Abstract
Crystallographic orientation relationships (CORs) between mineral inclusions and their hosts could potentially deliver information about inclusion formation processes and conditions. Most previous studies are based on small numbers of analyses. This paper uses EBSD to study host–inclusion CORs in an inclusion-rich Permian metapegmatite garnet (Koralpe region, Eastern Alps, Austria), demonstrating the importance of large data sets and of EBSD in particular for the analysis of CORs. The distribution of measured orientations reflects host garnet point group symmetry for 89% of inclusions analyzed (total N = 530). Each inclusion phase (rutile, corundum, and ilmenite) shows at least three different CORs to host garnet. “Statistical” CORs are introduced to describe distributions of inclusion orientations that have one or two degrees of freedom with respect to the host, but still reflect host crystal symmetry. Two end-member characteristics of statistical CORs are distinguished: rotation and dispersion. Most statistical CORs observed show a mixture of both. Each inclusion phase shows at least one statistical COR. Multiple coexisting CORs and statistical CORs are not restricted to rutile. Re-examination of previous garnet–rutile COR studies in light of the new results indicates that COR information may have been overlooked when using small data sets. Variation in COR parameters correlates with broad differences in assumed metamorphic conditions for new and literature samples, suggesting that petrogenetic information may be available if COR formation can be understood. The favorability of the detected CORs cannot be explained by a simple model involving minimization of misfit between lattice planes, implying that other interface properties or the inclusion formation mechanism are important controls on COR development.
Acknowledgments
The authors acknowledge funding by the University of Vienna doctoral school IK052 Deformation of Geological Materials (DOGMA) and the project of the Austrian Science Fund (FWF): I471-N19, as part of the international DFG-FWF funded research network FOR741-DACH. Helen M. Lang is thanked for providing information about the presumed source rocks of the Idaho star garnets.
References cited
Ague, J.J., and Eckert, J.O. Jr. (2012) Precipitation of rutile and ilmenite needles in garnet: Implications for extreme metamorphic conditions in the Acadian Orogen, U.S.A. American Mineralogist, 97, 840–855.10.2138/am.2012.4015Search in Google Scholar
Amouric, M., Baronnet, A., Nahon, D., and Didier, P. (1986) Electron microscopic investigations of iron oxyhydroxides and accompanying phases in lateritic iron-crust pisolites. Clays and Clay Minerals, 34, 45–52.10.1346/CCMN.1986.0340106Search in Google Scholar
Bachmann, F., Hielscher, R., and Schaeben, H. (2010) Texture analysis with MTEX— Free and open source software toolbox. Solid State Phenomena, 160, 63–68.10.4028/www.scientific.net/SSP.160.63Search in Google Scholar
Balluffi, R.W., Allen, S., and Carter, W.C. (2005) Kinetics of Materials, 674 p. Wiley, Hoboken.10.1002/0471749311Search in Google Scholar
Bestmann, M., Habler, G., Heidelbach, F., and Thoni, M. (2008) Dynamic recrystallization of garnet and related diffusion processes. Journal of Structural Geology, 30, 777–790.10.1016/j.jsg.2008.02.007Search in Google Scholar
Brearley, A.J., and Champness, P.E. (1986) Magnetite exsolution in almandine garnet. Mineralogical Magazine, 50, 621–633.10.1180/minmag.1986.050.358.07Search in Google Scholar
Bursill, L.A., and Withers, R.L. (1979) On the multiple orientation relationships between hematite and magnetite. Journal of Applied Crystallography, 12, 287–294.10.1107/S0021889879012486Search in Google Scholar
Burton, K.W. (1986) Garnet-quartz intergrowths in graphitic pelites: the role of the fluid phase. Mineralogical Magazine, 50, 611–620.10.1180/minmag.1986.050.358.06Search in Google Scholar
