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Structures of the hydrogen (+)-tartrates of sodium, thallium(I) and silver(I)

Veröffentlicht/Copyright: 28. Juli 2010
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 209 Heft 10

Abstract

The crystal structures of the sodium, thallium(I) and Silver(I) salts of hydrogen (+)-tartrate, Na+(HC4H4O6)−, (1) Tl+(HC4H4O6)−, (2) and Ag+ · (HC4H4O6)− · H2O, (3) have been determined by X-ray diffraction and refined to residuals R = 0.033, 0.028 and 0.019 for 2038, 1009 and 651 observed reflections respectively. All structures are network polymers with metal centres involved in coordination to both carboxylate and hydroxyl oxygens of tartrate residues, and in the case of (3), to a single water. The anhydrous sodium compound, (1) differs from the common monohydrate in having distorted octahedral coordination about the metal, linking six different tartrate residues [4 carboxyl, 2 hydroxyl: Na–O range, 2.319(1)–2.460(1) Å]. The thallium(I) salt (2) is a member of an isomorphous series (which includes the NH4+, K+, Rb+ and Cs+ salts), with square antiprismatic coordination about Tl[5 carboxyl, 3 hydroxyl: Tl–O range 2.805(8)–3.188(8) Å]. The monohydrated silver hydrogen tartrate salt (3) is similar to but not isomorphous with Na+(HC4H4O6)− · H2O, with the water and five tartrate oxygens coordinated [3 carboxyl, 2 hydroxyl: Ag–O range, 2.353(4)–2.801(3) Å]. The stereochemistry about silver in (3) is distorted skew trapezoidal bipyramidal.

Published Online: 2010-7-28
Published in Print: 1994-10-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Artikel in diesem Heft

  1. Microporous, noncentrosymmetric, octahedral/tetrahedral-framework phases: K2/3Li1/3Nb2PO8, K2/3Li1/3Ta2PO8 and K2/3Ag1/3Nb2PO8
  2. Proton disorder of water molecules in the structure of lithium hydrogen cis-4-cyclohexene-1,2-dicarboxylate dihydrate, LiHC8H8O4 · 2 H2O
  3. Crystal structures of tetrabutylbis[(2-(benzoylthio)acetato)]-distannoxane and tetrabutylbis[2-(2,4-dichloro-5-methylphenylthio)-acetato]distannoxane dimers
  4. Crystal structure of racemic trans-2-(4-methylphenyl)-cyclohexanol
  5. Crystal structure of 2-bromomethyl-1-(2′-methoxy-3,5-dimethyl)-naphthalene1
  6. Structures of the hydrogen (+)-tartrates of sodium, thallium(I) and silver(I)
  7. Crystal structures of N-aryl-N-pentopyranosylamines
  8. Crystal structure of 2-triphenylstannyl 1,2-benzisothiazol-3(2H)-one 1,1-dioxide-quinoline N-oxide (1/1) molecular complex
  9. The Crystal Structure of benzoyl – histidine monohydrate
  10. Crystal and molecular structure of tris (1,3-diphenylpropane-1,3-dionato)cobalt(III)
  11. Crystal and molecular structure of 3,5-dimethyl-N-nitroso-4-oximino-2,6-diphenyl piperidin-4-one(DMNOH)1
  12. Crystal structure of dicaesium tetrachlorothulate(II), Cs2TmCl4
  13. Crystal structure of bis(triphenylphosphine)iminium bis(l,3-dithiole-2-thione-4,5-dithiolato)aurate(III) dichloromethane hemisolvate, [N(P(C6H5)3)2]+[(C3S5)2Au]−· ½ CH2C12
  14. Crystal structure of 2-(1-carboxyphenyl)-N-methylammonium chloride hydrate, [o-HOOC(C6H4)NH2(CH3)]+Cl−·H2O
  15. Crystal structure of 2-(1-carboxyphenyl)-N-methylammonium chloride, [o-HOOC(C6H4)NH2(CH3)]+ Cl−
  16. Redetermination of the crystal structure of N-methylanthranilic acid, o-H3CNHC6H4CO2H
  17. Crystal structure of dimethylammonium bromide, (CH3)2NH2+Br−
  18. Crystal structure of (Z)-3-(4-benzyloxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)propenoic acid, C24H22O6
  19. Crystal structure of 1,3-diisopropyl-4,5-dimethylimidazolium chloride tris(trichlormethane), C11H21CIN2 · 3CHCl3
  20. Crystal structure of μ2-(dicyclohexylphosphino)-μ2-[(bis(trimethylsilyl)methylene)phosphino]hexacarbonyl-diiron(Fe-Fe), ((H3C)3Si)2CP(C6H11)2PFe2(CO)6
  21. Crystal structure of tetracarbonyl(η2,1η4,1 -3-tert-butyl-1,1,5,5-tetrakis(trimethylsilyl)-2,3,4-triphosphapenta-1,4-diene) molybdenum(0), ((H9C4)((H3C)3Si)4(C2P3))Mo(CO)4
  22. Crystal structure of carbonyl(η1.2,2η4.5,2 -3-tert-butyl-1,1,5,5-tetrakis(trimethylsilyl)-2,3,4-triphosphapenta-1,4-diene)-nickel(0), ((H3C)3Si)4(C4H9)C2P3NiCO
  23. Crystal structure of μ2-(di-tert-butylphosphino)-μ2-[(dicarbonyl-η2-(bis(trimethylsilyl)methylene)phosphino)-nickel(0)]-tetracarbonyldinickel(Ni-Ni), (C4H9)2P[((CH3)3Si)2CPNi(CO)2](CO)4Ni2
  24. Crystal structure of dicarbonyl(cyclopentadienyl)-[2-tert-butyl-3-phenyl-3-trimethylsilyl]diphosphiranido(1−)iron, (H5C6)((H3C)3Si)C(H9C4)P2Fe(CO)2(C5H5)
  25. Crystal structure of (5R,2R)-5-chloro-1-methoxycarbonyl-piperidine-2-carboxylic acid amide, C8H13ClN2O3
  26. Crystal structure of cesium-tert-butanolate, CsOC4H9
https://doi.org/10.1524/zkri.1994.209.10.803

