Sol-gel Approaches for Elaboration of Polyol Dehydrogenase-Based Bioelectrodes
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Veronika Urbanova
Abstract
This review describes the input of sol-gel chemistry to the immobilization of polyol dehydrogenases on electrodes, for applications in bioelectrocatalysis. The polyol dehydrogenases are described and their application for biosensing, biofuel cell and electrosynthesis are briefly discussed. The immobilization of proteins via sol-gel approaches is described, including a discussion on the difficulty to maintain the activity of proteins in a silica matrix and the strategies developed to offer a proper environment to the proteins by developing optimal organic-inorganic hybrid materials. Finally, the co-immobilization of the NAD+ co-factor and of mediators for the elaboration of reagentless devices is presented, based on published and original data. All-in-all, sol-gel approaches appear to be a very promising for development of original electrochemical applications involving dehydrogenases in near future.
© by Oldenbourg Wissenschaftsverlag, München, Germany
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- Direct Methanol Fuel Cell – Alternative Materials and Catalyst Preparation
- Growth Kinetics of the Anodic Oxide Film on Platinum under Potentiodynamic Polarization Conditions
- High-Throughput Optical Screening of Electrocatalysts for Fuel Cell Applications – Review and Present Developments
- Sulfonated Aromatic Polymers as Proton-Conducting Solid Electrolytes for Fuel Cells: a Short Review
- Electrocatalyst–Membrane Interface and Fuel Cell Performance with Sulfonated PolyEtherEtherKetone as Ionomer
- Actual State of Technology in Direct Carbon Fuel Cells
- Anodic Electrocatalytic Coatings for Electrolytic Chlorine Production: A Review
- Sol-gel Approaches for Elaboration of Polyol Dehydrogenase-Based Bioelectrodes
- Electrochemistry at the Edge of Reason: Chalcogen-Based Redox Systems in Biochemistry and Drug Design
Artikel in diesem Heft
- Direct Methanol Fuel Cell – Alternative Materials and Catalyst Preparation
- Growth Kinetics of the Anodic Oxide Film on Platinum under Potentiodynamic Polarization Conditions
- High-Throughput Optical Screening of Electrocatalysts for Fuel Cell Applications – Review and Present Developments
- Sulfonated Aromatic Polymers as Proton-Conducting Solid Electrolytes for Fuel Cells: a Short Review
- Electrocatalyst–Membrane Interface and Fuel Cell Performance with Sulfonated PolyEtherEtherKetone as Ionomer
- Actual State of Technology in Direct Carbon Fuel Cells
- Anodic Electrocatalytic Coatings for Electrolytic Chlorine Production: A Review
- Sol-gel Approaches for Elaboration of Polyol Dehydrogenase-Based Bioelectrodes
- Electrochemistry at the Edge of Reason: Chalcogen-Based Redox Systems in Biochemistry and Drug Design
