Startseite The crystal structure of Cu9.1(1)TeSb3, a stuffed derivative of Cr3Si
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The crystal structure of Cu9.1(1)TeSb3, a stuffed derivative of Cr3Si

Veröffentlicht/Copyright: 28. Juli 2010
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 213 Heft 7-8

Abstract

The intermetallic compound Cu9.1(1)TeSb3 prepared at 973 K is an ordered member of the solid solution Cu64Te31Sb5–Cu70Te8Sb22 which also exists, for more limited composition ranges, between 673 K and 1173 K. It is a stuffed derivative of the structure type A15 (Cr3Si). Te is surrounded by twelve 3/4-occupied Cu-positions in the vertices of a cubically-deformed icosahedron (Cu – Te = 2.614 Å) which itself is nested in an Sb-icosahedron (Cu–Sb = 2.777 Å (×2) and 2.603 Å). The Sb array corresponds to the Cr array in Cr3Si.

Published Online: 2010-7-28
Published in Print: 1998-8-1

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Artikel in diesem Heft

  1. The average atomic volume and density of proteins
  2. The β-Sn dual structure: a 4-connected net based on a packing of simple polyhedra with 18 faces
  3. Synthesis and crystal structure of the new isotypic compounds KBi6O9X (X = Cl, Br, I)
  4. The crystal structure of Cu9.1(1)TeSb3, a stuffed derivative of Cr3Si
  5. Structure and properties of the layer compound NaZnAsO4 · 2H2O
  6. Strukturverfeinerung des monoklinen Tief-Tridymits MC mit Beugungsintensitäten eines verzwillingten Kristalls
  7. Überstruktur des Strontiumvanadiumoxids, Sr0,5V2O5: ihre Zwillingsbildung, Gruppoid-Symmetrie und Interpretation als OD-Struktur
  8. Structural refinement of crystals with m = n = 1 in the series of [M2Cu2O3]m[CuO2]n-type cuprates
  9. Crystal structures of three polymorphic forms of 4-hydroxy-3-methoxy-4′-nitro-trans-stilbene
  10. A new two-dimensional alkoxyacetate of zinc: structure of μ-acetato-μ-[ethane-1,2-olato(−1)]-diacetatodizinc
  11. Structure of 2-(2′-cyano-2′-ethoxycarbonylethylenyl)-pyridine
  12. Dibutyltin derivatives of 4-hydroxy-2,6-pyridine-dicarboxylic (chelidamic) acid. Crystal structures of bis[aquadibutyl(4-hydroxy-2,6-pyridinedicarboxylato)tin] · 2[bis(dicyclohexylammonium) 2,6-pyridinedicarboxylate] and dibutyl(4-hydroxy-2,6-pyridinedicarboxylato)tin
  13. Dibutyltin derivatives of 2,6-pyridinedicarboxylic acids. Crystal structures of bis(diisopropylammonium) tris(2,6-pyridinedicarboxylato)bis(dibutylstannate) trihydrate and bis(diisopropylammonium) bis[aquadibutylstannyl(2,6-pyridinedicarboxylato-4-olate)]
  14. Direct re-determination of the modulated lamellar ‘ripple’ phase of hydrated lecithin
  15. Crystal and molecular structure of cis-bis(monothiodibenzoylmethanato)-dioxomolybdenum(VI)
  16. Books Received
https://doi.org/10.1524/zkri.1998.213.7-8.382

Artikel in diesem Heft

  1. The average atomic volume and density of proteins
  2. The β-Sn dual structure: a 4-connected net based on a packing of simple polyhedra with 18 faces
  3. Synthesis and crystal structure of the new isotypic compounds KBi6O9X (X = Cl, Br, I)
  4. The crystal structure of Cu9.1(1)TeSb3, a stuffed derivative of Cr3Si
  5. Structure and properties of the layer compound NaZnAsO4 · 2H2O
  6. Strukturverfeinerung des monoklinen Tief-Tridymits MC mit Beugungsintensitäten eines verzwillingten Kristalls
  7. Überstruktur des Strontiumvanadiumoxids, Sr0,5V2O5: ihre Zwillingsbildung, Gruppoid-Symmetrie und Interpretation als OD-Struktur
  8. Structural refinement of crystals with m = n = 1 in the series of [M2Cu2O3]m[CuO2]n-type cuprates
  9. Crystal structures of three polymorphic forms of 4-hydroxy-3-methoxy-4′-nitro-trans-stilbene
  10. A new two-dimensional alkoxyacetate of zinc: structure of μ-acetato-μ-[ethane-1,2-olato(−1)]-diacetatodizinc
  11. Structure of 2-(2′-cyano-2′-ethoxycarbonylethylenyl)-pyridine
  12. Dibutyltin derivatives of 4-hydroxy-2,6-pyridine-dicarboxylic (chelidamic) acid. Crystal structures of bis[aquadibutyl(4-hydroxy-2,6-pyridinedicarboxylato)tin] · 2[bis(dicyclohexylammonium) 2,6-pyridinedicarboxylate] and dibutyl(4-hydroxy-2,6-pyridinedicarboxylato)tin
  13. Dibutyltin derivatives of 2,6-pyridinedicarboxylic acids. Crystal structures of bis(diisopropylammonium) tris(2,6-pyridinedicarboxylato)bis(dibutylstannate) trihydrate and bis(diisopropylammonium) bis[aquadibutylstannyl(2,6-pyridinedicarboxylato-4-olate)]
  14. Direct re-determination of the modulated lamellar ‘ripple’ phase of hydrated lecithin
  15. Crystal and molecular structure of cis-bis(monothiodibenzoylmethanato)-dioxomolybdenum(VI)
  16. Books Received
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