Manjiroite or hydrous hollandite?
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Jeffrey E. Post
Abstract
In this study, we investigated an unusual natural Mn oxide hollandite-group mineral from the Kohare Mine, Iwate Prefecture, Japan, that has predominantly water molecules in the tunnels, with K, Na, Ca, and Ba. The specimens are labeled as type manjiroite, but our analyses show that Na is not the dominant tunnel species, nor is it even the primary tunnel cation, suggesting either an error in the original analyses or significant compositional variation within samples from the type locality. Chemical analyses, X‑ray photoelectron spectroscopy, and thermal gravimetric analysis measurements combined with Rietveld refinement results using synchrotron X‑ray powder diffraction data suggest the chemical formula:
Funding statement: Funding for this work was provided by NSF EAR1925903. This research also utilized samples from the Smithsonian Mineral Research Collection at the Museum of Natural History. The FTIR laboratory at the Smithsonian Institution was established with generous support from Stephen Turner. This research used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357. ESI is supported by the PNNL managed Geosciences Research Program of the U.S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. The research was performed in part using the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the U.S. DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for DOE by Battelle Memorial Institute under Contract No. DE-AC06-76RLO-1830. We also acknowledge support from NSF EAR11-47728.
References cited
Akkopru-Akgun, B., Trolier-McKinstry, S., and Lanagan, M.T. (2015) MnO2 thin film electrodes for enhanced reliability of thin glass capacitors. Journal of the American Ceramic Society, 98, 3270–3279.10.1111/jace.13774Suche in Google Scholar
Baur, W.H. (1972) Prediction of hydrogen bonds and hydrogen atom positions in crystalline solids. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 28, 1456–1465.10.1107/S0567740872004455Suche in Google Scholar
Brown, G.E., Sueno, S., and Prewitt, C.T. (1973) A new single-crystal heater for the precession camera and four-circle diffractometer. American Mineralogist, 58, 698–704.Suche in Google Scholar
Bruce, P.G., Freunberge, S.A., Hardwick, L.J., and Tarascon, J.-M. (2012) Li-O2 and Li-S batteries with high energy storage. Nature Materials, 11, 19–29.10.1038/nmat3191Suche in Google Scholar PubMed
Carmichael, S.K., Doctor, D.H., Wilson, C.G., Feierstein, J., and McAleer, R.J. (2017) New insight into the origin of manganese oxide ore deposits in the Appalachian Valley and Ridge of northeastern Tennessee and northern Virginia, U.S.A. Geological Society of America Bulletin, 129, B31682.1–1180.10.1130/B31682.1Suche in Google Scholar
Chen, C.C., Golden, D.C., and Dixon, J.B. (1986) Transformation of synthetic birnessite to cryptomelane—an electron-microscopic study. Clays and Clay Minerals, 34, 565–571.10.1346/CCMN.1986.0340510Suche in Google Scholar
Feng, Q., Kanoh, H., Miyai, Y., and Ooi, K. (1995) Alkali metal ions insertion/extraction reactions with hollandite-type manganese oxide in the aqueous phase. Chemistry of Materials, 7, 148–153.10.1021/cm00049a023Suche in Google Scholar
Grangeon, S., Lanson, B., and Lanson, M. (2014) Solid-state transformation of nano-crystalline phyllomanganate into tectomanganate: influence of initial layer and interlayer structure. Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 70, 828–838.10.1107/S2052520614013687Suche in Google Scholar PubMed
Grangeon, S., Fernandez-Martinez, A., Warmont, F., Gloter, A., Marty, N., Poulain, A., and Lanson, B. (2015) Cryptomelane formation from nanocrystalline vernadite precursor: A high energy X-ray scattering and transmission electron microscopy perspective on reaction mechanisms. Geochemical Transactions, 16, 12.10.1186/s12932-015-0028-ySuche in Google Scholar PubMed PubMed Central
Gruner, J.W. (1943) The chemical relationship of cryptomelane (psilomelane), hollandite, and coronadite. American Mineralogist, 28, 497–506.Suche in Google Scholar
Gutzmer, J., and Beukes, N.J. (2000) Asbestiform manjiroite and todorokite from the Kalahari manganese field, South Africa. South African Journal of Geology, 103, 163–174.10.2113/1030163Suche in Google Scholar