Frazer, C.S., Dickey, E.C., and Sayir, A. (2001) Crystallographic texture and orientation variants in Al2O3-Y3Al5O12 directionally solidified eutectic crystals. Journal of Crystal Growth, 233, 187–195.10.1016/S0022-0248(01)01590-1Search in Google Scholar
Glassley, W.E., Korstgård, J.A., Ensen, K.S., and Platou, S.W. (2014) A new UHP metamorphic complex in the ~1.8 Ga Nagssugtoqidian Orogen of west Greenland. American Mineralogist, 99, 1315–1334.10.2138/am.2014.4726Search in Google Scholar
Gou, L., Zhang, C., Zhang, L., and Wang, Q. (2014) Precipitation of rutile needles in garnet from sillimanite-bearing pelitic granulite from the Khondalite Belt, North China Craton. Chinese Science Bulletin, 59, 4359–4366.10.1007/s11434-014-0598-6Search in Google Scholar
Green, H.W. II, Dobrzhinetskaya, L., Riggs, E.M., and Jin, Z.-M. (1997) Alpe Arami: A peridotite massif from the mantle transition zone? Tectonophysics, 279, 1–21.10.1016/S0040-1951(97)00127-3Search in Google Scholar
Gregurek, D., Abart, R., and Hoinkes, G. (1997) Contrasting Eoalpine P-T evolutions in the southern Koralpe, Eastern Alps. Mineralogy and Petrology, 60, 61–80.10.1007/BF01163135Search in Google Scholar
Griffiths, T.A., Habler, G., Rhede, D., Wirth, R., Ram, F., and Abart, R. (2014) Localization of submicron inclusion re-equilibration at healed fractures in host garnet. Contributions to Mineralogy and Petrology, 168, 1–21.10.1007/s00410-014-1077-4Search in Google Scholar
Guinel, M.J.-F., and Norton, M.G. (2006) The origin of asterism in almandine-pyrope garnets from Idaho. Journal of Materials Science, 41, 719–725.10.1007/s10853-006-6500-4Search in Google Scholar
Habler, G., and Thöni, M. (2001) Preservation of Permo–Triassic low-pressure assemblages in the Cretaceous high-pressure metamorphic Saualpe crystalline basement (Eastern Alps, Austria). Journal of Metamorphic Geology, 19, 679–697.10.1046/j.0263-4929.2001.00338.xSearch in Google Scholar
Habler, G., Thöni, M., and Miller, C. (2007) Major and trace element chemistry and Sm-Nd age correlation of magmatic pegmatite garnet overprinted by eclogite-facies metamorphism. Chemical Geology, 241, 4–22.10.1016/j.chemgeo.2007.01.026Search in Google Scholar
Hatert, F., Baijot, M., Philippo, S., and Wouters, J. (2010) Qingheiite-(Fe2+), Na2Fe2+MgAl(PO4)3, a new phosphate mineral from the Sebastião Cristino pegmatite, Minas Gerais, Brazil. European Journal of Mineralogy, 22, 459–467.10.1127/0935-1221/2010/0022-2030Search in Google Scholar
Hielscher, R., Schaeben, H., and Siemes, H. (2010) Orientation distribution within a single hematite crystal. Mathematical Geosciences, 42, 359–375.10.1007/s11004-010-9271-zSearch in Google Scholar
Howe, J.M. (1997) Interfaces in Materials: Atomic Structure, Thermodynamics and Kinetics of Solid-Vapor, Solid-Liquid and Solid-Solid Interfaces. Wiley, Hoboken.Search in Google Scholar
Hwang, S.L., Yui, T.F., Chu, H.T., Shen, P., Schertl, H.P., Zhang, R.Y., and Liou, J.G. (2007) On the origin of oriented rutile needles in garnet from UHP eclogites. Journal of Metamorphic Geology, 25, 349–362.10.1111/j.1525-1314.2007.00699.xSearch in Google Scholar
Hwang, S.-L., Yui, T.-F., Chu, H.-T., Shen, P., Zhang, R.-Y., and Liou, J.G. (2011) An AEM study of garnet clinopyroxenite from the Sulu ultrahigh-pressure terrane: formation mechanisms of oriented ilmenite, spinel, magnetite, amphibole and garnet inclusions in clinopyroxene. Contributions to Mineralogy and Petrology, 161, 901–920.10.1007/s00410-010-0571-6Search in Google Scholar
Hwang, S.L., Shen, P., Chu, H.T., Yui, T.F., and Iizuka, Y. (2013) A TEM study of the oriented orthopyroxene and forsterite inclusions in garnet from Otrøy garnet peridotite, WGR, Norway: new insights on crystallographic characteristics and growth energetics of exsolved pyroxene in relict majoritic garnet. Journal of Metamorphic Geology, 31, 113–130.10.1111/jmg.12002Search in Google Scholar
