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Die Kristallstruktur einiger Alkohol-Halbhydrate

Veröffentlicht/Copyright: 28. Juli 2010
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Abstract

The semihydrates of pentamethylethylalcohol and of four other alcohols of similar, approximately spherical molecular structure have been investigated. The needle-shaped crystals have the orthorhombic space group C2v21Iba2 with eight alcohol and four water molecules per unit cell.

The structure of the pentamethyl-ethylalcohol hydrate has been determined. Parallel to the needle direction infinite chains are formed by hydrogen bonds …Ow = (OA)2 = Ow = (OA)2 = Ow…, the oxygen atoms Ow of the water molecules being surrounded by four oxygen atoms OA of the alcohol molecules in a nearly tetrahedral position.

Published Online: 2010-07-28
Published in Print: 1963-11
Heruntergeladen am 10.1.2026 von https://www.degruyterbrill.com/document/doi/10.1524/zkri.1963.119.1-2.15/pdf
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