Hammersley, A.P., Svensson, S.O., Hanfland, M., Fitch, A.N., and Hausermann, D. (1996) Two-dimensional detector software: From real detector to idealized image or two-theta scan. High Pressure Research, 14, 235–248.10.1080/08957959608201408Suche in Google Scholar
Ilton, E.S., Post, J.E., Heaney, P.J., Ling, F.T., and Kerisit, S.N. (2016) XPS determination of Mn oxidation states in Mn (hydr) oxides. Applied Surface Science, 366, 475–485.10.1016/j.apsusc.2015.12.159Suche in Google Scholar
Johnson, C.S., Dees, D.W., Mansuetto, M.F., Thackeray, M.M., Vissers, D.R., Argyriou, D., Loong, C.K., and Christensen, L. (1997) Structural and electrochemical studies of alpha-manganese dioxide (αMnO2). Journal of Power Sources, 68, 570–577.10.1016/S0378-7753(96)02633-XSuche in Google Scholar
Kijima, N., Takahashi, Y., Akimoto, J., and Awaka, J. (2005) Lithium ion insertion and extraction reactions with hollandite-type manganese dioxide free from any stabilizing cations in its tunnel cavity. Journal of Solid State Chemistry, 178, 2741–2750.10.1016/j.jssc.2005.06.023Suche in Google Scholar
Meisser, N., Perseil, E., Brugger, J., and Chiappero, P. (1999) Strontiomelane, SrMn64+Mn23+O16, a new mineral species of the cryptomelane group from St. Marcel–Praborna, Aosta Valley, Italy. Canadian Mineralogist, 37, 673–678.Suche in Google Scholar
Nambu, M., and Tanida, K. (1967) Manjiroite, new manganese dioxide mineral, from Kohare Mine, Iwate Prefecture, Japan. The Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists, 58, 39–54.10.2465/ganko1941.58.39Suche in Google Scholar
Nambu, M., and Tanida, K. (1980) Cryptomelane-Manjiroite-Hollandite Series Minerals. Journal of the Mineralogical Society of Japan, 14, 62–85 (in Japanese).10.2465/gkk1952.14.Special3_62Suche in Google Scholar
Post, J.E., and Bish, D.L. (1989) Rietveld refinement of the coronadite structure. American Mineralogist, 74, 913–917.Suche in Google Scholar
Post, J.E., and Burnham, C.W. (1986) Modeling tunnel-cation displacements in hollandites using structure-energy calculations. American Mineralogist, 71, 1178–1185.Suche in Google Scholar
Post, J.E. (1999) Manganese oxide minerals: crystal structures and economic and environmental significance. Proceedings of the National Academy of Sciences of the United States of America, 96, 3447–3454.10.1073/pnas.96.7.3447Suche in Google Scholar
Post, J.E., and Buchwald, V.F. (1991) Crystal structure refinement of akageneite. American Mineralogist, 76, 272–277.Suche in Google Scholar
Post, J.E., Von Dreele, R.B., and Buseck, P.R. (1982) Symmetry and cation displacements in hollandites: structure refinements of hollandite, cryptomelane and priderite. Acta Crystallographica, 38, 1056–1065.10.1107/S0567740882004968Suche in Google Scholar
Post, J.E., Heaney, P.J., Von Dreele, R.B., and Hanson, J.C. (2003) Neutron and temperature-resolved synchrotron X-ray powder diffraction study of akaganéite. American Mineralogist, 88, 782–788.10.2138/am-2003-5-607Suche in Google Scholar
Potter, R.M., and Rossman, G.R. (1979) The tetravalent manganese oxides: identification, hydration, and structural relationships by infrared spectroscopy. American Mineralogist, 64, 1199–1218.Suche in Google Scholar
Rietveld, H.M. (1969) A profile refinement method for nuclear and magnetic structures. Journal of Applied Crystallography, 2, 65–71.10.1107/S0021889869006558Suche in Google Scholar
Rossouw, M.H., Liles, D.C., Thackeray, M.M., David, W.I.F., and Hull, S. (1992) Alpha manganese-dioxide for lithium batteries—A structural and electrochemical study. Materials Research Bulletin, 27, 221–230.10.1016/0025-5408(92)90216-MSuche in Google Scholar
Sauvage, F., Laffont, L., Tarascon, J.-M., and Baudrin, E. (2007) Study of the insertion/deinsertion mechanism of sodium into Na0.44MnO2. Inorganic Chemistry, 46, 3289−–3294.Suche in Google Scholar
Shannon, R.D. (1976) Revised effective ionic radii and systematic studies of interatomie distances in halides and chaleogenides. Acta Crystallographica Section A, 32, 751–767.10.1107/S0567739476001551Suche in Google Scholar
Stephens, P.W. (1999) Phenomenological model of anisotropic peak broadening in powder diffraction. Journal of Applied Crystallography, 32, 281–289.10.1107/S0021889898006001Suche in Google Scholar