Hwang, S.-L., Shen, P., Chu, H.-T., Yui, T.-F., and Iizuka, Y. (2015) Origin of rutile needles in star garnet and implications for interpretation of inclusion textures in ultrahigh-pressure metamorphic rocks. Journal of Metamorphic Geology, 33, 249–272.10.1111/jmg.12119Search in Google Scholar
Khisina, N.R., Wirth, R., Abart, R., Rhede, D., and Heinrich, W. (2013) Oriented chromite–diopside symplectic inclusions in olivine from lunar regolith delivered by “Luna-24” mission. Geochimica et Cosmochimica Acta, 104, 84–98.10.1016/j.gca.2012.10.050Search in Google Scholar
Lang, H.M., Johnson, S.E., and Largent, K.J. (2014) Use of garnet zoning and pseudosection modeling to constrain the P-T path of metapelitic tectonites in the snow peak area, northern Idaho. Geological Society of America Abstracts with Programs, 46, 140.Search in Google Scholar
Miller, C., and Thöni, M. (1997) Eo-Alpine eclogitisation of Permian MORB-type gabbros in the Koralpe (Eastern Alps, Austria): New geochronological, geochemical and petrological data. Chemical Geology, 137, 283–310.10.1016/S0009-2541(96)00165-9Search in Google Scholar
Miller, C., Thöni, M., Konzett, J., Kurz, W., and Schuster, R. (2005) Eclogites from the Koralpe and Saualpe type-localities, eastern Alps, Austria. Mitteilungen der Österreichischen Mineralogischen Gesellschaft, 227–263.Search in Google Scholar
Miller, C., Zanetti, A., Thöni, M., and Konzett, J. (2007) Eclogitisation of gabbroic rocks: Redistribution of trace elements and Zr in rutile thermometry in an Eo-Alpine subduction zone (Eastern Alps). Chemical Geology, 239, 96–123.10.1016/j.chemgeo.2007.01.001Search in Google Scholar
Moore, P., and lto, J. (1979) Alluaudites, wyllieites, arrojadites: crystal chemistry and nomenclature. Mineralogical Magazine, 43, 227–235.10.1180/minmag.1979.043.326.04Search in Google Scholar
Mposkos, E.D., and Kostopoulos, D.K. (2001) Diamond, former coesite and supersilicic garnet in metasedimentary rocks from the Greek Rhodope: a new ultrahigh-pressure metamorphic province established. Earth and Planetary Science Letters, 192, 497–506.10.1016/S0012-821X(01)00478-2Search in Google Scholar
Perchuk, A. (2008) Unusual inclusions in garnet from the diamond-bearing gneiss of the Erzgebirge, Germany. Geochemistry International, 46, 296–303.10.1134/S0016702908030063Search in Google Scholar
Proyer, A., Habler, G., Abart, R., Wirth, R., Krenn, K., and Hoinkes, G. (2013) TiO2 exsolution from garnet by open-system precipitation: evidence from crystallographic and shape preferred orientation of rutile inclusions. Contributions to Mineralogy and Petrology, 166, 211–234.10.1007/s00410-013-0872-7Search in Google Scholar
Ram, F., Zaefferer, S., Jäpel, T., and Raabe, D. (2015) Error analysis of the crystal orientations and disorientations obtained by the classical electron backscatter diffraction technique. Journal of Applied Crystallography, 48, 797–813.10.1107/S1600576715005762Search in Google Scholar
Ruiz-Cruz, M.D., and Sanz de Galdeano, C. (2013) Coesite and diamond inclusions, exsolution microstructures and chemical patterns in ultrahigh pressure garnet from Ceuta (Northern Rif, Spain). Lithos, 177, 184–206.10.1016/j.lithos.2013.06.004Search in Google Scholar
Schmid, S.M., Fügenschuh, B., Kissling, E., and Schuster, R. (2004) Tectonic map and overall architecture of the Alpine orogen. Eclogae Geologicae Helvetiae, 97, 93–117.10.1007/s00015-004-1113-xSearch in Google Scholar
Schuster, R., and Stüwe, K. (2008) Permian metamorphic event in the Alps. Geology, 36, 603–606.10.1130/G24703A.1Search in Google Scholar
Sugiyama, K., Nakai, M., Yoshikawa, A., and Fukuda, T. (2009) Microstructure and crystal chemistry of eutectic Al2O3/Y3Al5O12 fibers modified by the partial substitution of Sc2O3 for Al2O3. High Temperature Materials and Processes, 28, 89–95.10.1515/HTMP.2009.28.1-2.89Search in Google Scholar
