The crystal structure of dithiobismorpholine (C4H8NOS)2
Abstract
The crystal and molecular structure of dithiobismorpholine has been determined by X-ray diffraction techniques. It crystallises in the monoclinic system with cell parameters a = 5.69 ± 0.03 Å, b = 8.86 ± 0.04 Å, c = 22.59 ± 0.08 Å, ββ = 92.5 ± 0.2°. The space group is P21/n and there are four molecules per unit cell. Three dimensional data were collected using a Weissenberg camera, the structure solved from a Patterson synthesis and least-squares refinement has been completed. The hydrogen atoms have been found and included but not refined. The final residual is 7.0%. The structure consists of discrete molecules which are bent into a somewhat open horse-shoe shape and are associated in pairs with open ends facing. They are linked by van der Waals forces. Within the molecule the following mean bond lengths have been found (uncorrected for thermal motion): sulphur—sulphur 2.068(8) Å, sulphur—nitrogen 1.687(7) Å, nitrogen—carbon 1.454(7) Å, carbon—carbon 1.510(9) Å and carbon—oxygen 1.422(8) Å.
Articles in the same Issue
- Rules governing the layer organization of inorganic crystal structures *
- Condensed models of structures based on loose packings*
- Crystal data for β naphthyl and some substituted phenyl maleamic acids
- Dipole-dipole van der Waals interaction in alkali halides
- Some properties of alkaline earth chalcides and heavy metal halides
- The crystal structure of dithiobismorpholine (C4H8NOS)2
- Partial information about structures with the aid of convolutions
- The crystal structures of germanate micas, KMg2.5Ge4O10F2 and KLiMg2Ge4O10F2
- Optical microscopic examination of orthorhombic Na2SO4 (III) in relation to its transformation to Na2SO4(I) hexagonal*
- Elastic, thermoelastic, piezoelectric, linear electrooptic, dielectric, and pyroelectric properties of trigonal Ca3(VO4)2 single crystals
- Refinement of the structure of thiourea: A neutron diffraction study at 293 K
- Zur Kristallstruktur von Natriumnitrat
- Types of sphere packings for crystallographic point groups, rod groups and layer groups
- X-ray powder data and crystallographic data of copper-salicylaldehyde-s-methylthiosemicarbazone and copper-8-quinolinealdehyde-s-methyltliiosemicarbazone complexes
- An X-ray study of cadmium bromate dihydrate
- Crystal data for 4-4′-tetramethyl-diamino-azobenzene
- An X-ray study of 2-mercapto benzimidazole
- Crystallographic data for the mesogenic material cholesteryl methyl carbonate
Articles in the same Issue
- Rules governing the layer organization of inorganic crystal structures *
- Condensed models of structures based on loose packings*
- Crystal data for β naphthyl and some substituted phenyl maleamic acids
- Dipole-dipole van der Waals interaction in alkali halides
- Some properties of alkaline earth chalcides and heavy metal halides
- The crystal structure of dithiobismorpholine (C4H8NOS)2
- Partial information about structures with the aid of convolutions
- The crystal structures of germanate micas, KMg2.5Ge4O10F2 and KLiMg2Ge4O10F2
- Optical microscopic examination of orthorhombic Na2SO4 (III) in relation to its transformation to Na2SO4(I) hexagonal*
- Elastic, thermoelastic, piezoelectric, linear electrooptic, dielectric, and pyroelectric properties of trigonal Ca3(VO4)2 single crystals
- Refinement of the structure of thiourea: A neutron diffraction study at 293 K
- Zur Kristallstruktur von Natriumnitrat
- Types of sphere packings for crystallographic point groups, rod groups and layer groups
- X-ray powder data and crystallographic data of copper-salicylaldehyde-s-methylthiosemicarbazone and copper-8-quinolinealdehyde-s-methyltliiosemicarbazone complexes
- An X-ray study of cadmium bromate dihydrate
- Crystal data for 4-4′-tetramethyl-diamino-azobenzene
- An X-ray study of 2-mercapto benzimidazole
- Crystallographic data for the mesogenic material cholesteryl methyl carbonate
