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Structure cristalline de l'octamolybdate de 3-ethyl pyridinium ápolyanions discrets [MO8O26]4−
Published/Copyright:
August 25, 2010
Abstract
The title compound MO8O26(C7NH10)4 crystallizes in the monoclinic system, space group P21/n with parameters a = 13.807(4), b = 10.979(9), c = 14.319(5)Å, and β = 91.53(3)°. The crystal structure has been refined to R = 0.024 for 3530 hkl reflections. The cell contains a [MO8O26]4− polyanion and two crystallographically independent 3-ethyl pyridinium cations. The network exhibits infinite chains of polyanions bridged by one of these 3-ethyl pyridinium cations and piled up in the (101) plane. In between these layers [MO8O26(C7NH10)2]n2− the remaining cations are inserted. Both independent cations exhibit analogous conformational features.
Published Online: 2010-8-25
Published in Print: 1981-1-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Articles in the same Issue
- Die Kristallstruktur von synthetischem Ammoniumtetraboratdihydrat, (NH4)2[B4O5(OH)4]·2H2O
- Structures of three crystals containing approximately — linear chains of triiodide ions
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- Neutron diffraction study of alums L The crystal structure of hydroxylammonium aluminium alum L The crystal structure of hydroxylammonium aluminium alum
- Structure cristalline de l'octamolybdate de 3-ethyl pyridinium ápolyanions discrets [MO8O26]4−
- The structure of hydrohematite
- Verfeinerung der Kristallstrukturen von Li2SiO3 und Li2GeO3
- Crystal and molecular structures of (l)acetatobis(acetone S-methylthiosemicarbazone)cobalt(II) iodide and (2)acetato-bis(acetone S-methylthiosemicarbazone) nickel(II) iodide*
- The frameworks of sodalite-like structures and of tetrahedrite-like structures1
- Crystal structure of beryllium polyphosphate BeP2O6 III – a derivative of silica K (keatite)
- Optical, electrooptical and piezoelectric constants of d( + )-camphoric acid acetone
- Beobachtung einer Wachstumsinstabilität durch Kathodolumineszenz
- The crystal structures of yttrium, holmium and erbium formate dihydrates*
- Gas-flame, high-temperature apparatus for single-crystal X-ray diffraction studies
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