Startseite A Raman calibration for the quantification of SO42− groups dissolved in silicate glasses: Application to natural melt inclusions
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A Raman calibration for the quantification of SO42− groups dissolved in silicate glasses: Application to natural melt inclusions

  • Yann Morizet EMAIL logo , Emanuela Gennaro , Sébastien Jego , Zoltan Zajacz , Giada Iacono-Marziano , Michel Pichavant , Ida Di Carlo , Clément Ferraina und Priscille Lesne
Veröffentlicht/Copyright: 2. Oktober 2017
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American Mineralogist
Aus der Zeitschrift American Mineralogist Band 102 Heft 10

Abstract

Sulfur is an important volatile element involved in magmatic systems. Its quantification in silicate glasses relies on state-of-the-art techniques such as electronprobe microanalyses (EPMA) or X-ray absorption spectroscopy but is often complicated by the fact that S dissolved in silicate glasses can adopt several oxidation states (S6+ for sulfates or S2− for sulfides). In the present work, we use micro-Raman spectroscopy on a series of silicate glasses to quantify the S content. The database is constituted by 47 silicate glasses of various compositions (natural and synthetic) with S content ranging from 1179 to 13 180 ppm. Most of the investigated glasses have been synthesized at high pressure and high temperature and under fully oxidizing conditions. The obtained Raman spectra are consistent with these fO2 conditions and only S6+ is present and shows a characteristic peak located at ~1000 cm−1 corresponding to the symmetric stretch of the sulfate molecular group (ν1SO42−). The intensity of the ν1SO42− peak is linearly correlated to the parts per million of S6+ determined by EPMA. Using subsequent deconvolution of the Raman spectra, we established an equation using the ratio between the areas of the ν1SO42− peak and the silicate network species (Qn) in the high-frequency region:

ppm S6+=34371ASO42−AQn±609.

We tested our calibration on several silicate glasses equilibrated under moderately reducing conditions (QFM+0.8 ≤fO2≤ QFM+1.4) in which S is dissolved as both SO42− and S2−. We also analyzed several olivine-hosted melt inclusions collected from Etna for which the fO2 and S speciation are unknown. For these samples, the S content estimated by the Raman calibration is systematically lower than the total S measured by EPMA. We combined both methods to estimate the S2− content not accounted for by Raman and derive the S speciation and fO2 conditions. The derived fO2 is consistent with the imposed fO2 for synthesized glasses and with current assumed fO2 conditions for basaltic melt inclusions from Etna.

Keywords: Micro-Raman spectroscopy; S content; silicate glass; melt inclusions; S speciation; redox conditions

Acknowledgments

The authors are grateful to the CNRS INSU (ALEAS program) and the OSUNA for their financial support for the current work. Zoltan Zajacz acknowledges the support of the Swiss National Science Foundation (Ambizione Grant no. PZ00P2-136857) and the Discovery Grant program of the Natural Sciences and Engineering Research Council of Canada. The authors thank the University of Orléans and the University of Nantes for their access to analytical facilities.

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Received: 2017-2-1
Accepted: 2017-6-6
Published Online: 2017-10-2
Published in Print: 2017-10-26

