Startseite Characterization of modified mineral waste material adsorbent as affected by thermal treatment for optimizing its adsorption of lead and methyl orange
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Characterization of modified mineral waste material adsorbent as affected by thermal treatment for optimizing its adsorption of lead and methyl orange

  • Lingcheng Su , Jiajun Chen , Huada Ruan , Dongqi Chen , Xi Chen und Chiuhong Lee
Veröffentlicht/Copyright: 20. September 2020
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen
American Mineralogist
Aus der Zeitschrift American Mineralogist Band 105 Heft 9

Abstract

Thermal treatment is one of the most common processes in mineral modification, and this process has been applied to the modification of mineral waste material to improve its adsorption ability of methyl orange (MO) and lead (Pb) in this study. The properties of modified mineral waste material (MMWM) before and after thermal modification were characterized by using the Brunauer–Emmett–Teller (BET) N2 adsorption/desorption measurement, field emission scanning electron microscope (FESEM) coupled with energy-dispersive X‑ray (EDX), X‑ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). Phase transformation was investigated related to the change in surface morphology and dehydroxylation that occurred in MMWM samples during the process of thermal treatment. To study adsorption performances of Pb and MO onto the newly modified MMWM, several experiments were carried out under different adsorption conditions and the results were determined using inductively coupled plasma optical emission spectrometry (ICP-OES) and UV-Vis spectrophotometry. The thermally treated MMWM samples showed morphological transformation and an increasing trend in BET specific surface area (SSA) up to 500 °C followed by a decreasing trend till 1000 °C. Thermal modification of MMWM successfully improved Pb adsorption from 349 to 515 mg/g, corresponding to the MMWM modified at 600 °C, and the methyl orange (MO) adsorption from 68 to 87.6 mg/g at 400 °C. The adsorptions of Pb and MO were mainly chemisorption and monolayer coverage, as the pseudo-second-order model and the Langmuir equation displayed good correlations for Pb and MO adsorption data.

Keywords: Adsorption; dehydroxylation; lead (Pb); methyl orange (MO); modified mineral waste material (MMWM)

  1. Funding

    This research was financially supported by the Beijing Normal University-Hong Kong University United International College (UIC), under the Research Project R201710 and the Zhuhai Key Laboratory Research Fund R1053. The XRD and FESEM used in this work was supported by the Institute of Advanced Materials (IAM) with funding from the Special Equipment Grant from the University Grants Committee of the Hong Kong Special Administrative Region, China (SEG_HKBU06).

References cited

Adebowale, K.O., Unuabonah, E.I., and Olu-Owolabi, B.I. (2008) Kinetic and thermodynamic aspects of the adsorption of Pb2+ and Cd2+ ions on tripolyphosphate-modified kaolinite clay. Chemical Engineering Journal, 136, 99–107. https://doi.org/10.1016/j.cej.2007.03.012.10.1016/j.cej.2007.03.012Suche in Google Scholar

Alvarez-Ayuso, E., and Garćia-Sánchez, A. (2003) Removal of heavy metals from waste waters by natural and Na-exchanged bentonites. Clays and Clay Minerals, 51, 475–480. https://doi.org/10.1346/CCMN.2003.0510501.10.1346/CCMN.2003.0510501Suche in Google Scholar

Belzunces, B., Hoyau, S., Benoit, M., Tarrat, N., and Bessac, F. (2017) Theoretical study of the atrazine pesticide interaction with pyrophyllite and Ca2+-mont-morillonite clay surfaces. Journal of Computational Chemistry, 38, 133–143. https://doi.org/10.1002/jcc.24530.10.1002/jcc.24530Suche in Google Scholar PubMed

Bhatnagar, A., Jain, A.K., Minocha, A.K., and Singh, S. (2006) Removal of lead ions from aqueous solutions by different types of industrial waste materials: equilibrium and kinetic studies. Separation Science and Technology, 41, 1881–1892. https://doi.org/10.1080/01496390600725828.10.1080/01496390600725828Suche in Google Scholar

