Home Florenskyite, FeTiP, a new phosphide from the Kaidun meteorite
Article
Licensed
Unlicensed Requires Authentication

Florenskyite, FeTiP, a new phosphide from the Kaidun meteorite

  • Andrei V. Ivanov , Michael E. Zolensky EMAIL logo , Akihiro Saito , Kazumasa Ohsumi , Vincent Yang , Nataliya N. Kononkova and Takashi Mikouchi
Published/Copyright: March 26, 2015
Become an author with De Gruyter Brill
Author Information
American Mineralogist
From the journal American Mineralogist Volume 85 Issue 7-8

Abstract

Florenskyite is a new phosphide species from the Kaidun chondritic meteorite, which fell in South Yemen in 1980. Kaidun is a unique chondritic breccia containing a huge variety of fragments of different chondritic types. Florenskyite was found as four dispersed grains with a maximum dimension of 14 μm within a single mass of Fe-rich serpentine within one Kaidun clast. Florenskyite is associated with submicrometer-sized grains of pentlandite and small (up to 1.5 μm in width) laths of a still uncharacterized Fe-Cr phosphide. Florenskyite is creamy white in reflected light, and its luster is metallic. The average of three electron microprobe analyses gave (wt%) Fe 40.52, Ti 30.08, Ni 5.47, Cr 0.93, V 0.91, Co 0.60, P 21.69, Si 0.59, sum 100.79, corresponding to Fe1.01(Ti0.87Ni0.13Cr0.03V0.02Co0.01)1.06(P0.97Si0.03). Single-crystal structure analysis was performed on florenskyite using a Laue pattern collected from a multiple crystal by in-situ synchrotron X-ray diffraction. Florenskyite crystallizes in the space group Pnma, and has the anti-PbCl2 structure. Previously determined cell constants of synthetic material [a = 6.007(1), b = 3.602(1), c = 6.897(1) Å] were used in the single-crystal data reduction. We used the POWD12 program to calculate a powder XRD pattern; the 5 most intense reflections are d = 2.301 (I = 100), 2.188 (88), 2.307 (47), 1.938 (45), and 1.801 Å (45). Florenskyite is only the fourth phosphide to be described from nature. Its paragenesis may be unique, and may be due to melting of a mineral assemblage including Fe-Ni metal, schreibersite, daubreelite, osbornite, or heideite and subsequent crystallization of phosphides from the melt.

Received: 1999-8-12
Accepted: 2000-2-17
Published Online: 2015-3-26
Published in Print: 2000-7-1

© 2015 by Walter de Gruyter Berlin/Boston

Articles in the same Issue

  1. Application of new experimental and garnet Margules data to the garnet-biotite geothermometer
  2. Volumes of mixing in aluminosilicate garnets: Solid solution and strain behavior
  3. Cerium anomaly and Th/U fractionation in the 1.85 Ga Flin Flon Paleosol: Clues from REE- and U-rich accessory minerals and implications for paleoatmospheric reconstruction
  4. Os solubility in silicate melts: New efforts and results
  5. Enstatite-forsterite-water equilibria at elevated temperatures and pressures
  6. The OH-F substitution in synthetic pargasite at 1.5 kbar, 850 °C
  7. Uptake of aqueous Pb by Cl-, F–, and OH– apatites: Mineralogic evidence for nucleation mechanisms
  8. Temperature dependence of the hyperfine parameters of synthetic P21/c Mg-Fe clinopyroxenes along the MgSiO3-FeSiO3 join
  9. Single-crystal thermometric calibration of Fe-Mg order-disorder in pigeonites
  10. TEM observations on the P1̄ -I1̄ phase transition in feldspars along the join CaAl2Si2O8-SrAl2Si2O8
  11. Phase transitions induced by solid solution in stuffed derivatives of quartz: A powder synchrotron XRD study of the LiAlSiO4-SiO2 join
  12. The transformation of andalusite to mullite and silica: Part I. Transformation mechanism in [001]A direction
  13. The transformation of andalusite to mullite and silica: Part II. Transformation mechanisms in [100]A and [010]A directions
  14. Structure and twinning of tetragonal Ca3Mn2Ge3O12 garnet
  15. The equation of state of lawsonite to 7 GPa and 873 K, and calculation of its high pressure stability
  16. Boron K-edge XANES of borate and borosilicate minerals
  17. 113Cd double-resonance NMR as a probe of clay mineral cation exchange sites
  18. Solid state NMR study of oxygen site exchange and Al-O-Al site concentration in analcime
  19. Isomorphous substitution effect on the vibration frequencies of hydroxyl groups in molecular cluster models of the clay octahedral sheet
  20. Molecular modeling of the structure and dynamics of the interlayer and surface species of mixed-metal layered hydroxides: Chloride and water in hydrocalumite (Friedel’s salt)
  21. VIII(Mg,Fe)0.85VI(Mg,Fe)4IV(Fe,Ge)3O12: A new tetragonal phase and its comparison with garnet
  22. Rietveld analysis of dicalcium aluminate (Ca2Al2O5) – A new high pressure phase with the Brownmillerite-type structure
  23. Suredaite, PbSnS3, a new mineral species, from the Pirquitas Ag-Sn deposit, NW-Argentina: mineralogy and crystal structure
  24. Kozoite-(Nd), Nd(CO3)(OH), a new mineral in an alkali olivine basalt from Hizen-cho, Saga Prefecture, Japan
  25. Florenskyite, FeTiP, a new phosphide from the Kaidun meteorite
  26. Letters. Computer simulation of high-temperature, forsterite-melt partitioning
https://doi.org/10.2138/am-2000-0725

