphibole; trace element partition coefficient; lattice strain model; Campi Flegrei

Articles in the same Issue

  1. Fluorine-rich mafic lower crust in the southern Rocky Mountains: The role of pre-enrichment in generating fluorine-rich silicic magmas and porphyry Mo deposits
  2. Apatite in brachinites: Insights into thermal history and halogen evolution
  3. A high-pressure structural transition of norsethite-type BaFe(CO3)2: Comparison with BaMg(CO3)2 and BaMn(CO3)2
  4. An evolutionary system of mineralogy, Part VII: The evolution of the igneous minerals (>2500 Ma)
  5. Oriented secondary magnetite micro-inclusions in plagioclase from oceanic gabbro
  6. A multi-methodological study of the bastnäsite-synchysite polysomatic series: Tips and tricks of polysome identification and the origin of syntactic intergrowths
  7. Petrogenesis of Chang’E-5 mare basalts: Clues from the trace elements in plagioclase
  8. Experimental investigation of trace element partitioning between amphibole and alkali basaltic melt: Toward a more general partitioning model with implications for amphibole fractionation at deep crustal levels
  9. Grain-scale zircon Hf isotope heterogeneity inherited from sediment-metasomatized mantle: Geochemical and Nd-Hf-Pb-O isotopic constraints on Early Cretaceous intrusions in central Lhasa Terrane, Tibetan Plateau
  10. Mechanism and kinetics of the pseudomorphic replacement of anhydrite by calcium phosphate phases at hydrothermal conditions
  11. Vacancy infilling during the crystallization of Fe-deficient hematite: An in situ synchrotron X-ray diffraction study of non-classical crystal growth
  12. Simulated diagenesis of the iron-silica precipitates in banded iron formations
  13. Wave vector and field vector orientation dependence of Fe K pre-edge X-ray absorption features in clinopyroxenes
  14. Structure and compressibility of Fe-bearing Al-phase D
  15. Synthesis of boehmite-type GaOOH: A new polymorph of Ga oxyhydroxide and geochemical implications
  16. Scheelite U-Pb geochronology and trace element geochemistry fingerprint W mineralization in the giant Zhuxi W deposit, South China
  17. A rare sekaninaite occurrence in the Nenana Coal Basin, Alaska Range, Alaska
  18. Slyudyankaite, Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2)·2H2O, a new sodalite-group mineral from the Malo-Bystrinskoe lazurite deposit, Baikal Lake area, Russia
  19. Ruizhongite, (Ag2□)Pb3Ge2S8, a thiogermanate mineral from the Wusihe Pb-Zn deposit, Sichuan Province, Southwest China
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