Bhattacharyya, K.G., and Gupta, S.S. (2008) Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: a review. Advances in Colloid and Interface Science, 140, 114–131. https://doi.org/10.1016/j.cis.2007.12.008.10.1016/j.cis.2007.12.008Suche in Google Scholar PubMed

Brown, G. and Brindley, G.W. (1980) Xray diffraction procedures for clay mineral identification. In G.W. Brindley and G. Brown, Eds., Crystal structures of clay minerals and their X-ray identification, p. 305–356. Mineralogical Society of London. https://doi.org/10.1180/mono-5.5.10.1180/mono-5.5Suche in Google Scholar

Chen, H., Zhong, A., Wu, J., Zhao, J., and Yan, H. (2012) Adsorption behaviors and mechanisms of methyl orange on heat-treated palygorskite clays. Industrial & Engineering Chemistry Research, 51, 14026–14036. https://doi.org/10.1021/ie300702j10.1021/ie300702jSuche in Google Scholar

Csáki, Š., Trnovcová, V., Štubňa, I., Ondruška, J., Sunitrová, I., Vozár, L., and Dobroň, P. (2017) AC conductivity of an illitic clay with zeolite addition after firing at different temperatures. Proceeding of AIP Conference Proceedings 1866, 040008. American Institute of Physics. https://doi.org/10.1063/1.4994488.10.1063/1.4994488Suche in Google Scholar

Eljiedi, A.A.A., and Kamari, A. (2017) Removal of methyl orange and methylene blue dyes from aqueous solution using lala clam (Orbicularia orbiculata) shell. Proceeding of AIP Conference Proceedings, 1847, 040003. American Institute of Physics. https://doi.org/10.1063/1.4983899.10.1063/1.4983899Suche in Google Scholar

Elkhalifah, A.E., Bustam, M.A., and Murugesan, T. (2013) Thermal properties of different transition metal forms of montmorillonite intercalated with mono-, di-, and triethanol ammonium compounds. Journal of Thermal Analysis and Calorimetry, 112, 929–935. https://doi.org/10.1007/s10973-012-2657-z10.1007/s10973-012-2657-zSuche in Google Scholar

Etci, Ö., Bektaş, N., and Öncel, M.S. (2010) Single and binary adsorption of lead and cadmium ions from aqueous solution using the clay mineral beidellite. Environmental Earth Sciences, 61, 231–240. https://doi.org/10.1007/s12665-009-0338-4.10.1007/s12665-009-0338-4Suche in Google Scholar

Fonseca, C.G., Vaiss, V.S., Wypych, F., Diniz, R., and Leitão, A.A. (2017) Structural and thermodynamic investigation of the hydration-dehydroxylation dehydroxylation process of Na+-montmorillonite using DFT calculations. Applied Clay Science, 143, 212–219. https://doi.org/10.1016/j.clay.2017.03.025.10.1016/j.clay.2017.03.025Suche in Google Scholar

Frost, R.L., Horváth, E., Makó, É., and Kristóf, J. (2004) Modification of low- and high-defect kaolinite surfaces: implications for kaolinite mineral processing. Journal of Colloid and Interface Science, 270, 337–346. https://doi.org/10.1016/j.jcis.2003.10.034.10.1016/j.jcis.2003.10.034Suche in Google Scholar PubMed

Freundlich, H. (1907) Über die adsorption in lösungen. Zeitschrift für physikalische Chemie, 57, 385–470. https://doi.org/10.1515/zpch-1907-5723.10.1515/zpch-1907-5723Suche in Google Scholar

Guggenheim, S., Cn, Y.H., and Van Gnoos, L.A.K. (1987) Muscovite dehydroxylation: High-temperature studies. American Mineralogist, 72, 537–550.Suche in Google Scholar