Szymański, J.T. (1986) The crystal structure of mannardite, a new hydrated cryptomelane-group (hollandite) mineral with a doubled short axis. Canadian Mineralogist, 24, 67–78.Suche in Google Scholar
Thompson, P., Cox, D.E., and Hastings, J.B. (1987) Rietveld refinement of Debye-Scherrer synchrotron X-ray data from Al2O3. Journal of Applied Crystallography, 20, 79–83.10.1107/S0021889887087090Suche in Google Scholar
Toby, B.H., and Von Dreele, R.B. (2013) GSAS-II: The genesis of a modern open-source all purpose crystallography software package. Journal of Applied Crystallography, 46, 544–549.10.1107/S0021889813003531Suche in Google Scholar
Tompsett, D.A., and Islam, M.S. (2013) Electrochemistry of Hollandite α-MnO2: Li-Ion and Na-Ion Insertion and Li2O Incorporation. Chemistry of Materials, 25, 2515–2526.10.1021/cm400864nSuche in Google Scholar
Yang, Z., Trahey, L., Ren, Y., Chan, M.K.Y., Lin, C., Okasinski, J., and Thackeray, M.M. (2015) In situ high-energy synchrotron X-ray diffraction studies and first principles modeling of α-MnO2 electrodes in Li-O2 and Li-ion coin cells. Journal of Materials Chemistry A, 3, 7389−–7398.10.1039/C4TA06633BSuche in Google Scholar
Yang, Z., Ford, D.C., Park, J.S., Ren, Y., Kim, S., Kim, H., Fister, T.T., Chan, M.K.Y., and Thackeray, M.M. (2017) Probing the Release and Uptake of Water in α-MnO2·xH2O. Chemistry of Materials, 29, 1507–1517.10.1021/acs.chemmater.6b03721Suche in Google Scholar
Zhang, R., Yu, X., Nam, K.-W., Ling, C., Arthur, T.S., Song, W., Knapp, A.M., Ehrlich, S.N., Yang, X.-Q., and Matsui, M. (2012) α-MnO2 as a cathode material for rechargeable Mg batteries. Electrochemistry Communications, 23, 110–113.10.1016/j.elecom.2012.07.021Suche in Google Scholar
© 2022 Mineralogical Society of America
Artikel in diesem Heft
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Artikel in diesem Heft
- Perspectives
- Resolving the conundrum of equilibrium solubility of smectites
- Manjiroite or hydrous hollandite?
- Petrologic evolution of boninite lavas from the IBM Fore-arc, IODP Expedition 352: Evidence for open-system processes during early subduction zone magmatism
- Coupled hydrogen and fluorine incorporation in garnet: New constraints from FTIR, ERDA, SIMS, and EPMA
- Incorporation mechanism of structurally bound gold in pyrite: Insights from an integrated chemical and atomic-scale microstructural study
- The electrical conductivity of albite feldspar: Implications for oceanic lower crustal sequences and subduction zones
- A high-pressure, clinopyroxene-structured polymorph of albite in highly shocked terrestrial and meteoritic rocks
- Water in the crystal structure of CaSiO3 perovskite
- Release of chromite nanoparticles and their alteration in the presence of Mn-oxides
- The absorption indicatrix as an empirical model to describe anisotropy in X-ray absorption spectra of pyroxenes
- Atomistic mechanism of cadmium incorporation into hydroxyapatite
- Copper isotope evidence for a Cu-rich mantle source of the world-class Jinchuan magmatic Ni-Cu deposit
- Gamma radiation effects on quartz Al and Ti center electron spin resonance signal intensity: Implications for quartz provenance discrimination
- A new high-pressure experimental apparatus to study magmatic processes at precisely controlled redox conditions
- Effect of structural water on the elasticity of orthopyroxene
- Cryogenic heat capacity measurements and thermodynamic analysis of lithium aluminum layered double hydroxides (LDHs) with intercalated chloride
- A theoretical and experimental investigation of hetero- vs. homo-connectivity in barium silicates
- Radiation-induced changes in vanadium speciation in basaltic glasses: Implications for oxybarometry measurements using vanadium K-edge X-ray absorption spectroscopy
- The crystal structure of Fe2S at 90 GPa based on single-crystal X-ray diffraction techniques
- Hydration-driven stabilization and volume collapse of grain boundaries in Mg2SiO4 forsterite predicted by first-principles simulations
- Kinetics of dehydrogenation of riebeckite Na2Fe23+Fe32+Si8O22(OH)2: An HT-FTIR study
- Ferro-tschermakite with polysomatic chain-width disorder identified in silician magnetite from Wirrda Well, South Australia: A HAADF STEM study
- New Mineral Names: High-Pressure and Precious Minerals
