Determination of 234U and 238U in seawater samples by alpha spectrometry after concentration of U(VI) onto hydrotalcite and co-precipitation with LaF3
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N. V. Suc
und
T. T. Bich
Summary
This paper presents a simple and accurate method for determination of uranium isotopes (234U and 238U) in seawater samples using alpha spectrometry. Uranium is pre-concentrated from seawater samples via adsorption on hydrotalcite at pH 6.5. The absorbent is dissolved into 50 ml of 8M HNO3; then filtered through a Dowex-1 column. U(VI) in the elution solution is reduced to U(IV) using zinc metal in 4M solution of HCl and then co-precipitated with LaF3. The chemical separation efficiency is found to be 97.12±2.68%, eliminating the need of using 232U tracer in other published methods. This method is validated via comparison with results obtained using inductively coupled plasma mass spectrometry (ICP-MS) and neutron activation analysis (NAA) for three seawater samples.
© 2013 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
Artikel in diesem Heft
- Inhalt
- Cross-sections of 45Sc(n, 2n)44m,gSc reaction from the reaction threshold to 20 MeV
- Fast neutron spectrum unfolding of a TRIGA Mark II reactor and measurement of spectrum-averaged cross sections: integral tests of differential cross sections of neutron threshold reactions
- Determination of 234U and 238U in seawater samples by alpha spectrometry after concentration of U(VI) onto hydrotalcite and co-precipitation with LaF3
- Substitution of IO3 −, IO4−, SeO3 2−, and SeO42− for CO32− in Na4[UO2(CO3)3]
- Structure and spectroscopy of uranyl salicylaldiminate complexes
- A comparison between the chemical behaviour of lead-gold and lead-bismuth eutectics towards 316L stainless steel
- Effect of temperature on the solubility and solid phase stability of zirconium hydroxide
- Purification of selenium from thorium, uranium, radium, actinium and potassium impurities for low background measurements
- Analysis of long-lived radionuclides produced by proton irradiation in lead targets – γ -measurements
- Feasibility studies for production of 89Sr in the Fast Breeder Test Reactor (FBTR)
- Synthesis of I-131 labelled iodine species relevant during severe nuclear accidents in light water reactors
Artikel in diesem Heft
- Inhalt
- Cross-sections of 45Sc(n, 2n)44m,gSc reaction from the reaction threshold to 20 MeV
- Fast neutron spectrum unfolding of a TRIGA Mark II reactor and measurement of spectrum-averaged cross sections: integral tests of differential cross sections of neutron threshold reactions
- Determination of 234U and 238U in seawater samples by alpha spectrometry after concentration of U(VI) onto hydrotalcite and co-precipitation with LaF3
- Substitution of IO3 −, IO4−, SeO3 2−, and SeO42− for CO32− in Na4[UO2(CO3)3]
- Structure and spectroscopy of uranyl salicylaldiminate complexes
- A comparison between the chemical behaviour of lead-gold and lead-bismuth eutectics towards 316L stainless steel
- Effect of temperature on the solubility and solid phase stability of zirconium hydroxide
- Purification of selenium from thorium, uranium, radium, actinium and potassium impurities for low background measurements
- Analysis of long-lived radionuclides produced by proton irradiation in lead targets – γ -measurements
- Feasibility studies for production of 89Sr in the Fast Breeder Test Reactor (FBTR)
- Synthesis of I-131 labelled iodine species relevant during severe nuclear accidents in light water reactors