Gupta, S.S., and Bhattacharyya, K.G. (2005) Interaction of metal ions with clays: I. A case study with Pb (II). Applied Clay Science, 30, 199–208. https://doi.org/10.1016/j.clay.2005.03.008.10.1016/j.clay.2005.03.008Suche in Google Scholar

Habiba, U., Siddique, T.A., Joo, T.C., Salleh, A., Ang, B.C., and Afifi, A.M. (2017) Synthesis of chitosan/polyvinyl alcohol/zeolite composite for removal of methyl orange, Congo red and chromium (VI) by flocculation/adsorp-tion. Carbohydrate Polymers, 157, 1568–1576. https://doi.org/10.1016/j.carbpol.2016.11.037.10.1016/j.carbpol.2016.11.037Suche in Google Scholar PubMed

Húlan, T., Trník, A., and Medveď, I. (2017) Kinetics of thermal expansion of illite-based ceramics in the dehydroxylation region during heating. Journal of Thermal Analysis and Calorimetry, 127, 291–298. https://doi.org/10.1007/s10973-016-5873-0.10.1007/s10973-016-5873-0Suche in Google Scholar

Hurlbut, C.S., and Klein, C. (1977) Manual of Mineralogy (after James D. Dana), pp. 429. Wiley.Suche in Google Scholar

Jiang, Y.N., Ruan, H.D., Lai, S.Y., Lee, C.H., Yu, C.F., Wu, Z., and He, S. (2013a) Recycling of solid waste material in Hong Kong: I. Properties of modified clay mineral waste material and its application for removal of cadmium in water. Earth Science, 2, 40–46. https://doi.org/10.11648/j.earth.20130202.13.10.11648/j.earth.20130202.13Suche in Google Scholar

Jiang, Y.N., Ruan, H.D., Zhang, G.F., Lai, S.Y., Lee, C.H., Yu, C.F., and He, S. (2013b) Recycling of solid waste material: II. phosphate adsorption by modified clay mineral waste material relating to remediation of eutrophication in aquatic systems. Proceedings of International Congress on Engineering and Information, 42. SAR, Hong Kong.10.11648/j.earth.20130202.13Suche in Google Scholar

Jiang, Y.N., Su, L.C., Ruan, H.D., Zhang, G.F., Lai, S.Y., Lee, C.H., and He, S. (2014) Adsorption of phosphorus by modified clay mineral waste material relating to removal of it from aquatic system. International Journal of Environmental Monitoring and Analysis, 2, 36–44. https://doi.org/10.11648/j.ijema.20140201.14.10.11648/j.ijema.20140201.14Suche in Google Scholar

Kelley, F.R. (1957) Field Trip to the Ione Clay Area1 Held in Conjunction with the sixth national clay conference August 21, 1957. Clays and Clay Minerals, 6, 1–17. https://doi.org/10.1346/CCMN.1957.0060102.10.1346/CCMN.1957.0060102Suche in Google Scholar

Kremer, B., Kazmierczak, J., and Stal, L.J. (2008) Calcium carbonate precipitation in cyanobacterial mats from sandy tidal flats of the North Sea. Geobiology, 6, 46–56.10.1111/j.1472-4669.2007.00128.xSuche in Google Scholar

Krupskaya, V.V., Zakusin, S.V., Tyupina, E.A., Dorzhieva, O.V., Zhukhlistov, A.P., Belousov, P.E., and Timofeeva, M.N. (2017) Experimental study of montmorillonite structure and transformation of its properties under treatment with inorganic acid solutions. Minerals, 7, 49. https://doi.org/10.3390/min7040049.10.3390/min7040049Suche in Google Scholar

Langmuir, I. (1916) The constitution and fundamental properties of solids and liquids. Part I. Solids. Journal of the American Chemical Society, 38, 2221–2295. https://doi.org/10.1021/ja02268a002.10.1016/S0016-0032(17)90938-XSuche in Google Scholar

