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The crystal structures of yttrium, holmium and erbium formate dihydrates*
Veröffentlicht/Copyright:
25. August 2010
Abstract
Crystal structures of orthorhombic P212121 isomorphous Y, Ho and Er formate dihydrates [Y(HCO2)3 · 2 H2O] have been determined from X-ray diffraction data. The metal atom is coordinated by eight oxygens in a distorted D4d square antiprism. Two of the oxygens are associated with water, six with the three formate groups. The three formate groups link the metal polyhedra to a three dimensional framework structure. Lanthanide contraction is expressed in slightly shorter M–O distances in Er-formate dihydrate.
Published Online: 2010-8-25
Published in Print: 1981-1-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Artikel in diesem Heft
- Die Kristallstruktur von synthetischem Ammoniumtetraboratdihydrat, (NH4)2[B4O5(OH)4]·2H2O
- Structures of three crystals containing approximately — linear chains of triiodide ions
- Graph-theoretic construction of periodic bond chains II. Ionic case
- Neutron diffraction study of alums L The crystal structure of hydroxylammonium aluminium alum L The crystal structure of hydroxylammonium aluminium alum
- Structure cristalline de l'octamolybdate de 3-ethyl pyridinium ápolyanions discrets [MO8O26]4−
- The structure of hydrohematite
- Verfeinerung der Kristallstrukturen von Li2SiO3 und Li2GeO3
- Crystal and molecular structures of (l)acetatobis(acetone S-methylthiosemicarbazone)cobalt(II) iodide and (2)acetato-bis(acetone S-methylthiosemicarbazone) nickel(II) iodide*
- The frameworks of sodalite-like structures and of tetrahedrite-like structures1
- Crystal structure of beryllium polyphosphate BeP2O6 III – a derivative of silica K (keatite)
- Optical, electrooptical and piezoelectric constants of d( + )-camphoric acid acetone
- Beobachtung einer Wachstumsinstabilität durch Kathodolumineszenz
- The crystal structures of yttrium, holmium and erbium formate dihydrates*
- Gas-flame, high-temperature apparatus for single-crystal X-ray diffraction studies
- Crystal and molecular structure of bromobis(N,N’-dibenzylethylenediamine)copper(II) bromide
