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The crystal structure of barium hydroxide octahydrate Ba(OH)2·8H2O*

Published/Copyright: July 28, 2010
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Zeitschrift für Kristallographie
From the journal Zeitschrift für Kristallographie Volume 119 Issue 5-6

Abstract

An x-ray analysis of the crystal structure of barium hydroxide octahydrate has been carried out by two-dimensional Fourier methods. The monoclinic crystals belong to the space group P21/n and have four formula units in a cell of dimensions a = 9.35 Å, b = 9.28 Å, c = 11.87 Å with β = 99°. The R factor for 1020 visually observed reflections in eight zones is 0.124. The barium ion in this structure is found to be coordinated by eight water oxygens in the form of a slightly distorted Archimedean antiprism at distances between 2,69 Å and 2.77 Å. Based on the interatomic distances hydrogen bonds have been proposed, which link the oxygen atoms with one another utilising all the hydrogen atoms in the unit cell.

Published Online: 2010-07-28
Published in Print: 1964-06

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  1. Struktur elektrolytischer Schichten im Endwachstum* Eine Untersuchung des Zusammenhanges von Oberflächenform und Vorzugsorientierung mit den Methoden der Elektronenbeugung und Elektronenmikroskopie
  2. The crystal structure of barium hydroxide octahydrate Ba(OH)2·8H2O*
  3. The crystal structure of anhydrous zinc metaborate Zn4O(BO2)6
  4. Relations between diffuse reflections and geometry of the unit cells in isomorphous compounds [Me(II)(N2H4)2]Cl2
  5. An electron-diffraction study of NaF thin films condensed in vacuum
  6. Crystal structure of an authigenic maximum microcline
  7. The crystal structure of tetrahedrite, Cu12Sb4S13
  8. Stacking relations in the hexagonal ferrites and a new series of mixed-layer structures*
  9. Crystallographic data for NiSeO4 · 6H2O and MgSeO4 · 6H2O
  10. Unit cell and space group of B-trimethyl N-triphenyl borazole, B3(CH3)3N3(C6H5)3
  11. Zur Gitterstruktur von (c-C6H11)2P(O)SH und (c-C6H 1)2(S)P-P(S)(c-C6H11)2
  12. Errata
  13. Q values for indexing x-ray powder patterns according to Ito.
  14. Errata
  15. International Conference on Electron Diffraction and Crystal Defects, Melbourne, 1965
https://doi.org/10.1524/zkri.1964.119.5-6.357

Articles in the same Issue

  1. Struktur elektrolytischer Schichten im Endwachstum* Eine Untersuchung des Zusammenhanges von Oberflächenform und Vorzugsorientierung mit den Methoden der Elektronenbeugung und Elektronenmikroskopie
  2. The crystal structure of barium hydroxide octahydrate Ba(OH)2·8H2O*
  3. The crystal structure of anhydrous zinc metaborate Zn4O(BO2)6
  4. Relations between diffuse reflections and geometry of the unit cells in isomorphous compounds [Me(II)(N2H4)2]Cl2
  5. An electron-diffraction study of NaF thin films condensed in vacuum
  6. Crystal structure of an authigenic maximum microcline
  7. The crystal structure of tetrahedrite, Cu12Sb4S13
  8. Stacking relations in the hexagonal ferrites and a new series of mixed-layer structures*
  9. Crystallographic data for NiSeO4 · 6H2O and MgSeO4 · 6H2O
  10. Unit cell and space group of B-trimethyl N-triphenyl borazole, B3(CH3)3N3(C6H5)3
  11. Zur Gitterstruktur von (c-C6H11)2P(O)SH und (c-C6H 1)2(S)P-P(S)(c-C6H11)2
  12. Errata
  13. Q values for indexing x-ray powder patterns according to Ito.
  14. Errata
  15. International Conference on Electron Diffraction and Crystal Defects, Melbourne, 1965
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