Langmuir, I. (1917) The constitution and fundamental properties of solids and liquids. II. Liquids. Journal of the American Chemical Society, 39, 1848–1906. https://doi.org/10.1021/ja02254a006.10.1016/S0016-0032(17)90938-XSuche in Google Scholar

Leodopoulos, C., Doulia, D., Gimouhopoulos, K., and Triantis, T.M. (2012) Single and simultaneous adsorption of methyl orange and humic acid onto bentonite. Applied Clay Science, 70, 84–90. https://doi.org/10.1016/j.clay.2012.08.005.10.1016/j.clay.2012.08.005Suche in Google Scholar

Liu, B., Wang, X., Yang, B., and Sun, R. (2011) Rapid modification of montmorillonite with novel cationic Gemini surfactants and its adsorption for methyl orange. Materials Chemistry and Physics, 130, 1220–1226. https://doi.org/10.1016/j.matchemphys.2011.08.064.10.1016/j.matchemphys.2011.08.064Suche in Google Scholar

Lounis, Z., Saddouki, S., and Djafri, F. (2012) Removal of Pb2+ ions in aqueous phase by a sodic montmorillonite. Journal of Analytical Science & Technology, 3, 104–112. https://doi.org/10.5355/JAST.2012.104.10.5355/JAST.2012.104Suche in Google Scholar

Lu, H.R., Su, L.C., and Ruan, H.D. (2016) Removal of Pb, Cd, and Cr in a water purification system using modified mineral waste materials and activated carbon derived from waste materials. Proceeding of IOP Conference Series: Earth and Environmental Science. 39, 1755–1315. IOP Publishing. https://doi.org/10.1088/1755-1315/39/1/012005.10.1088/1755-1315/39/1/012005Suche in Google Scholar

Luo, Z., Gao, M., Ye, Y., and Yang, S. (2015) Modification of reduced-charge montmorillonites by a series of gemini surfactants: characterization and application in methyl orange removal. Applied Surface Science, 324, 807–816. https://doi.org/10.1016/j.apsusc.2014.11.043.10.1016/j.apsusc.2014.11.043Suche in Google Scholar

Martinez, J.M., Volzone, C., and Garrido, L.B. (2017) Thermal transformations up to 1200° C of Al-pillared montmorillonite precursors prepared by different OH–Al polymers. Journal of Thermal Analysis and Calorimetry, 128, 61–69. https://doi.org/10.1007/s10973-016-5938-0.10.1007/s10973-016-5938-0Suche in Google Scholar

Miller, J.G., and Oulton, T.D. (1970) Prototropy in kaolinite during percussive grinding. Clays Clay Minerals, 18, 313–323. https://doi.org/10.1346/CCMN.1970.0180603.10.1346/CCMN.1970.0180603Suche in Google Scholar

Mittal, A., Malviya, A., Kaur, D., Mittal, J., and Kurup, L. (2007) Studies on the adsorption kinetics and isotherms for the removal and recovery of Methyl Orange from wastewaters using waste materials. Journal of Hazardous Materials, 148, 229–240. https://doi.org/10.1016/j.jhazmat.2007.02.028.10.1016/j.jhazmat.2007.02.028Suche in Google Scholar PubMed

Msaadi, R., Ammar, S., Chehimi, M.M., and Yagci, Y. (2017) Diazonium-based ion-imprinted polymer/clay nanocomposite for the selective extraction of lead (ii) ions in aqueous media. European Polymer Journal, 89, 367–380. https://doi.org/10.1016/j.eurpolymj.2017.02.029.10.1016/j.eurpolymj.2017.02.029Suche in Google Scholar

Naseem, R., and Tahir, S.S. (2001) Removal of Pb (II) from aqueous/acidic solutions by using bentonite as an adsorbent. Water Research, 35(16), 3982–3986. https://doi.org/10.1016/S0043-1354(01)00130-0.10.1016/S0043-1354(01)00130-0Suche in Google Scholar