Tenczer, V., and Stüwe, K. (2003) The metamorphic field gradient in the eclogite type locality, Koralpe region, Eastern Alps. Journal of Metamorphic Geology, 21, 377–393.10.1046/j.1525-1314.2003.00448.xSearch in Google Scholar
Tenczer, V., Powell, R., and Stüwe, K. (2006) Evolution of H2O content in a poly-metamorphic terrane: the Plattengneiss Shear Zone (Koralpe, Austria). Journal of Metamorphic Geology, 24, 281–295.10.1111/j.1525-1314.2006.00637.xSearch in Google Scholar
Thöni, M. (2006) Dating eclogite-facies metamorphism in the Eastern Alps—Approaches, results, interpretations: A review. Mineralogy and Petrology, 88, 123–148.10.1007/s00710-006-0153-5Search in Google Scholar
Thöni, M., and Jagoutz, E. (1992) Some new aspects of dating eclogites in orogenic belts: Sm-Nd, Rb-Sr, and Pb-Pb isotopic results from the Austroalpine Saualpe and Koralpe type-locality (Carinthia/Styria, southeastern Austria). Geochimica et Cosmochimica Acta, 56, 347–368.10.1016/0016-7037(92)90138-9Search in Google Scholar
Thöni, M., and Miller, C. (2000) Permo-triassic pegmatites in the eo-alpine eclogite-facies Koralpe complex, Austria: Age and magma source constraints from mineral chemical, Rb-Sr and Sm-Nd isotope data. Schweizerische Mineralogische und Petrographische Mitteilungen, 80, 169–186.Search in Google Scholar
Thöni, M., and Miller, C. (2009) The “Permian event” in the Eastern European Alps: Sm–Nd and P–T data recorded by multi-stage garnet from the Plankogel unit. Chemical Geology, 260, 20–36.10.1016/j.chemgeo.2008.11.017Search in Google Scholar
Thöni, M., Miller, C., Zanetti, A., Habler, G., and Goessler, W. (2008) Sm-Nd isotope systematics of high-REE accessory minerals and major phases: ID-TIMS, LA-ICP-MS and EPMA data constrain multiple Permian-Triassic pegmatite emplacement in the Koralpe, Eastern Alps. Chemical Geology, 254, 216–237.10.1016/j.chemgeo.2008.03.008Search in Google Scholar
Van Roermund, H.L.M., Drury, M.R., Barnhoorn, A., and De Ronde, A.A. (2000) Super-ilicic garnet microstructures from an orogenic garnet peridotite, evidence for an ultra-deep (>6 GPa) origin. Journal of Metamorphic Geology, 18, 135–147.10.1046/j.1525-1314.2000.00251.xSearch in Google Scholar
West, N., Foley, N., and Evans, J. (2005) Garnet gravels and their source rocks: a comparative study of garnet resources of the Emerald Creek area, Idaho. Geological Society of America Abstracts with Programs, 37, 63.Search in Google Scholar
Xu, H., Zhang, J., Zong, K., and Liu, L. (2015) Quartz exsolution topotaxy in clinopyroxene from the UHP eclogite of Weihai, China. Lithos, 226, 17–30.10.1016/j.lithos.2015.02.010Search in Google Scholar
Ye, K., Cong, B., and Ye, D. (2000) The possible subduction of continental material to depths greater than 200 km. Nature, 407, 734–736.10.1038/35037566Search in Google Scholar PubMed
Zhang, R.Y., and Liou, J.G. (2003) Clinopyroxenite from the Sulu ultrahigh-pressure terrane, eastern China: Origin and evolution of garnet exsolution in clinopyroxene. American Mineralogist, 88, 1591–1600.10.2138/am-2003-1022Search in Google Scholar
Zhang, J.F., Xu, H.J., Liu, Q., Green, H.W., and Dobrzhinetskaya, L.F. (2011) Pyroxene exsolution topotaxy in majoritic garnet from 250 to 300 km depth. Journal of Metamorphic Geology, 29, 741–751.10.1111/j.1525-1314.2011.00939.xSearch in Google Scholar
Manuscript handled by Callum Hetherington.
© 2016 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
- Editorial
- The most-cited journal in mineralogy and petrology (and what scientists can learn from baseball)
- Fluids in the Crust
- Fluids in the crust during regional metamorphism: Forty years in the Waterville limestone
- Research Article
- Remanent magnetization, magnetic coupling, and interface ionic configurations of intergrown rhombohedral and cubic Fe-Ti oxides: A short survey
- Research Article
- Are covalent bonds really directed?