Articles in the same Issue

  1. Application of new experimental and garnet Margules data to the garnet-biotite geothermometer
  2. Volumes of mixing in aluminosilicate garnets: Solid solution and strain behavior
  3. Cerium anomaly and Th/U fractionation in the 1.85 Ga Flin Flon Paleosol: Clues from REE- and U-rich accessory minerals and implications for paleoatmospheric reconstruction
  4. Os solubility in silicate melts: New efforts and results
  5. Enstatite-forsterite-water equilibria at elevated temperatures and pressures
  6. The OH-F substitution in synthetic pargasite at 1.5 kbar, 850 °C
  7. Uptake of aqueous Pb by Cl-, F–, and OH– apatites: Mineralogic evidence for nucleation mechanisms
  8. Temperature dependence of the hyperfine parameters of synthetic P21/c Mg-Fe clinopyroxenes along the MgSiO3-FeSiO3 join
  9. Single-crystal thermometric calibration of Fe-Mg order-disorder in pigeonites
  10. TEM observations on the P1̄ -I1̄ phase transition in feldspars along the join CaAl2Si2O8-SrAl2Si2O8
  11. Phase transitions induced by solid solution in stuffed derivatives of quartz: A powder synchrotron XRD study of the LiAlSiO4-SiO2 join
  12. The transformation of andalusite to mullite and silica: Part I. Transformation mechanism in [001]A direction
  13. The transformation of andalusite to mullite and silica: Part II. Transformation mechanisms in [100]A and [010]A directions
  14. Structure and twinning of tetragonal Ca3Mn2Ge3O12 garnet
  15. The equation of state of lawsonite to 7 GPa and 873 K, and calculation of its high pressure stability
  16. Boron K-edge XANES of borate and borosilicate minerals
  17. 113Cd double-resonance NMR as a probe of clay mineral cation exchange sites
  18. Solid state NMR study of oxygen site exchange and Al-O-Al site concentration in analcime
  19. Isomorphous substitution effect on the vibration frequencies of hydroxyl groups in molecular cluster models of the clay octahedral sheet
  20. Molecular modeling of the structure and dynamics of the interlayer and surface species of mixed-metal layered hydroxides: Chloride and water in hydrocalumite (Friedel’s salt)
  21. VIII(Mg,Fe)0.85VI(Mg,Fe)4IV(Fe,Ge)3O12: A new tetragonal phase and its comparison with garnet
  22. Rietveld analysis of dicalcium aluminate (Ca2Al2O5) – A new high pressure phase with the Brownmillerite-type structure
  23. Suredaite, PbSnS3, a new mineral species, from the Pirquitas Ag-Sn deposit, NW-Argentina: mineralogy and crystal structure
  24. Kozoite-(Nd), Nd(CO3)(OH), a new mineral in an alkali olivine basalt from Hizen-cho, Saga Prefecture, Japan
  25. Florenskyite, FeTiP, a new phosphide from the Kaidun meteorite
  26. Letters. Computer simulation of high-temperature, forsterite-melt partitioning
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 27.9.2025 from https://www.degruyterbrill.com/document/doi/10.2138/am-2000-0725/html
Scroll to top button