Artikel in diesem Heft

  1. Microporous, noncentrosymmetric, octahedral/tetrahedral-framework phases: K2/3Li1/3Nb2PO8, K2/3Li1/3Ta2PO8 and K2/3Ag1/3Nb2PO8
  2. Proton disorder of water molecules in the structure of lithium hydrogen cis-4-cyclohexene-1,2-dicarboxylate dihydrate, LiHC8H8O4 · 2 H2O
  3. Crystal structures of tetrabutylbis[(2-(benzoylthio)acetato)]-distannoxane and tetrabutylbis[2-(2,4-dichloro-5-methylphenylthio)-acetato]distannoxane dimers
  4. Crystal structure of racemic trans-2-(4-methylphenyl)-cyclohexanol
  5. Crystal structure of 2-bromomethyl-1-(2′-methoxy-3,5-dimethyl)-naphthalene1
  6. Structures of the hydrogen (+)-tartrates of sodium, thallium(I) and silver(I)
  7. Crystal structures of N-aryl-N-pentopyranosylamines
  8. Crystal structure of 2-triphenylstannyl 1,2-benzisothiazol-3(2H)-one 1,1-dioxide-quinoline N-oxide (1/1) molecular complex
  9. The Crystal Structure of benzoyl – histidine monohydrate
  10. Crystal and molecular structure of tris (1,3-diphenylpropane-1,3-dionato)cobalt(III)
  11. Crystal and molecular structure of 3,5-dimethyl-N-nitroso-4-oximino-2,6-diphenyl piperidin-4-one(DMNOH)1
  12. Crystal structure of dicaesium tetrachlorothulate(II), Cs2TmCl4
  13. Crystal structure of bis(triphenylphosphine)iminium bis(l,3-dithiole-2-thione-4,5-dithiolato)aurate(III) dichloromethane hemisolvate, [N(P(C6H5)3)2]+[(C3S5)2Au]−· ½ CH2C12
  14. Crystal structure of 2-(1-carboxyphenyl)-N-methylammonium chloride hydrate, [o-HOOC(C6H4)NH2(CH3)]+Cl−·H2O
  15. Crystal structure of 2-(1-carboxyphenyl)-N-methylammonium chloride, [o-HOOC(C6H4)NH2(CH3)]+ Cl−
  16. Redetermination of the crystal structure of N-methylanthranilic acid, o-H3CNHC6H4CO2H
  17. Crystal structure of dimethylammonium bromide, (CH3)2NH2+Br−
  18. Crystal structure of (Z)-3-(4-benzyloxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)propenoic acid, C24H22O6
  19. Crystal structure of 1,3-diisopropyl-4,5-dimethylimidazolium chloride tris(trichlormethane), C11H21CIN2 · 3CHCl3
  20. Crystal structure of μ2-(dicyclohexylphosphino)-μ2-[(bis(trimethylsilyl)methylene)phosphino]hexacarbonyl-diiron(Fe-Fe), ((H3C)3Si)2CP(C6H11)2PFe2(CO)6
  21. Crystal structure of tetracarbonyl(η2,1η4,1 -3-tert-butyl-1,1,5,5-tetrakis(trimethylsilyl)-2,3,4-triphosphapenta-1,4-diene) molybdenum(0), ((H9C4)((H3C)3Si)4(C2P3))Mo(CO)4
  22. Crystal structure of carbonyl(η1.2,2η4.5,2 -3-tert-butyl-1,1,5,5-tetrakis(trimethylsilyl)-2,3,4-triphosphapenta-1,4-diene)-nickel(0), ((H3C)3Si)4(C4H9)C2P3NiCO
  23. Crystal structure of μ2-(di-tert-butylphosphino)-μ2-[(dicarbonyl-η2-(bis(trimethylsilyl)methylene)phosphino)-nickel(0)]-tetracarbonyldinickel(Ni-Ni), (C4H9)2P[((CH3)3Si)2CPNi(CO)2](CO)4Ni2
  24. Crystal structure of dicarbonyl(cyclopentadienyl)-[2-tert-butyl-3-phenyl-3-trimethylsilyl]diphosphiranido(1−)iron, (H5C6)((H3C)3Si)C(H9C4)P2Fe(CO)2(C5H5)
  25. Crystal structure of (5R,2R)-5-chloro-1-methoxycarbonyl-piperidine-2-carboxylic acid amide, C8H13ClN2O3
  26. Crystal structure of cesium-tert-butanolate, CsOC4H9
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