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The crystal structure of anhydrous zinc metaborate Zn4O(BO2)6
Veröffentlicht/Copyright:
28. Juli 2010
Abstract
The crystal structure of zinc metaborate has been determined by single crystal x-ray methods. The crystals have cubic symmetry with a = 7.48±0.01 Å, space group I[unk]3m, and two molecules in the unit cell. A complete set of atomic parameters has been determined by Patterson and electron-density projections and the final parameters have been refined by (Fo–Fc) syntheses. The structure has all boron atoms in four-fold coordination. All these tetrahedra are linked to each other forming a three-dimensional framework. The zinc ion lies inside of a tetrahedron whose corners are occupied by three oxygen atoms of the metaborate ion and a free oxygen atom.
Published Online: 2010-07-28
Published in Print: 1964-06
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- Struktur elektrolytischer Schichten im Endwachstum* Eine Untersuchung des Zusammenhanges von Oberflächenform und Vorzugsorientierung mit den Methoden der Elektronenbeugung und Elektronenmikroskopie
- The crystal structure of barium hydroxide octahydrate Ba(OH)2·8H2O*
- The crystal structure of anhydrous zinc metaborate Zn4O(BO2)6
- Relations between diffuse reflections and geometry of the unit cells in isomorphous compounds [Me(II)(N2H4)2]Cl2
- An electron-diffraction study of NaF thin films condensed in vacuum
- Crystal structure of an authigenic maximum microcline
- The crystal structure of tetrahedrite, Cu12Sb4S13
- Stacking relations in the hexagonal ferrites and a new series of mixed-layer structures*
- Crystallographic data for NiSeO4 · 6H2O and MgSeO4 · 6H2O
- Unit cell and space group of B-trimethyl N-triphenyl borazole, B3(CH3)3N3(C6H5)3
- Zur Gitterstruktur von (c-C6H11)2P(O)SH und (c-C6H 1)2(S)P-P(S)(c-C6H11)2
- Errata
- Q values for indexing x-ray powder patterns according to Ito.
- Errata
- International Conference on Electron Diffraction and Crystal Defects, Melbourne, 1965
Artikel in diesem Heft
- Struktur elektrolytischer Schichten im Endwachstum* Eine Untersuchung des Zusammenhanges von Oberflächenform und Vorzugsorientierung mit den Methoden der Elektronenbeugung und Elektronenmikroskopie
- The crystal structure of barium hydroxide octahydrate Ba(OH)2·8H2O*
- The crystal structure of anhydrous zinc metaborate Zn4O(BO2)6
- Relations between diffuse reflections and geometry of the unit cells in isomorphous compounds [Me(II)(N2H4)2]Cl2
- An electron-diffraction study of NaF thin films condensed in vacuum
- Crystal structure of an authigenic maximum microcline
- The crystal structure of tetrahedrite, Cu12Sb4S13
- Stacking relations in the hexagonal ferrites and a new series of mixed-layer structures*
- Crystallographic data for NiSeO4 · 6H2O and MgSeO4 · 6H2O
- Unit cell and space group of B-trimethyl N-triphenyl borazole, B3(CH3)3N3(C6H5)3
- Zur Gitterstruktur von (c-C6H11)2P(O)SH und (c-C6H 1)2(S)P-P(S)(c-C6H11)2
- Errata
- Q values for indexing x-ray powder patterns according to Ito.
- Errata
- International Conference on Electron Diffraction and Crystal Defects, Melbourne, 1965