Ozdes, D., Duran, C., and Senturk, H.B. (2011) Adsorptive removal of Cd(II) and Pb(II) ions from aqueous solutions by using turkish illitic clay. Journal of Environmental Management, 92, 3082–3090. https://doi.org/10.1016/j.jenvman.2011.07.022.10.1016/j.jenvman.2011.07.022Suche in Google Scholar PubMed

Rathnayake, S.I., Xi, Y., Frost, R.L., and Ayoko, G.A. (2016) Environmental applications of inorganic–organic clays for recalcitrant organic pollutants removal: Bisphenol A. Journal of Colloid and Interface Science, 470, 183–195. https://doi.org/10.1016/j.jcis.2016.02.034.10.1016/j.jcis.2016.02.034Suche in Google Scholar PubMed

Rathnayake, S.I., Martens, W.N., Xi, Y., Frost, R.L., and Ayoko, G.A. (2017) Remediation of Cr (VI) by inorganic-organic clay. Journal of Colloid and Interface Science, 490, 163–173. https://doi.org/10.1016/j.jcis.2016.11.070.10.1016/j.jcis.2016.11.070Suche in Google Scholar PubMed

Ruan, H.D., and Gilkes, R.J. (1996) Kinetics of thermal dehydroxylation of synthetic aluminous goethite. Journal of Thermal Analysis. 46, 1223–1238. https://doi.org/10.1007/BF01979237.10.1007/BF01979237Suche in Google Scholar

Sen, G.S., and Bhattacharyya, K.G. (2008) Immobilization of Pb(II), Cd(II), and Ni(II) ions on kaolinite and montmorillonite surfaces from aqueous medium. Journal of Environmental Management, 87, 46–58. https://doi.org/10.1016/j.jenvman.2007.01.048.10.1016/j.jenvman.2007.01.048Suche in Google Scholar PubMed

Sordori, J., and Eberl, D.D. (1984) Illite. In S.W. Bailey, Ed., Micas, 13, p. 495–544. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Chantilly, Virginia.Suche in Google Scholar

Takahashi, H. (1959) Effects of dry grinding on kaolin minerals. I. kaolinite. Bulletin of the Chemical Society of Japan, 32, 235–245. https://doi.org/10.1246/bcsj.32.235.10.1346/CCMN.1957.0060121Suche in Google Scholar

Tambach, T.J., Hensen, E.J., and Smit, B. (2004) Molecular simulations of swelling clay minerals. The Journal of Physical Chemistry B, 108, 7586–7596. https://doi.org/10.1021/jp049799h10.1021/jp049799hSuche in Google Scholar

Traoré, K., Kabré, T.S., and Blanchart, P. (2003) Gehlenite and anorthite crystallisation from kaolinite and calcite mix. Ceramics International, 29, 377–383. https://doi.org/10.1016/S0272-8842(02)00148-7.10.1016/S0272-8842(02)00148-7Suche in Google Scholar

Yao, W., Yu, S., Wang, J., Zou, Y., Lu, S., Ai, Y., and Wang, X. (2017) Enhanced removal of methyl orange on calcined glycerol-modified nano-crystallized Mg/Al layered double hydroxides. Chemical Engineering Journal, 307, 476–486. https://doi.org/10.1016/j.cej.2016.08.117.10.1016/j.cej.2016.08.117Suche in Google Scholar
Received: 2019-07-25
Accepted: 2020-02-22
Published Online: 2020-09-20
Published in Print: 2020-09-25

