Home Physical Sciences The crystal structures of 1-(3′,5′-dinitrobenzoyloxy)-bicyclo[3.3.1]-9-oxanonane and 5-(3′,5′-dinitrobenzoyloxy)-cyclooctanone1
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The crystal structures of 1-(3′,5′-dinitrobenzoyloxy)-bicyclo[3.3.1]-9-oxanonane and 5-(3′,5′-dinitrobenzoyloxy)-cyclooctanone1

Published/Copyright: August 25, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 163 Issue 1-2

Abstract

The crystal structures of the title compounds (3) and (4) have been determined. (3): P21/c, a = 13.765(2), b = 6.012(1), c = 18.780(3) Å, β = 102.34(2)°, Z = 4, R = 0.038 for 2145 unique observed reflections. The ground state extension to 1.468 Ă of the bond to the leaving group (with respect to acetal hydrolysis) occurs without assistance from the lone pair electrons of the ring oxygen, since the endocyclic acetal bond length is unaffected. (4): P21/n, a = 12.989(3), b = 6.512(2), c = 18.701(5) Å, β = 97.23(2)°, Z = 4, R = 0.056 for 1739 unique observed reflections. This ring-opened isomer of (3) shows no ground state features connected with the ready transannular cyclisation.

Published Online: 2010-8-25
Published in Print: 1983-1-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Articles in the same Issue

  1. Crystal chemistry of compounds M3O[TO4]
  2. The crystal structure of C.I. Pigment Yellow 3, α-(1-hydroxyethylidene)-2-chloro-acetanilide-α-azo-(4′-chloro-2′-nitrobenzene)
  3. Solid-state reactions in “salt X”
  4. Grandite garnet structures in connection with the growth mechanism
  5. The crystal structure and electron density of tetraphenyl-silicon, (C6H5)4Si
  6. Effects of symmetry and atomic heterogeneity on X-ray intensities – a case of hypercentric distribution*
  7. Refinement of a partially disordered natrolite, Na2Al2Si3O10 · 2H2O
  8. The crystal structures of 1-(3′,5′-dinitrobenzoyloxy)-bicyclo[3.3.1]-9-oxanonane and 5-(3′,5′-dinitrobenzoyloxy)-cyclooctanone1
  9. The crystal structure of methoxymethoxy-2,4-dinitrobenzene1
  10. The crystal structure of 2-(3′,5′-dinitrobenzoyloxy)-tetrahydropyran Cyclohexane Solvate1
  11. The crystal structure of 2-(N-phthalimidomethoxy)-tetrahydropyran1
  12. The crystal structure of 9-oxabicyclo[3.3.1]non-1-yl diphenyl phosphate1
  13. The crystal structure of 9-oxabicyclo[3.3.1]non-l-yl methanesulphonate1
  14. Crystal and molecular structure of bis-tetrasulphurtetranitride-tetrachlorotin
  15. The crystal structure of 1,2-dibenzylidenehydrazinium hexafluoroarsenate
  16. Possible incommensurate phase in KFeF4
  17. The crystal structure of aceto-acetanilide azo-pigments II. C.I. Pigment Yellow 6, α-(1-hydroxyethylidene)acetanilide-α-azo-(4′-chloro-2′-nitrobenzene)
  18. The crystal structure of zinc(II) fumarate tetrahydrate
  19. The crystal structure of manganese(II) succinate tetrahydrate
https://doi.org/10.1524/zkri.1983.163.1-2.75

Articles in the same Issue

  1. Crystal chemistry of compounds M3O[TO4]
  2. The crystal structure of C.I. Pigment Yellow 3, α-(1-hydroxyethylidene)-2-chloro-acetanilide-α-azo-(4′-chloro-2′-nitrobenzene)
  3. Solid-state reactions in “salt X”
  4. Grandite garnet structures in connection with the growth mechanism
  5. The crystal structure and electron density of tetraphenyl-silicon, (C6H5)4Si
  6. Effects of symmetry and atomic heterogeneity on X-ray intensities – a case of hypercentric distribution*
  7. Refinement of a partially disordered natrolite, Na2Al2Si3O10 · 2H2O
  8. The crystal structures of 1-(3′,5′-dinitrobenzoyloxy)-bicyclo[3.3.1]-9-oxanonane and 5-(3′,5′-dinitrobenzoyloxy)-cyclooctanone1
  9. The crystal structure of methoxymethoxy-2,4-dinitrobenzene1
  10. The crystal structure of 2-(3′,5′-dinitrobenzoyloxy)-tetrahydropyran Cyclohexane Solvate1
  11. The crystal structure of 2-(N-phthalimidomethoxy)-tetrahydropyran1
  12. The crystal structure of 9-oxabicyclo[3.3.1]non-1-yl diphenyl phosphate1
  13. The crystal structure of 9-oxabicyclo[3.3.1]non-l-yl methanesulphonate1
  14. Crystal and molecular structure of bis-tetrasulphurtetranitride-tetrachlorotin
  15. The crystal structure of 1,2-dibenzylidenehydrazinium hexafluoroarsenate
  16. Possible incommensurate phase in KFeF4
  17. The crystal structure of aceto-acetanilide azo-pigments II. C.I. Pigment Yellow 6, α-(1-hydroxyethylidene)acetanilide-α-azo-(4′-chloro-2′-nitrobenzene)
  18. The crystal structure of zinc(II) fumarate tetrahydrate
  19. The crystal structure of manganese(II) succinate tetrahydrate
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