Startseite Naturwissenschaften The crystal structure and disorder in tetrapropylammonium tetrafluoroborate, (n-C3H7)4NBF4
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

The crystal structure and disorder in tetrapropylammonium tetrafluoroborate, (n-C3H7)4NBF4

Veröffentlicht/Copyright: 28. Juli 2010
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 212 Heft 5

Abstract

Mr = 273.164, orthorhombic, P212121, a = 12.075(2) Å, b = 13.694(2) Å, c = 9.610(1) Å, V = 1589(3) Å3, Z = 4, Dx = 1.141, Dm = 1.115g cm−3, λ(MoKα) = 0.7107 Å, μ = 0.91 cm−1, F(000) = 592, R = 0.049 for 717 unique reflections with I > 2σ(I). The interaction compound is formed by the tetrapropylammonium cation and the tetrafluoroborate anion. The remarkable features of this crystal at room temperature are: i) the non centrosymmetric structure; ii) the ordered distribution of the fluoroborate tetrahedra, also confirmed by NMR measurements, iii) the partial disorder of the n-propylammonium cations, which are statistically arranged in two orientations symmetrical to a mirror plane.

Published Online: 2010-7-28
Published in Print: 1997-5-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Artikel in diesem Heft

  1. Surface X-ray diffraction on clean and Cs-covered Ag(001)
  2. On the structure of mathematical expressions and crystals
  3. On new settings in some centrosymmetric space groups: an apparently paradoxical situation
  4. Towards the structure determination of proteins from the near edge anomalous dispersion of sulphur: a comparison of first results from trypsin with the known structure
  5. The crystal structures of the cryptates Ag(C222)X, X = ClO4−, NO3−, ClO3−, BrO3−, IO4−, ReO4−, BF4−, PF6−, AsF6−, and Na(C222)X, X = ClO4−, IO4−, ReO4−
  6. Crystal structure of three diaza-crowns-18
  7. The crystal structure and disorder in tetrapropylammonium tetrafluoroborate, (n-C3H7)4NBF4
  8. Crystal and molecular structure of unsubstituted and p-methoxy-substituted acetylbenzoylmethanatoboron difluoride
  9. Structure of 2,10 dichloro 6-(2,3 dimethylphenoxy) dibenzo [d,g] [1,3,6,2]dioxathiaphosphocin 6-sulphide
  10. Crystal structure of bis(triisopropylphosphin)dibromonickel(II), [Ni(Pi-(C3H7)3)2Br2]
  11. Crystal structure of bromo(tricarbonyl)(cyclopentadienyl) molybdenum(II), (C5H5)Mo(CO)3Br
  12. Crystal structure of metaclopromide tetrathiocyanatocobaltate, C28H44O4N6Cl2 · [Co(NCS)4]
  13. Crystal structure of 4-cyanophenyl 4-heptylbenzoate, H3C(CH2)6(C6H4)O(CO)(C6H4)CN
  14. Crystal structure of N-p-methoxybenzylidene p-phenylazoaniline, HCO(C6H4)CN(C6H4)NN(C6H5)
  15. Crystal structure of 2-chlorophenol morpholino complex, (C6H4OCl)2(C4H10ON)
  16. Crystal structure of lignocaine tetrabromozincate, (C14H22ON2)4(ZnBr4)2
  17. Crystal structure of 1:2;7:8-dibenzo-3,6,15,18-tetraaza-tricyclo[13.3.0.02,6] octadeca-1(18),2,4,10,16-pentaene-8,12-diyne, C22H14N4
  18. Crystal structure of 11:12-benzo-13:14-naphtho-1,10-diazabicyclo[8.2.2] tetradeca-5,11,13-triene-3,7-diyne dichloromethane solvate, C22H14N4 · CH2Cl2
  19. Crystal structure of 5-(3,5-di-tert-butyl-4-hydroxybenzyl)-1,3,5-tri-tert-butyl-2-oxo-bicyclo[4.1.0]hept-3-ene, C34H54O2
  20. Biokompatible Werkstoffe und Bauweisen. Implantate für Medizin und Umwelt
  21. Grundlagen der Festkörperphysik
  22. Crystallography
  23. Quasicrystals and Geometry
  24. Tables of Physical and Chemical Constants
  25. Praktische Physik
https://doi.org/10.1524/zkri.1997.212.5.367

Artikel in diesem Heft

  1. Surface X-ray diffraction on clean and Cs-covered Ag(001)
  2. On the structure of mathematical expressions and crystals
  3. On new settings in some centrosymmetric space groups: an apparently paradoxical situation
  4. Towards the structure determination of proteins from the near edge anomalous dispersion of sulphur: a comparison of first results from trypsin with the known structure
  5. The crystal structures of the cryptates Ag(C222)X, X = ClO4−, NO3−, ClO3−, BrO3−, IO4−, ReO4−, BF4−, PF6−, AsF6−, and Na(C222)X, X = ClO4−, IO4−, ReO4−
  6. Crystal structure of three diaza-crowns-18
  7. The crystal structure and disorder in tetrapropylammonium tetrafluoroborate, (n-C3H7)4NBF4
  8. Crystal and molecular structure of unsubstituted and p-methoxy-substituted acetylbenzoylmethanatoboron difluoride
  9. Structure of 2,10 dichloro 6-(2,3 dimethylphenoxy) dibenzo [d,g] [1,3,6,2]dioxathiaphosphocin 6-sulphide
  10. Crystal structure of bis(triisopropylphosphin)dibromonickel(II), [Ni(Pi-(C3H7)3)2Br2]
  11. Crystal structure of bromo(tricarbonyl)(cyclopentadienyl) molybdenum(II), (C5H5)Mo(CO)3Br
  12. Crystal structure of metaclopromide tetrathiocyanatocobaltate, C28H44O4N6Cl2 · [Co(NCS)4]
  13. Crystal structure of 4-cyanophenyl 4-heptylbenzoate, H3C(CH2)6(C6H4)O(CO)(C6H4)CN
  14. Crystal structure of N-p-methoxybenzylidene p-phenylazoaniline, HCO(C6H4)CN(C6H4)NN(C6H5)
  15. Crystal structure of 2-chlorophenol morpholino complex, (C6H4OCl)2(C4H10ON)
  16. Crystal structure of lignocaine tetrabromozincate, (C14H22ON2)4(ZnBr4)2
  17. Crystal structure of 1:2;7:8-dibenzo-3,6,15,18-tetraaza-tricyclo[13.3.0.02,6] octadeca-1(18),2,4,10,16-pentaene-8,12-diyne, C22H14N4
  18. Crystal structure of 11:12-benzo-13:14-naphtho-1,10-diazabicyclo[8.2.2] tetradeca-5,11,13-triene-3,7-diyne dichloromethane solvate, C22H14N4 · CH2Cl2
  19. Crystal structure of 5-(3,5-di-tert-butyl-4-hydroxybenzyl)-1,3,5-tri-tert-butyl-2-oxo-bicyclo[4.1.0]hept-3-ene, C34H54O2
  20. Biokompatible Werkstoffe und Bauweisen. Implantate für Medizin und Umwelt
  21. Grundlagen der Festkörperphysik
  22. Crystallography
  23. Quasicrystals and Geometry
  24. Tables of Physical and Chemical Constants
  25. Praktische Physik
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2026 De Gruyter Brill
Heruntergeladen am 2.2.2026 von https://www.degruyterbrill.com/document/doi/10.1524/zkri.1997.212.5.367/pdf
Button zum nach oben scrollen