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Crystal and molecular structure of tris (1,3-diphenylpropane-1,3-dionato)cobalt(III)

Veröffentlicht/Copyright: 28. Juli 2010
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 209 Heft 10

Abstract

The title compound appeared to be isomorphous and isostructural to one of two polymorphs of the corresponding iron(III) complexes. The crystals of the complex belong to the triclinic system, space group P[unk]. The cell dimensions are: a = 9.851(3) Å, b = 10.647(3) Å, c = 18.008(6) Å, α = 93.44(2)°, β = 94.91(2)°, γ = 107.14(2)°, V = 179(1) Å3, Z = 2, μ(MoKα = 0.52 mm−1), Dx = 1.351 gcm−3. Data collection was made with Philips PW1100 (STOE upgraded) automatic diffractometer using MoKα radiation. The structure was solved by the heavy-atom method and refined by least-squares techniques to a conventional R factor 0.034 for 2997 unique reflections. The structure is built up of discrete molecules separated by normal van der Waals distances. The cobalt atom coordination is distorted octahedrally with an averaged Co–O bond length 1.833(3) Å. The rotational orientation of the terminal phenyl rings with regard to the plane of the chelate ring are dictated by both electronic and dominant steric effect.

Published Online: 2010-7-28
Published in Print: 1994-10-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Artikel in diesem Heft

  1. Microporous, noncentrosymmetric, octahedral/tetrahedral-framework phases: K2/3Li1/3Nb2PO8, K2/3Li1/3Ta2PO8 and K2/3Ag1/3Nb2PO8
  2. Proton disorder of water molecules in the structure of lithium hydrogen cis-4-cyclohexene-1,2-dicarboxylate dihydrate, LiHC8H8O4 · 2 H2O
  3. Crystal structures of tetrabutylbis[(2-(benzoylthio)acetato)]-distannoxane and tetrabutylbis[2-(2,4-dichloro-5-methylphenylthio)-acetato]distannoxane dimers
  4. Crystal structure of racemic trans-2-(4-methylphenyl)-cyclohexanol
  5. Crystal structure of 2-bromomethyl-1-(2′-methoxy-3,5-dimethyl)-naphthalene1
  6. Structures of the hydrogen (+)-tartrates of sodium, thallium(I) and silver(I)
  7. Crystal structures of N-aryl-N-pentopyranosylamines
  8. Crystal structure of 2-triphenylstannyl 1,2-benzisothiazol-3(2H)-one 1,1-dioxide-quinoline N-oxide (1/1) molecular complex
  9. The Crystal Structure of benzoyl – histidine monohydrate
  10. Crystal and molecular structure of tris (1,3-diphenylpropane-1,3-dionato)cobalt(III)
  11. Crystal and molecular structure of 3,5-dimethyl-N-nitroso-4-oximino-2,6-diphenyl piperidin-4-one(DMNOH)1
  12. Crystal structure of dicaesium tetrachlorothulate(II), Cs2TmCl4
  13. Crystal structure of bis(triphenylphosphine)iminium bis(l,3-dithiole-2-thione-4,5-dithiolato)aurate(III) dichloromethane hemisolvate, [N(P(C6H5)3)2]+[(C3S5)2Au]−· ½ CH2C12
  14. Crystal structure of 2-(1-carboxyphenyl)-N-methylammonium chloride hydrate, [o-HOOC(C6H4)NH2(CH3)]+Cl−·H2O
  15. Crystal structure of 2-(1-carboxyphenyl)-N-methylammonium chloride, [o-HOOC(C6H4)NH2(CH3)]+ Cl−
  16. Redetermination of the crystal structure of N-methylanthranilic acid, o-H3CNHC6H4CO2H
  17. Crystal structure of dimethylammonium bromide, (CH3)2NH2+Br−
  18. Crystal structure of (Z)-3-(4-benzyloxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)propenoic acid, C24H22O6
  19. Crystal structure of 1,3-diisopropyl-4,5-dimethylimidazolium chloride tris(trichlormethane), C11H21CIN2 · 3CHCl3
  20. Crystal structure of μ2-(dicyclohexylphosphino)-μ2-[(bis(trimethylsilyl)methylene)phosphino]hexacarbonyl-diiron(Fe-Fe), ((H3C)3Si)2CP(C6H11)2PFe2(CO)6
  21. Crystal structure of tetracarbonyl(η2,1η4,1 -3-tert-butyl-1,1,5,5-tetrakis(trimethylsilyl)-2,3,4-triphosphapenta-1,4-diene) molybdenum(0), ((H9C4)((H3C)3Si)4(C2P3))Mo(CO)4
  22. Crystal structure of carbonyl(η1.2,2η4.5,2 -3-tert-butyl-1,1,5,5-tetrakis(trimethylsilyl)-2,3,4-triphosphapenta-1,4-diene)-nickel(0), ((H3C)3Si)4(C4H9)C2P3NiCO
  23. Crystal structure of μ2-(di-tert-butylphosphino)-μ2-[(dicarbonyl-η2-(bis(trimethylsilyl)methylene)phosphino)-nickel(0)]-tetracarbonyldinickel(Ni-Ni), (C4H9)2P[((CH3)3Si)2CPNi(CO)2](CO)4Ni2
  24. Crystal structure of dicarbonyl(cyclopentadienyl)-[2-tert-butyl-3-phenyl-3-trimethylsilyl]diphosphiranido(1−)iron, (H5C6)((H3C)3Si)C(H9C4)P2Fe(CO)2(C5H5)
  25. Crystal structure of (5R,2R)-5-chloro-1-methoxycarbonyl-piperidine-2-carboxylic acid amide, C8H13ClN2O3
  26. Crystal structure of cesium-tert-butanolate, CsOC4H9
https://doi.org/10.1524/zkri.1994.209.10.818

