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A high-pressure structural transition of norsethite-type BaFe(CO3)2: Comparison with BaMg(CO3)2 and BaMn(CO3)2

  • Chengcheng He ORCID logo , Chaoshuai Zhao , Jianjun Jiang , Pan Wang and Heping Li
Published/Copyright: August 31, 2023
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American Mineralogist
From the journal American Mineralogist Volume 108 Issue 9

Abstract

Investigations on the phase stability of the norsethite-type family [BaMg(CO3)2, BaMn(CO3)2, BaFe(CO3)2] under high-pressure conditions are of great significance for understanding the structure and metal cationic (Mg2+, Fe2+, Mn2+) substitution mechanism in double divalent metal carbonates. The structural evolution and equation of state of BaFe(CO3)2 were studied at high pressure up to ~7.3 GPa by synchrotron X-ray diffraction (XRD) in diamond-anvil cell (DAC) in this study. BaFe(CO3)2 undergoes a reversible phase transition from R3̄m (α-phase) to C2/c (γ-phase) space groups at ~3.0 GPa. The fitted elastic parameters are V0 = 377.79(2) Å3 and K0 = 40.3(7) GPa for α-BaFe(CO3)2, V0 = 483.24(5) Å3 and K0 = 91.2(24) GPa for γ-BaFe(CO3)2 using second-order Birch-Murnaghan equation of state (BM2-EoS). Besides, the vibrational properties and structural stability of complete norsethite-type minerals were also investigated first by Raman spectroscopy combined with DAC up to 11.1 GPa. Similar structural phase transitions occur in BaMg(CO3)2, BaFe(CO3)2, BaMn(CO3)2 at 2.2–2.6, 2.6–3.7, and 3.7–4.1 GPa, respectively. The onset phase transition pressures of the norsethite-type family are much lower than that of dolomite-type Ca(Mg,Fe,Mn)(CO3)2 and calcite-type (Mg,Fe,Mn)CO3 carbonates. These results provide new insights into the divalent cation substitution effects on the stability and structural evolution of carbonates under high-pressure conditions.

Keywords: Norsethite-type minerals; synchrotron X-ray diffraction; Raman spectroscopy; phase transition; diamond anvil cell; Earth Analogs for Martian Geological Materials and Processes

† Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html.

Funding statement: This study was supported by the Strategic Priority Research Program (B) of the Chinese Academy of Sciences (XDB 18010401), the Chinese Academy of Sciences “Light of West China” Program (2019), and the National Natural Science Foundation of China (NSFC grant no. 42104101).

Acknowledgments

We appreciate two anonymous reviewers for their constructive suggestions and comments, which helped improve the manuscript significantly. We thank Wen Liang for providing the norsethite samples and guidance on the experiments. We acknowledge Dawei Fan, Zhilin Ye, and Shijie Huang for the in situ X-ray diffraction measurements. We are also grateful for the support of beamline scientists at BL15U1 of SSRF.

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Received: 2022-07-21
Accepted: 2022-10-27
Published Online: 2023-08-31
Published in Print: 2023-09-26

© 2023 by Mineralogical Society of America

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https://doi.org/10.2138/am-2022-8722
Keywords for this article
Norsethite-type minerals; synchrotron X-ray diffraction; Raman spectroscopy; phase transition; diamond anvil cell; Earth Analogs for Martian Geological Materials and Processes

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  15. Synthesis of boehmite-type GaOOH: A new polymorph of Ga oxyhydroxide and geochemical implications
  16. Scheelite U-Pb geochronology and trace element geochemistry fingerprint W mineralization in the giant Zhuxi W deposit, South China
  17. A rare sekaninaite occurrence in the Nenana Coal Basin, Alaska Range, Alaska
  18. Slyudyankaite, Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2)·2H2O, a new sodalite-group mineral from the Malo-Bystrinskoe lazurite deposit, Baikal Lake area, Russia
  19. Ruizhongite, (Ag2□)Pb3Ge2S8, a thiogermanate mineral from the Wusihe Pb-Zn deposit, Sichuan Province, Southwest China
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