Abstract
The prediction of viscosity in silicate melts, over the range of conditions found in nature, remains one of the most challenging and elusive goals in Earth Sciences. We present a strategy for fitting non-Arrhenian models [e.g., Vogel-Tammann-Fulcher (VTF) or Adam-Gibbs (AG)] to viscosity data that can be employed toward a full multicomponent model for melt viscosity. Our postulate is that the high-T viscosities of silicate melts converge to a common value. The implications are twofold. First, the number of composition-dependent parameters is reduced by a third. Second, our optimization constrains the experimentally inaccessible, high-T properties of silicate melts. The high-T limits to melt viscosity are constrained by the VTF and AG models to between 10-4.3±0.74 and 10-3.2±0.66 Pa·s, respectively, and overlap in the interval 10-3.86 to 10-3.56 Pa·s.
© 2015 by Walter de Gruyter Berlin/Boston
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Artikel in diesem Heft
- Melting of garnet peridotite: Effects of capsules and thermocouples, and implications for the high-pressure mantle solidus
- High-resolution and energy-filtered TEM of the interface between hematite and ilmenite exsolution lamellae: Relevance to the origin of lamellar magnetism
- The structural evolution of mercury sulfide precipitate: an XAS and XRD study
- Synthetic fluid inclusions as recorders of microfracture healing and overgrowth formation rates
- Fluid-induced nucleation of (Y+REE)-phosphate minerals within apatite: Nature and experiment. Part II. Fluorapatite
- A technique for measuring 3D crystal-size distributions of prismatic microlites in obsidian
- TEM investigation of forsterite dendrites
- Mechanism and kinetics of element and isotopic exchange mediated by a fluid phase
- Chromian spinel during melting experiments of dry peridotite (KLB-1) at 1.0–2.5 GPa
- Resonant XPS study of the pyrite valence band with implications for molecular orbital contributions
- Petrology and mineralogy of wollastonite- and melilite-bearing paralavas from the Central Apennines, Italy
- Variation of antiphase domain size in omphacite: A tool to determine the temperature–time history of eclogites revisited
- Compressional and shear wave velocities of ringwoodite γ-Mg2SiO4 to 12 GPa
- A vibrational spectroscopic study of the oxidation of pyrite by ferric iron
- The atomic arrangement of the ganophyllite-group modulated layer silicates as determined from the orthorhombic dimorph of tamaite, with the elusive 16.8 Å ganophyllite-group superstructure revealed
- The crystal structure of chromian kassite from the Saranovskoye deposit, Northern Urals, Russia
- Spectroscopic and related evidence on the coloring and constitution of New Zealand jade
- Chemical speciation of Ag in galena by EPR spectroscopy
- Pressure dependence of melt viscosity in the system NaAlSi3O8-CaMgSi2O6
- Molecules in the SiO2-clathrate melanophlogite: A single-crystal Raman study
- Mn-rich tourmaline from Austria: structure, chemistry, optical spectra, and relations to synthetic solid solutions
- Compositional heterogeneity of olivine in thermally metamorphosed serpentinite from Southwest Japan
- Magnetic monitoring of hydrothermal magnetite nucleation-and-growth: Record of magnetic reversals
- High-temperature limits on viscosity of non-Arrhenian silicate melts
- First reported sedimentary occurrence of berlinite (AlPO4) in phosphate-bearing sediments from Cioclovina Cave, Romania