Artikel in diesem Heft

  1. Microporous, noncentrosymmetric, octahedral/tetrahedral-framework phases: K2/3Li1/3Nb2PO8, K2/3Li1/3Ta2PO8 and K2/3Ag1/3Nb2PO8
  2. Proton disorder of water molecules in the structure of lithium hydrogen cis-4-cyclohexene-1,2-dicarboxylate dihydrate, LiHC8H8O4 · 2 H2O
  3. Crystal structures of tetrabutylbis[(2-(benzoylthio)acetato)]-distannoxane and tetrabutylbis[2-(2,4-dichloro-5-methylphenylthio)-acetato]distannoxane dimers
  4. Crystal structure of racemic trans-2-(4-methylphenyl)-cyclohexanol
  5. Crystal structure of 2-bromomethyl-1-(2′-methoxy-3,5-dimethyl)-naphthalene1
  6. Structures of the hydrogen (+)-tartrates of sodium, thallium(I) and silver(I)
  7. Crystal structures of N-aryl-N-pentopyranosylamines
  8. Crystal structure of 2-triphenylstannyl 1,2-benzisothiazol-3(2H)-one 1,1-dioxide-quinoline N-oxide (1/1) molecular complex
  9. The Crystal Structure of benzoyl – histidine monohydrate
  10. Crystal and molecular structure of tris (1,3-diphenylpropane-1,3-dionato)cobalt(III)
  11. Crystal and molecular structure of 3,5-dimethyl-N-nitroso-4-oximino-2,6-diphenyl piperidin-4-one(DMNOH)1
  12. Crystal structure of dicaesium tetrachlorothulate(II), Cs2TmCl4
  13. Crystal structure of bis(triphenylphosphine)iminium bis(l,3-dithiole-2-thione-4,5-dithiolato)aurate(III) dichloromethane hemisolvate, [N(P(C6H5)3)2]+[(C3S5)2Au]−· ½ CH2C12
  14. Crystal structure of 2-(1-carboxyphenyl)-N-methylammonium chloride hydrate, [o-HOOC(C6H4)NH2(CH3)]+Cl−·H2O
  15. Crystal structure of 2-(1-carboxyphenyl)-N-methylammonium chloride, [o-HOOC(C6H4)NH2(CH3)]+ Cl−
  16. Redetermination of the crystal structure of N-methylanthranilic acid, o-H3CNHC6H4CO2H
  17. Crystal structure of dimethylammonium bromide, (CH3)2NH2+Br−
  18. Crystal structure of (Z)-3-(4-benzyloxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)propenoic acid, C24H22O6
  19. Crystal structure of 1,3-diisopropyl-4,5-dimethylimidazolium chloride tris(trichlormethane), C11H21CIN2 · 3CHCl3
  20. Crystal structure of μ2-(dicyclohexylphosphino)-μ2-[(bis(trimethylsilyl)methylene)phosphino]hexacarbonyl-diiron(Fe-Fe), ((H3C)3Si)2CP(C6H11)2PFe2(CO)6
  21. Crystal structure of tetracarbonyl(η2,1η4,1 -3-tert-butyl-1,1,5,5-tetrakis(trimethylsilyl)-2,3,4-triphosphapenta-1,4-diene) molybdenum(0), ((H9C4)((H3C)3Si)4(C2P3))Mo(CO)4
  22. Crystal structure of carbonyl(η1.2,2η4.5,2 -3-tert-butyl-1,1,5,5-tetrakis(trimethylsilyl)-2,3,4-triphosphapenta-1,4-diene)-nickel(0), ((H3C)3Si)4(C4H9)C2P3NiCO
  23. Crystal structure of μ2-(di-tert-butylphosphino)-μ2-[(dicarbonyl-η2-(bis(trimethylsilyl)methylene)phosphino)-nickel(0)]-tetracarbonyldinickel(Ni-Ni), (C4H9)2P[((CH3)3Si)2CPNi(CO)2](CO)4Ni2
  24. Crystal structure of dicarbonyl(cyclopentadienyl)-[2-tert-butyl-3-phenyl-3-trimethylsilyl]diphosphiranido(1−)iron, (H5C6)((H3C)3Si)C(H9C4)P2Fe(CO)2(C5H5)
  25. Crystal structure of (5R,2R)-5-chloro-1-methoxycarbonyl-piperidine-2-carboxylic acid amide, C8H13ClN2O3
  26. Crystal structure of cesium-tert-butanolate, CsOC4H9
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