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. MSA Centennial Review Paper
  2. How American Mineralogist and the Mineralogical Society of America influenced a career in mineralogy, petrology, and plate pushing, and thoughts on mineralogy’s future role
  3. Petrographic and spectral study of hydrothermal mineralization in drill core from Hawaii: A potential analog to alteration in the martian subsurface
  4. Characterizing low-temperature aqueous alteration of Mars-analog basalts from Mauna Kea at multiple scales
  5. Archean to Paleoproterozoic seawater halogen ratios recorded by fluid inclusions in chert and hydrothermal quartz
  6. Metasomatism-controlled hydrogen distribution in the Spitsbergen upper mantle
  7. Phase transformation of hydrous ringwoodite to the lower-mantle phases and the formation of dense hydrous silica
  8. Density and sound velocity of liquid Fe-S alloys at Earth’s outer core P-T conditions
  9. Some geometrical properties of fission-track-surface intersections in apatite
  10. Thermal equation of state of post-aragonite CaCO3-Pmmn
  11. Structure of NaFeSiO4, NaFeSi2O6, and NaFeSi3O8 glasses and glass-ceramics
  12. Raman spectroscopic studies of O–H stretching vibration in Mn-rich apatites: A structural approach
  13. Characterization of modified mineral waste material adsorbent as affected by thermal treatment for optimizing its adsorption of lead and methyl orange
  14. Morin-type transition in 5C pyrrhotite
  15. The formation of marine red beds and iron cycling on the Mesoproterozoic North China Platform
  16. A multi-methodological study of kernite, a mineral commodity of boron
  17. Letter
  18. Si-rich Mg-sursassite Mg4Al5Si7O23(OH)5 with octahedrally coordinated Si: A new ultrahigh-pressure hydrous phase
  19. Inherited Eocene magmatic tourmaline captured by the Miocene Himalayan leucogranites
  20. Memorial of F. Donald Bloss 1920–2020
  21. Book Review
https://doi.org/10.2138/am-2020-7227
Schlagwörter für diesen Artikel
Adsorption; dehydroxylation; lead (Pb); methyl orange (MO); modified mineral waste material (MMWM)

Artikel in diesem Heft

  1. MSA Centennial Review Paper
  2. How American Mineralogist and the Mineralogical Society of America influenced a career in mineralogy, petrology, and plate pushing, and thoughts on mineralogy’s future role
  3. Petrographic and spectral study of hydrothermal mineralization in drill core from Hawaii: A potential analog to alteration in the martian subsurface
  4. Characterizing low-temperature aqueous alteration of Mars-analog basalts from Mauna Kea at multiple scales
  5. Archean to Paleoproterozoic seawater halogen ratios recorded by fluid inclusions in chert and hydrothermal quartz
  6. Metasomatism-controlled hydrogen distribution in the Spitsbergen upper mantle
  7. Phase transformation of hydrous ringwoodite to the lower-mantle phases and the formation of dense hydrous silica
  8. Density and sound velocity of liquid Fe-S alloys at Earth’s outer core P-T conditions
  9. Some geometrical properties of fission-track-surface intersections in apatite
  10. Thermal equation of state of post-aragonite CaCO3-Pmmn
  11. Structure of NaFeSiO4, NaFeSi2O6, and NaFeSi3O8 glasses and glass-ceramics
  12. Raman spectroscopic studies of O–H stretching vibration in Mn-rich apatites: A structural approach
  13. Characterization of modified mineral waste material adsorbent as affected by thermal treatment for optimizing its adsorption of lead and methyl orange
  14. Morin-type transition in 5C pyrrhotite
  15. The formation of marine red beds and iron cycling on the Mesoproterozoic North China Platform
  16. A multi-methodological study of kernite, a mineral commodity of boron
  17. Letter
  18. Si-rich Mg-sursassite Mg4Al5Si7O23(OH)5 with octahedrally coordinated Si: A new ultrahigh-pressure hydrous phase
  19. Inherited Eocene magmatic tourmaline captured by the Miocene Himalayan leucogranites
  20. Memorial of F. Donald Bloss 1920–2020
  21. Book Review
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 7.11.2025 von https://www.degruyterbrill.com/document/doi/10.2138/am-2020-7227/html?lang=de
Button zum nach oben scrollen