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On the exchange of molybdenum by rhenium in γ-Mo4–xRexO11
Veröffentlicht/Copyright:
28. Juli 2010
Abstract
We present results of X-ray structure refinement of γ-Mo4–xRexO11 for 0 ≤ x ≤ 1 at room temperature. Single crystals of γ-Mo4–xRexO11 have been grown by chemical transport reaction. Space group Pna21 has been confirmed. The volume of the unit cell is decreasing with increasing Re content. Re substitutes preferably one out of four Mo sites. We propose that this is accomplished by a mixture of Re4+ and Re5+.
Published Online: 2010-7-28
Published in Print: 1999-2-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Artikel in diesem Heft
- A solution of the phase problem. I. Latent lattices and their optimisation
- Elastic properties of citric acid, citric acid hydrate, trilithium citrate tetrahydrate, trisodium citrate pentahydrate, and tripotassium citrate hydrate
- Determination of the superstructures for the stannides ZrIrSn, HfCoSn, and HfRhSn
- On the exchange of molybdenum by rhenium in γ-Mo4–xRexO11
- Rechnerische Simulation eines ein-dimensionalen Fehlordnungsmodells für K0,5V2O5
- New phases in the Yb–Au–Si and Ca–Au–Si systems
- Molecular structures and packing in crystals of ZnX2L2 complexes, having L as a monodentate oxo-ligand
- Molecular and crystal structures of two Nα-protected α-aminoacyl fluorides and their free carboxylic acid synthetic precursors1
- An examination of the influence of crystal structure on molecular structure. The crystal and molecular structures of some diorganotinchloro-(N,N-dialkyldithiocarbamate)s, R2Sn(S2CNR′2)Cl, R = Me, tBu, Ph, Cy; R′2 = (Et)2, (Et, Cy) and (Cy)2: a comparison between solid state and theoretical structures