- Dana Medal Paper
- Constraints on the early delivery and fractionation of Earth’s major volatiles from C/H, C/N, and C/S ratios
- Crossroads in Earth and Planetary Materials
- Octahedral chemistry of 2:1 clay minerals and hydroxyl band position in the near-infrared: Application to Mars
- Special Collection: Advances in Ultrahigh-Pressure Metamorphism
- Multi-stage barite crystallization in partially melted UHP eclogite from the Sulu belt, China
- Spinels Renaissance: The Past, Present, and Future of those Ubiquitous Minerals and Materials
- Crystal chemistry of spinels in the system MgAl2O4-MgV2O4-Mg2VO4
- Spinels Renaissance: The Past, Present, and Future of those Ubiquitous Minerals and Materials
- Magnetite spherules in pyroclastic iron ore at El Laco, Chile
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- Evidence for dissolution-reprecipitation of apatite and preferential LREE mobility in carbonatite-derived late-stage hydrothermal processes
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- Compositional variation of apatite from rift-related alkaline igneous rocks of the Gardar Province, South Greenland
- Special Collection: Perspectives on Origins and Evolution of Crustal Magmas
- Dynamics and thermodynamics of magma mixing: Insights from a simple exploratory model
- Special Collection: From Magmas to Ore Deposits
- Geochemistry, petrologic evolution, and ore deposits of the Miocene Bodie Hills Volcanic Field, California and Nevada
- Research Article
- Recognizing sulfate and phosphate complexes chemisorbed onto nanophase weathering products on Mars using in-situ and remote observations
- Research Article
- Crystallographic orientation relationships in host–inclusion systems: New insights from large EBSD data sets
- Research Article
- In-situ infrared spectroscopic studies of hydroxyl in amphiboles at high pressure
- Research Article
- Confined water in tunnel nanopores of sepiolite: Insights from molecular simulations
- Research Article
- Equation of state of the high-pressure Fe3O4 phase and a new structural transition at 70 GPa
- Research Article
- Reflectance spectroscopy of chromium-bearing spinel with application to recent orbital data from the Moon
- Research Article
- Temperature dependences of the hyperfine parameters of Fe2+ in FeTiO3 as determined by 57Fe-Mössbauer spectroscopy
- Letter
- Accurate predictions of iron redox state in silicate glasses: A multivariate approach using X-ray absorption spectroscopy
- Research Article
- New Mineral Names
Articles in the same Issue
- Editorial
- The most-cited journal in mineralogy and petrology (and what scientists can learn from baseball)
- Fluids in the Crust
- Fluids in the crust during regional metamorphism: Forty years in the Waterville limestone
- Research Article
- Remanent magnetization, magnetic coupling, and interface ionic configurations of intergrown rhombohedral and cubic Fe-Ti oxides: A short survey
- Research Article
- Are covalent bonds really directed?
- Dana Medal Paper
- Constraints on the early delivery and fractionation of Earth’s major volatiles from C/H, C/N, and C/S ratios
- Crossroads in Earth and Planetary Materials
- Octahedral chemistry of 2:1 clay minerals and hydroxyl band position in the near-infrared: Application to Mars
- Special Collection: Advances in Ultrahigh-Pressure Metamorphism
- Multi-stage barite crystallization in partially melted UHP eclogite from the Sulu belt, China
- Spinels Renaissance: The Past, Present, and Future of those Ubiquitous Minerals and Materials
- Crystal chemistry of spinels in the system MgAl2O4-MgV2O4-Mg2VO4
- Spinels Renaissance: The Past, Present, and Future of those Ubiquitous Minerals and Materials
- Magnetite spherules in pyroclastic iron ore at El Laco, Chile
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- Evidence for dissolution-reprecipitation of apatite and preferential LREE mobility in carbonatite-derived late-stage hydrothermal processes
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- Compositional variation of apatite from rift-related alkaline igneous rocks of the Gardar Province, South Greenland
- Special Collection: Perspectives on Origins and Evolution of Crustal Magmas
- Dynamics and thermodynamics of magma mixing: Insights from a simple exploratory model
- Special Collection: From Magmas to Ore Deposits
- Geochemistry, petrologic evolution, and ore deposits of the Miocene Bodie Hills Volcanic Field, California and Nevada
- Research Article
- Recognizing sulfate and phosphate complexes chemisorbed onto nanophase weathering products on Mars using in-situ and remote observations
- Research Article
- Crystallographic orientation relationships in host–inclusion systems: New insights from large EBSD data sets
- Research Article
- In-situ infrared spectroscopic studies of hydroxyl in amphiboles at high pressure
- Research Article
- Confined water in tunnel nanopores of sepiolite: Insights from molecular simulations
- Research Article
- Equation of state of the high-pressure Fe3O4 phase and a new structural transition at 70 GPa
- Research Article
- Reflectance spectroscopy of chromium-bearing spinel with application to recent orbital data from the Moon
- Research Article
- Temperature dependences of the hyperfine parameters of Fe2+ in FeTiO3 as determined by 57Fe-Mössbauer spectroscopy
- Letter
- Accurate predictions of iron redox state in silicate glasses: A multivariate approach using X-ray absorption spectroscopy
- Research Article
- New Mineral Names