© 2017 by Walter de Gruyter Berlin/Boston

Artikel in diesem Heft

  1. Highlights and Breakthroughs
  2. Making a fine-scale ruler for oxide inclusions
  3. Special Collection: Biomaterials—Mineralogy Meets Medicine
  4. Substitution of sulfate in apatite
  5. Actinides in Geology, Energy, and the Environment
  6. Thermodynamic characterization of synthetic autunite
  7. Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
  8. The crystal structure of turneaureite, Ca5(AsO4)3Cl, the arsenate analog of chlorapatite, and its relationships with the arsenate apatites johnbaumite and svabite
  9. Special Collection: From Magmas to Ore Deposits
  10. Cu-Mo partitioning between felsic melts and saline-aqueous fluids as a function of XNaCleq, fO2, and fS2
  11. Special Collection: Dynamics of Magmatic Processes
  12. Continuous mush disaggregation during the long-lasting Laki fissure eruption, Iceland
  14. A new hydrothermal moissanite cell apparatus for optical in-situ observations at high pressure and high temperature, with applications to bubble nucleation in silicate melts
  16. Experimental and thermodynamic investigations on the stability of Mg14Si5O24 anhydrous phase B with relevance to Mg2SiO4 forsterite, wadsleyite, and ringwoodite
  18. Model for the origin, ascent, and eruption of lunar picritic magmas
  20. Phase relations of Fe-Mg spinels including new high-pressure post-spinel phases and implications for natural samples
  22. A Raman calibration for the quantification of SO42− groups dissolved in silicate glasses: Application to natural melt inclusions
  24. The system fayalite-albite-anorthite and the syenite problem
  26. Kiglapait mineralogy V: Feldspars in a hot, dry magma
  28. Orientation of exsolution lamellae in mantle xenolith pyroxenes and implications for calculating exsolution pressures
  30. Spin state and electronic environment of iron in basaltic glass in the lower mantle
  32. A shallow origin of so-called ultrahigh-pressure chromitites, based on single-crystal X-ray structure analysis of the high-pressure Mg2Cr2O5 phase, with modified ludwigite-type structure
  34. Biologically mediated crystallization of buddingtonite in the Paleoproterozoic: Organic-igneous interactions from the Volyn pegmatite, Ukraine
  36. Mengxianminite (Ca2Sn2Mg3Al8[(BO3)(BeO4)O6]2) a new borate mineral from Xianghualing skarn, Hunan Province, China, with a highly unusual chemical combination (B + Be + Sn)
  37. Letter: Special Collection: Nanominerals and Mineral Nanoparticles
  38. Previously unknown mineral-nanomineral relationships with important environmental consequences: The case of chromium release from dissolving silicate minerals
  39. Letter: Special Collection: Nanominerals and Mineral Nanoparticles
  40. Protoenstatite: A new mineral in Oregon sunstones with “watermelon” colors
  42. Book Review
https://doi.org/10.2138/am-2017-6100
Schlagwörter für diesen Artikel
Micro-Raman spectroscopy; S content; silicate glass; melt inclusions; S speciation; redox conditions

Artikel in diesem Heft

  1. Highlights and Breakthroughs
  2. Making a fine-scale ruler for oxide inclusions
  3. Special Collection: Biomaterials—Mineralogy Meets Medicine
  4. Substitution of sulfate in apatite
  5. Actinides in Geology, Energy, and the Environment
  6. Thermodynamic characterization of synthetic autunite
  7. Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
  8. The crystal structure of turneaureite, Ca5(AsO4)3Cl, the arsenate analog of chlorapatite, and its relationships with the arsenate apatites johnbaumite and svabite
  9. Special Collection: From Magmas to Ore Deposits
  10. Cu-Mo partitioning between felsic melts and saline-aqueous fluids as a function of XNaCleq, fO2, and fS2
  11. Special Collection: Dynamics of Magmatic Processes
  12. Continuous mush disaggregation during the long-lasting Laki fissure eruption, Iceland
  14. A new hydrothermal moissanite cell apparatus for optical in-situ observations at high pressure and high temperature, with applications to bubble nucleation in silicate melts
  16. Experimental and thermodynamic investigations on the stability of Mg14Si5O24 anhydrous phase B with relevance to Mg2SiO4 forsterite, wadsleyite, and ringwoodite
  18. Model for the origin, ascent, and eruption of lunar picritic magmas
  20. Phase relations of Fe-Mg spinels including new high-pressure post-spinel phases and implications for natural samples
  22. A Raman calibration for the quantification of SO42− groups dissolved in silicate glasses: Application to natural melt inclusions
  24. The system fayalite-albite-anorthite and the syenite problem
  26. Kiglapait mineralogy V: Feldspars in a hot, dry magma
  28. Orientation of exsolution lamellae in mantle xenolith pyroxenes and implications for calculating exsolution pressures
  30. Spin state and electronic environment of iron in basaltic glass in the lower mantle
  32. A shallow origin of so-called ultrahigh-pressure chromitites, based on single-crystal X-ray structure analysis of the high-pressure Mg2Cr2O5 phase, with modified ludwigite-type structure
  34. Biologically mediated crystallization of buddingtonite in the Paleoproterozoic: Organic-igneous interactions from the Volyn pegmatite, Ukraine
  36. Mengxianminite (Ca2Sn2Mg3Al8[(BO3)(BeO4)O6]2) a new borate mineral from Xianghualing skarn, Hunan Province, China, with a highly unusual chemical combination (B + Be + Sn)
  37. Letter: Special Collection: Nanominerals and Mineral Nanoparticles
  38. Previously unknown mineral-nanomineral relationships with important environmental consequences: The case of chromium release from dissolving silicate minerals
  39. Letter: Special Collection: Nanominerals and Mineral Nanoparticles
  40. Protoenstatite: A new mineral in Oregon sunstones with “watermelon” colors
  42. Book Review
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