Startseite A method to estimate the pre-eruptive water content of basalts: Application to the Wudalianchi–Erkeshan–Keluo volcanic field, Northeastern China
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A method to estimate the pre-eruptive water content of basalts: Application to the Wudalianchi–Erkeshan–Keluo volcanic field, Northeastern China

  • Yankun Di , Wei Tian EMAIL logo , Mimi Chen , Zefeng Li , Zhuyin Chu und Ju Liang
Veröffentlicht/Copyright: 23. Januar 2020
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Abstract

Water plays an important role in the generation and evolution of volcanic systems. However, the direct measurement of the pre-eruption water content of subaerial volcanic rocks is difficult, because of the degassing during magma ascent. In this study, we developed a method to calculate the pre-eruption water content of the basalts from the Cenozoic Wudalianchi–Erkeshan–Keluo (WEK) potassic volcanic field, Northeastern China, and investigated their mantle source. A water-insensitive clinopyroxene– melt thermobarometer and a water-sensitive silica activity thermobarometer were applied to these basalts. Two pressure-temperature (P-T) paths of the ascending magma were calculated using these two independent thermobarometers, with a similar P-T slope but clear offset. By adjusting the water content used in the calculation, the difference between the two P-T paths was minimized, and the water content of the WEK melts was estimated to be 4.5 ± 1.2 wt% at a pressure range of 10.1–13.5 kbar, corresponding to depths of 37–47 km. Degassing modeling shows that during the magma ascent from below the Moho to near the surface, CO2 was predominantly degassed, while the melt H2O content kept stable. Significant H2O degassing occurred until the magma ascended to 5–2 kbar. The silica activity P–T estimates of the most primary WEK samples suggest that the magmas were generated by the melting of convective mantle, which was probably facilitated by a wet upwelling plume from the mantle transition zone. The high water content found in the WEK basalts is similar to the recent reports on Phanerozoic intraplate large igneous provinces (LIPs) and supports the presence of hydrated deep mantle reservoirs as one possible source of the LIPs.


† Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html.

‡ Present address: Research School of Earth Sciences, Australian National University, Acton, ACT 2601, Australia

§ Present address: Research School of Astronomy & Astrophysics, Australian National University, Weston Creek, ACT 2611, Australia


Acknowledgments

We thank Zhongbo Gao and Miaoyuan Lang for help on programming and statistics, Ping Zhang for discussion on the local seismology, and Guiming Shu and Xiaoli Li for help on EPMA analysis. We appreciate the thorough review and instructive comments from Keith Putirka and an anonymous reviewer. We also thank Anne Peslier for editorial handling. We are grateful to Durgalakshmi for a careful proofreading of the manuscript. The authors thank Enago (www.enago.cn) for their professional English language editing.

  1. Funding

    This research was financially supported by the National Natural Science Foundation of China (grant number 41630205), the National Key R&D Program of China (2017YFC0601302) and National Student’s Platform for Innovation and Entrepreneurship Training Program of China (grant number 201511001041). Y.D. thanks “Tan Siu Lin Overseas Exchange Endowment for Undergraduates” for providing financial support for the trip and presentation of this research in the 2016 Goldschmidt conference.

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Received: 2019-05-29
Accepted: 2019-09-24
Published Online: 2020-01-23
Published in Print: 2020-02-25

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

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  8. Cl-bearing fluorcalciobritholite in high-Ti basalts from Apollo 11 and 17: Implications for volatile histories of late-stage lunar magmas
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