Startseite Structure of 2,10 dichloro 6-(2,3 dimethylphenoxy) dibenzo [d,g] [1,3,6,2]dioxathiaphosphocin 6-sulphide
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Structure of 2,10 dichloro 6-(2,3 dimethylphenoxy) dibenzo [d,g] [1,3,6,2]dioxathiaphosphocin 6-sulphide

Veröffentlicht/Copyright: 28. Juli 2010
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 212 Heft 5

Abstract

2,10 Dichloro 6-(2,3 dimethylphenoxy) dibenzo [d. g] [1,3.6,2] dioxathiaphosphocin 6-sulphide (C20H15Cl2O3PS) crystallizes in the triclinic system, P[unk] with a = 7.845(3) Å, b = 11.720(2) Å, c = 11.871(2) Å, a = 88.5(2)°, β = 73.6(2)°, γ = 89.1(2)°, V = 1046.7(4) Å3, Z = 2, Dc = 1.489M gm−3, (MoKα) = 0.71069 Å, F(000) = 480 and T = 293 K. The crystal structure was solved by direct methods and refined by full matrix least-squares method to a final R = 0.0345 for 2701 unique observed reflections [I ≥ 2σ(I)]. The chlorobenzene rings A & B which are at 68.8° to each other, are oriented respectively at 19.9° and 61.6° to the phenyl ring and both are at 36.5° to the best plane of the heterocyclic ring. The heterocyclic ring adopts a distorted boat chair conformation.

Published Online: 2010-7-28
Published in Print: 1997-5-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Artikel in diesem Heft

  1. Surface X-ray diffraction on clean and Cs-covered Ag(001)
  2. On the structure of mathematical expressions and crystals
  3. On new settings in some centrosymmetric space groups: an apparently paradoxical situation
  4. Towards the structure determination of proteins from the near edge anomalous dispersion of sulphur: a comparison of first results from trypsin with the known structure
  5. The crystal structures of the cryptates Ag(C222)X, X = ClO4−, NO3−, ClO3−, BrO3−, IO4−, ReO4−, BF4−, PF6−, AsF6−, and Na(C222)X, X = ClO4−, IO4−, ReO4−
  6. Crystal structure of three diaza-crowns-18
  7. The crystal structure and disorder in tetrapropylammonium tetrafluoroborate, (n-C3H7)4NBF4
  8. Crystal and molecular structure of unsubstituted and p-methoxy-substituted acetylbenzoylmethanatoboron difluoride
  9. Structure of 2,10 dichloro 6-(2,3 dimethylphenoxy) dibenzo [d,g] [1,3,6,2]dioxathiaphosphocin 6-sulphide
  10. Crystal structure of bis(triisopropylphosphin)dibromonickel(II), [Ni(Pi-(C3H7)3)2Br2]
  11. Crystal structure of bromo(tricarbonyl)(cyclopentadienyl) molybdenum(II), (C5H5)Mo(CO)3Br
  12. Crystal structure of metaclopromide tetrathiocyanatocobaltate, C28H44O4N6Cl2 · [Co(NCS)4]
  13. Crystal structure of 4-cyanophenyl 4-heptylbenzoate, H3C(CH2)6(C6H4)O(CO)(C6H4)CN
  14. Crystal structure of N-p-methoxybenzylidene p-phenylazoaniline, HCO(C6H4)CN(C6H4)NN(C6H5)
  15. Crystal structure of 2-chlorophenol morpholino complex, (C6H4OCl)2(C4H10ON)
  16. Crystal structure of lignocaine tetrabromozincate, (C14H22ON2)4(ZnBr4)2
  17. Crystal structure of 1:2;7:8-dibenzo-3,6,15,18-tetraaza-tricyclo[13.3.0.02,6] octadeca-1(18),2,4,10,16-pentaene-8,12-diyne, C22H14N4
  18. Crystal structure of 11:12-benzo-13:14-naphtho-1,10-diazabicyclo[8.2.2] tetradeca-5,11,13-triene-3,7-diyne dichloromethane solvate, C22H14N4 · CH2Cl2
  19. Crystal structure of 5-(3,5-di-tert-butyl-4-hydroxybenzyl)-1,3,5-tri-tert-butyl-2-oxo-bicyclo[4.1.0]hept-3-ene, C34H54O2
  20. Biokompatible Werkstoffe und Bauweisen. Implantate für Medizin und Umwelt
  21. Grundlagen der Festkörperphysik
  22. Crystallography
  23. Quasicrystals and Geometry
  24. Tables of Physical and Chemical Constants
  25. Praktische Physik
https://doi.org/10.1524/zkri.1997.212.5.377

Artikel in diesem Heft

  1. Surface X-ray diffraction on clean and Cs-covered Ag(001)
  2. On the structure of mathematical expressions and crystals
  3. On new settings in some centrosymmetric space groups: an apparently paradoxical situation
  4. Towards the structure determination of proteins from the near edge anomalous dispersion of sulphur: a comparison of first results from trypsin with the known structure
  5. The crystal structures of the cryptates Ag(C222)X, X = ClO4−, NO3−, ClO3−, BrO3−, IO4−, ReO4−, BF4−, PF6−, AsF6−, and Na(C222)X, X = ClO4−, IO4−, ReO4−
  6. Crystal structure of three diaza-crowns-18
  7. The crystal structure and disorder in tetrapropylammonium tetrafluoroborate, (n-C3H7)4NBF4
  8. Crystal and molecular structure of unsubstituted and p-methoxy-substituted acetylbenzoylmethanatoboron difluoride
  9. Structure of 2,10 dichloro 6-(2,3 dimethylphenoxy) dibenzo [d,g] [1,3,6,2]dioxathiaphosphocin 6-sulphide
  10. Crystal structure of bis(triisopropylphosphin)dibromonickel(II), [Ni(Pi-(C3H7)3)2Br2]
  11. Crystal structure of bromo(tricarbonyl)(cyclopentadienyl) molybdenum(II), (C5H5)Mo(CO)3Br
  12. Crystal structure of metaclopromide tetrathiocyanatocobaltate, C28H44O4N6Cl2 · [Co(NCS)4]
  13. Crystal structure of 4-cyanophenyl 4-heptylbenzoate, H3C(CH2)6(C6H4)O(CO)(C6H4)CN
  14. Crystal structure of N-p-methoxybenzylidene p-phenylazoaniline, HCO(C6H4)CN(C6H4)NN(C6H5)
  15. Crystal structure of 2-chlorophenol morpholino complex, (C6H4OCl)2(C4H10ON)
  16. Crystal structure of lignocaine tetrabromozincate, (C14H22ON2)4(ZnBr4)2
  17. Crystal structure of 1:2;7:8-dibenzo-3,6,15,18-tetraaza-tricyclo[13.3.0.02,6] octadeca-1(18),2,4,10,16-pentaene-8,12-diyne, C22H14N4
  18. Crystal structure of 11:12-benzo-13:14-naphtho-1,10-diazabicyclo[8.2.2] tetradeca-5,11,13-triene-3,7-diyne dichloromethane solvate, C22H14N4 · CH2Cl2
  19. Crystal structure of 5-(3,5-di-tert-butyl-4-hydroxybenzyl)-1,3,5-tri-tert-butyl-2-oxo-bicyclo[4.1.0]hept-3-ene, C34H54O2
  20. Biokompatible Werkstoffe und Bauweisen. Implantate für Medizin und Umwelt
  21. Grundlagen der Festkörperphysik
  22. Crystallography
  23. Quasicrystals and Geometry
  24. Tables of Physical and Chemical Constants
  25. Praktische Physik
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